Studies on photoinduced effects in pulse-electrodeposited Ag/Hg-1212/CdSe hetero-nanostructures

Metal/superconductor/semiconductor (Ag/Hg-1212/CdSe) hetero-nanostructures have been fabricated using pulse-electrodeposition technique and are characterized by X-ray diffraction (XRD), full-width at half-maximum (FWHM) and scanning electron microscopy (SEM) studies. The junction capacitance of Ag/Hg-1212, Hg-1212/CdSe and Ag/Hg-1212/CdSe heterojunctions is measured in dark and under laser irradiation at room temperature. The nature of the junction formed and built-in-junction potentials were determined. The increase in carrier concentration across the junction due to photo-irradiation has been observed.     

Effect of laser irradiation of C-V characteristics of electrodeposited Ag/Tl-2223/CdSe hetero-nanostructures

One of the innovative technological directions for the high-temperature superconductors has been persued by fabricating the heteroepitaxial multilayer structures such as superconductor-semiconductor heterostructures. In the present investigation, metal/superconductor/semiconductor (Ag/Tl-2223/CdSe) hetero-nanostructures have successfully been fabricated using dc electrodeposition technique and were characterized by X-ray diffraction (XRD), full-width at half-maximum (FWHM) and scanning electron microscopy (SEM) studies. The measurement of junction capacitance as a function of biasing voltage was used for the estimation of junction built-in-potential (V _D) and to study the charge distribution in a heterojunction. The Mott-Schottky plots were measured for each junction in dark and under the photo-irradiation. The effect of laser irradiation on C-V characteristics of hetero-nanostructure has been studied.     

Quantum Chemical Study of Water Adsorption on the Surfaces of SrTiO3 Nanotubes

We have studied the adsorption of water molecules on the inner and outer surfaces of nanotubes generated by rolling (001) layers of SrTiO₃ cubic crystals. The stability and the atomic and electronic structures of the adsorbed layers are determined by using hybrid density functional theory. The absorption energy and the preferred adsorbate structure are essentially governed by the nature of the surface of the nanotube. Dissociative adsorption prevails on the outer nanotube surfaces. The stability of the adsorbed layers on the inner surfaces is related to the possibility of the formation of hydrogen bonds between water molecules and surface oxygen atoms, and depends on the surface curvature. The presence of water molecules on the inner surface of the nanotubes leads to an increase of the electronic band gap. Externally TiO₂‐terminated nanotubes could be used for the photocatalytic decomposition of water by ultraviolet radiation.     

Calculation of Young’s Modulus of MoS2-Based Single-Wall Nanotubes Using Force-Field and Hybrid Density Functional Theory

Physics of the Solid State - A force field is proposed that reproduces with a high accuracy a large number of properties of the bulk crystal MoS2 phases, monolayers, and nanotubes. The reproduced...     

Hybrid HF–DFT modeling of monolayer water adsorption on (001) surface of cubic BaHfO3 and BaZrO3 crystals

First-principles calculations have been used to study the atomic structure, preferred sites and adsorption energies for water adsorption at different terminations of the cubic phase of perovskite-structured BaHfO₃ and BaZrO₃. By considering different initial positions of water molecules, the possibility of water dissociation has been investigated. It is demonstrated that the site selectivity and the form of adsorbed molecule can be affected by the choice of surface unit cell. Dissociative adsorption was found to be favorable for all surfaces in consideration. Hydroxylation of ZrO₂- and HfO₂-terminated surfaces is accomplished by a noticeable reconstruction of the surface structure of cubic phase towards the orthorhombic phase. Calculated atomic charges in bare and hydroxylated surfaces show that BaHfO₃ crystal is slightly more ionic than BaZrO₃.     

BaTiO3‐based nanolayers and nanotubes: First‐principles calculations

The first‐principles calculations using hybrid exchange‐correlation functional and localized atomic basis set are performed for BaTiO₃ (BTO) nanolayers and nanotubes (NTs) with the structure optimization. Both the cubic and the ferroelectric BTO phases are used for the nanolayers and NTs modeling. It follows from the calculations that nanolayers of the different ferroelectric BTO phases have the practically identical surface energies and are more stable than nanolayers of the cubic phase. Thin nanosheets composed of three or more dense layers of (0 1 0) and (0 1 ) faces preserve the ferroelectric displacements inherent to the initial bulk phase. The structure and stability of BTO single‐wall NTs depends on the original bulk crystal phase and a wall thickness. The majority of the considered NTs with the low formation and strain energies has the mirror plane perpendicular to the tube axis and therefore cannot exhibit ferroelectricity. The NTs folded from (0 1 ) layers may show antiferroelectric arrangement of Ti? O bonds. Comparison of stability of the BTO‐based and SrTiO₃‐based NTs shows that the former are more stable than the latter. © 2012 Wiley Periodicals, Inc.     

玫瑰红与介孔二氧化硅生物光敏复合体的激发态性质

以光动力治疗药物玫瑰红( Rose Bengal,RB)与孔径为2.7nm的介孔二氧化硅MCM-41为主体材料进行结构组装,制备了具有生物光敏功能的介孔复合载体.对介孔复合载体的性质进行了表征,通过紫外吸收和荧光光谱对玫瑰红RB在介孔孔道内的光学性质进行了分析.由于介孔道表面与RB的相互作用,不同结构和性质的内孔道中的...     

环形区域上Zernike模式法波前重构

 针对激光技术领域常见的环形激光光束,利用圆域Zernike多项式和环域Zernike多项式进行模式法波前重构,结果显示,如果环形激光光束波前相位畸变主要由低空间频率成分组成,则可以直接利用圆域Zernike多项式进行波前重构;如果环形激光光束波前相位畸变含有较多的高阶频率成分,则利用环域Zernike多项式进行波前重构。