Electrospun Porous NiCo2O4 Nanotubes as Advanced Electrodes for Electrochemical Capacitors

Novel, porous NiCo₂O₄ nanotubes (NCO‐NTs) are prepared by a single‐spinneret electrospinning technique followed by calcination in air. The obtained NCO‐NTs display a one‐dimensional architecture with a porous structure and hollow interiors. The effect of precursor concentration on the morphologies of the products is investigated. Due to their unique structure, the prepared NCO‐NT electrode exhibits a high specific capacitance (1647 F g^?1 at 1 A g^?1), excellent rate capability (77.3 % capacity retention at 25 A g^?1), and outstanding cycling stability (6.4 % loss after 3000 cycles), which indicates it has great potential for high‐performance electrochemical capacitors. The desirable enhanced capacitive performance of NCO‐NTs can be attributed to the relatively large specific surface area of these porous and hollow one‐dimensional nanostructures.     

平面圆电流在远处任一点激发的磁场

文章用普通物理的方法计算了平面载流圆线圈在远处任意一点激发的磁场．     

恢复系数e一定满足0≤e≤1吗?

作者从恢复系数ｅ的一般定义出发，引入了“穿透”碰撞与“爆炸”碰撞的概念，从而将ｅ的取值范围扩大到实数．     

任意形状载流线圈在p_m“延长线”上和“中垂面”上远处一点激发的磁场

文章用普通物理的方法计算了任意形状载流线圈在过线圈几何中心且与 pm平行的直线上和过线圈几何中心且与 pm 垂直的平面上远处点激发的磁场     

Carbon coated nano-LiTi2(PO4)3 electrodes for non-aqueous hybrid supercapacitors

The Pechini type polymerizable complex decomposition method is employed to prepare LiTi(2)(PO(4))(3) at 1000 °C in air. High energy ball milling followed by carbon coating by the glucose-method yielded C-coated nano-LiTi(2)(PO(4))(3) (LTP) with a crystallite size of 80(±5) nm. The phase is characterized by X-ray diffraction, Rietveld refinement, thermogravimetry, SEM, HR-TEM and Raman spectra. Lithium cycling properties of LTP show that 1.75 moles of Li (~121 mA h g(-1) at 15 mA g(-1) current) per formula unit can be reversibly cycled between 2 and 3.4 V vs. Li with 83% capacity retention after 70 cycles. Cyclic voltammograms (CV) reveal the two-phase reaction mechanism during Li insertion/extraction. A hybrid electrochemical supercapacitor (HEC) with LTP as negative electrode and activated carbon (AC) as positive electrode in non-aqueous electrolyte is studied by CV at various scan rates and by galvanostatic cycling at various current rates up to 1000 cycles in the range 0-3 V. Results show that the HEC delivers a maximum energy density of 14 W h kg(-1) and a power density of 180 W kg(-1).     

关于恢复系数e的讨论

定义了物体的绝对恢复系数、计算一两物体碰撞时的共同恢复系数与两物体各自绝对恢复系数的关系，讨论了碰撞中的两物体各自因范性形变而损失的机械能。     

非平面载流线圈的磁矩

本文定义了非平面载流线圈的磁矩，计算了它在均匀磁场中所受的磁力矩，并举例计算了线圈的磁矩和磁力矩．     

Electrospun Hierarchical CaCo2O4 Nanofibers with Excellent Lithium Storage Properties

Hierarchical CaCo₂O₄ nanofibers (denoted as CCO‐NFs) with a unique hierarchical structure have been prepared by a facile electrospinning method and subsequent calcination in air. The as‐prepared CCO‐NFs are composed of well‐defined ultrathin nanoplates that arrange themselves in an oriented manner to form one‐dimensional (1D) hierarchical structures. The controllable formation process and possible formation mechanism are also discussed. Moreover, as a demonstration of the functional properties of such hierarchical architecture, the 1D hierarchical CCO‐NFs were investigated as materials for lithium‐ion batteries (LIBs) anode; they not only delivers a high reversible capacity of 650 mAh g^?1 at a current of 100 mA g^?1 and with 99.6 % capacity retention over 60 cycles, but they also show excellent rate capability with respect to counterpart nanoplates‐in‐nanofibers and nanoplates. The high specific surface areas as well as the unique feature of hierarchical structures are probably responsible for the enhanced electrochemical performance. Considering their facile preparation and good lithium storage properties, 1D hierarchical CCO‐NFs will hold promise in practical LIBs.