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排序方式: 共有4227条查询结果,搜索用时 15 毫秒
1.
Shilin Jiang Dr. Yalan Liu Dr. Lin Wang Prof. Zhifang Chai Prof. Wei-Qun Shi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201145
The coordination chemistry of f-block elements (lanthanide and actinide) in molten salts has become a resounding topic in view of its great importance to the research and development (R&D) of molten salt reactors and pyroprocessing. In this Review article, a general overview of the coordination chemistry of f-block elements in molten salts is provided including past achievements and recent advances. Particular emphases are placed on the oxidation state, speciation, and solution structure of f-block metal ions in molten salts, as well as their relationships with the salt composition. Furthermore, this review briefly discusses the spectroscopic and theoretical methods that complement each other in revealing the coordination properties. 相似文献
2.
Hao Lu Xiaodong Wang Hang Wang Andong Zhang Xinming Zheng Na Yu Zheng Tang Xinjun Xu Yahui Liu Ya-Nan Chen Zhishan Bo 《中国科学:化学(英文版)》2022,65(3):594-601
Three nonfused ring electron acceptors (NFREAs) TTC6,TT-C8T and TT-TC8 were purposefully designed and synthesized.The molecular geometry can be adjusted by the steric hindrance of lateral substituents.According to the DFT calculations,from TTC6 to TT-C8T and TT-TC8,planarity of the molecular backbone is gradually improved,accompanying with the enhancing of intramolecular charge transfer effect.As for TT-TC8,the two phenyl substituents are almost perpendicular to the molecular backbone,which endues the acceptor with good solubility and suppresses it to form over-aggregation.Multidirectional regular molecular orientation and closer molecular stacking are formed in TT-TC8 film.As a result,TT-TC8 based devices afford the highest PCE of 13.13%,which is much higher than that of TTC6 (4.41%) and TT-C8T (10.42%) and among the highest PCE values based on NFREAs. 相似文献
3.
本文给出了混合型多项式Hammerstein积分方程正解的迭代求法,并将所得结果应用到二阶非线性常微分方程的边值问题 相似文献
4.
Inspired by the recent work [HHM03], we prove two stability results for compact Riemannian manifolds with nonzero parallel spinors. Our first result says that Ricci flat metrics which also admit nonzero parallel spinors are stable (in the direction of changes in conformal structures) as the critical points of the total scalar curvature functional. Our second result, which is a local version of the first one, shows that any metric of positive scalar curvature cannot lie too close to a metric with nonzero parallel spinor. We also prove a rigidity result for special holonomy metrics. In the case of SU(m) holonomy, the rigidity result implies that scalar flat deformations of Calabi-Yau metric must be Calabi-Yau. Finally we explore the connection with a positive mass theorem of [D03], which presents another approach to proving these stability and rigidity results. Dedicated to Jeff Cheeger for his sixtieth birthday 相似文献
5.
This paper presents a multiobjective hybrid metaheuristic approach for an intelligent spatial zoning model in order to draw territory line for geographical or spatial zone for the purpose of space control. The model employs a Geographic Information System (GIS) and uses multiobjective combinatorial optimization techniques as its components. The proposed hybrid metaheuristic consists of the symbiosis between tabu search and scatter search method and it is used heuristically to generate non-dominated alternatives. The approach works with a set of current solution, which through manipulation of weights are optimized towards the non-dominated frontier while at the same time, seek to disperse over the frontier by a strategic oscillation concept. The general procedure and its algorithms are given as well as its implementation in the GIS environment. The computation has resulted in tremendous improvements in spatial zoning. 相似文献
6.
A reliable method is presented for the chiral separation of three basic drugs (mexiletine, chlorpheniramine and propranolol) with serum albumins (human and porcine, HSA and PSA) as chiral selectors by capillary electrophoresis in combination with the partial filling technique. Based on the systematic optimization of operation variables, the chiral separation of mexiletine, chlorpheniramine and propranolol was achieved in the pH 7.4 phosphate buffer by using HSA, PSA and PSA as selectors, respectively. The chiral recognition ability of HSA and PSA was compared. HSA and PSA show a different chiral recognition ability for each of the three drugs. In addition, the association constants between enantiomeric drugs and proteins were determined to be 2.00 and 3.80 x 10(2) M(-1) for mexiletine and HSA, 0.59 and 1.12 x 10(3) M(-1) for chlorpheniramine and PSA, and 0.87 and 1.42 x 10(3) M(-1) for propranolol and PSA. The method for the chiral separation and determination of association constants possesses the advantages of simple performance, effective avoiding of the interference of the UV detection from protein, and lowering of the reagent consumption. 相似文献
7.
Xiaodong Hu 《应用数学学报(英文版)》1993,9(2):97-103
Since the point-to-set maps were introduced by Zangwill[1] in the study of conceptual algorithms, various sufficient conditions for the algorithms to be of global convergence have been established. In this paper, the relations among all these conditions are illustrated by a unified approach; still more, unlike the sufficient conditions previously given in the literature, a new necessary condition is put forward at the end of the paper, so that it implies more applications. 相似文献
8.
Banach空间中一类非线性算子Ishikawa迭代序列收敛定理 总被引:7,自引:1,他引:6
柴国庆 《数学物理学报(A辑)》1998,18(4):459-466
在一般的Banach空间中,研究了Ishikawa迭代序列收敛问题,去掉了通常文献中关于空间X的一致光滑或S-一致光滑的严格要求,此外,还去掉或减弱了其它某些条件。因而本质地改进了近期文献的一系列相应定理。 相似文献
9.
10.
Study on the in—plane electrical resistivity and thermoelectric power in single crystals of La2—xBaxCuO4 下载免费PDF全文
The in-plane electrical resistivity and thermoelectric power have been measured on single crystals of La2-xBaxCuO4 at around x=0.125. The room temperature resistivity and thermopower have their maximum values at x=0.125, indicating that the carrier concentration is the minimum and the carriers are most strongly localized at x=0.125. The observed semiconductor-like behaviour can be well described by the weak-localized quasi-two-dimensional state. The steep rise in electric resistivity of the sample at x=0.125 below 70K is attributed to the formation of static stripe-order of holes and spins, which are pinned by the low-temperature tetragonal (LTT) structure, as discovered in La1.48Nd0.4Sr0.12CuO4. The temperature dependence of electric resistivity below 70K is still well described by the formula ρ∝ lnT. A definite change in the slope of thermopower is observed at the low-temperature orthorhombic-LTT structural phase transition temperature. The origin of the 1/8 anomaly is discussed in the text. 相似文献