The infrared spectra (600-150 cm−1 of pyridine N-oxide complexes of metal(II) halides and mixed-ligand (pyridine N-oxide—dimethylsulphoxide) complexes of copper(II) halides

The infrared spectra of the complexes [M(pyO)(H₂O)Cl₂] (M = Mn, Fe, Co, Ni, Cu; pyO = pyridine N-oxide) have been determined. Assignments of ν M-Opy, νM-OH₂ and ν M-Cl are made by observing the effects of deuterating the coordinated pyO and H₂O and replacing chloride by bromide in the Mn(II) complex. Assignments of metal—ligand modes in the mixed ligand complexes [M(pyO)(dmso)X₂] (dmso = dimethylsulphoxide) are made by comparison with the spectra of (ML₂X₂] (L = pyO, dmso) and by observing the effects of deuteration of pyO and dmso. Structural aspects of the spectra are discussed.     

Growth and Atomic-Scale Characterization of Ultrathin Silica and Germania Films: The Crucial Role of the Metal Support

The present review reports on the preparation and atomic-scale characterization of the thinnest possible films of the glass-forming materials silica and germania. To this end state-of-the-art surface science techniques, in particular scanning probe microscopy, and density functional theory calculations have been employed. The investigated films range from monolayer to bilayer coverage where both, the crystalline and the amorphous films, contain characteristic XO₄ (X=Si,Ge) building blocks. A side-by-side comparison of silica and germania monolayer, zigzag phase and bilayer films supported on Mo(112), Ru(0001), Pt(111), and Au(111) leads to a more general comprehension of the network structure of glass former materials. This allows us to understand the crucial role of the metal support for the pathway from crystalline to amorphous ultrathin film growth.     

An orthonormalization method: Theory and application to the j-j coupling of fermions in a single j-shell

An orthonormalization method suitable to deal with an overcomplete and non-orthogonal set of vectors is derived. It is then used to obtain the orthonormal set of states connected with the angular momentum coupling of N fermions in a single j-shell.     

Unambiguous identification of three beta-decaying isomers in 70Cu

Using resonant laser ionization, beta-decay studies, and for the first time mass measurements, three beta-decaying states have been unambiguously identified in 70Cu. A mass excess of -62 976.1(1.6) keV and a half-life of 44.5(2) s for the (6-) ground state have been determined. The level energies of the (3-) isomer at 101.1(3) keV with T(1/2)=33(2) s and the 1+ isomer at 242.4(3) keV with T(1/2)=6.6(2) s are confirmed by high-precision mass measurements. The low-lying levels of 70Cu populated in the decay of 70Ni and in transfer reactions compare well with large-scale shell-model calculations, and the wave functions appear to be dominated by one proton-one neutron configurations outside the closed Z=28 shell and N=40 subshell. This does not apply to the 1+ state at 1980 keV which exhibits a particular feeding and deexcitation pattern not reproduced by the shell-model calculations.     

\alpha-decay spectroscopy of light odd-odd Bi isotopes - II: 186Bi and the new nuclide 184Bi

Alpha-decay of the new nuclide ¹⁸⁴Bi has been studied in the complete-fusion reaction ⁹³Nb(⁹⁴Mo, 3n)¹⁸⁴Bi at the velocity filter SHIP. The evaporation residues were separated in-flight and subsequently identified on the basis of recoil- , recoil- - analysis and excitation functions measurements. Two -decaying isomeric states in ¹⁸⁴Bi with half-life values of 13(2) ms and 6.6(1.5) ms were identified. The -branching ratio of ¹⁸⁰Tl was deduced for the first time as . Improved data on the fine-structure -decay of ¹⁸⁶Bi were obtained in the ⁹³Nb(⁹⁵Mo, 2n)¹⁸⁶Bi reaction. A similarity of the decay energies and half-life values of ^184,186Bi is pointed out and a possible explanation for this effect is suggested.Received: 14 March 2003, Revised: 29 April 2003, Published online: 2 September 2003PACS: 23.60.+e decay - 27.70.+q - 27.80.+w K. Heyde: Present address: EP-ISOLDE, CERN, CH-1211, Geneva 23, Switzerland.     

A Cautionary note on modeling with fractional Lévy flights

Temporal scaling and infinite variance are two stylized features often seen together in times series of complex systems. We find that because of their infinite moments samples from fractional Lévy flights produce bi-linear scaling functions which may be incorrectly attributed as evidence of multifractality. We argue that it is unnecessary to consider truncated fractional Lévy flights which are inherently problematic.     

Alkalimetrische Mikrobestimmung der Aminos?uren und Peptide

Ohne Zusammenfassung