全文获取类型
收费全文 | 775篇 |
免费 | 25篇 |
国内免费 | 1篇 |
专业分类
化学 | 479篇 |
晶体学 | 13篇 |
力学 | 9篇 |
数学 | 85篇 |
物理学 | 215篇 |
出版年
2023年 | 3篇 |
2022年 | 12篇 |
2021年 | 13篇 |
2020年 | 20篇 |
2019年 | 15篇 |
2018年 | 15篇 |
2017年 | 13篇 |
2016年 | 17篇 |
2015年 | 19篇 |
2014年 | 13篇 |
2013年 | 79篇 |
2012年 | 43篇 |
2011年 | 50篇 |
2010年 | 47篇 |
2009年 | 39篇 |
2008年 | 48篇 |
2007年 | 39篇 |
2006年 | 48篇 |
2005年 | 23篇 |
2004年 | 24篇 |
2003年 | 39篇 |
2002年 | 23篇 |
2001年 | 11篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 7篇 |
1997年 | 7篇 |
1996年 | 6篇 |
1995年 | 12篇 |
1994年 | 15篇 |
1993年 | 7篇 |
1992年 | 6篇 |
1991年 | 2篇 |
1990年 | 4篇 |
1989年 | 9篇 |
1988年 | 5篇 |
1987年 | 7篇 |
1986年 | 6篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1982年 | 7篇 |
1981年 | 8篇 |
1980年 | 7篇 |
1972年 | 4篇 |
1970年 | 2篇 |
1969年 | 3篇 |
1966年 | 1篇 |
1965年 | 1篇 |
1957年 | 1篇 |
1954年 | 1篇 |
排序方式: 共有801条查询结果,搜索用时 93 毫秒
1.
2.
Gowravaram Sabitha G.S.Kiran Kumar ReddyK.Bhaskar Reddy J.S. Yadav 《Tetrahedron letters》2003,44(34):6497-6499
The three component condensation of an aldehyde, a β-keto ester and urea (thiourea) in the presence of a catalytic amount of VCl3 is disclosed for the solution phase synthesis of dihydropyrimidinones. The ease of synthesis and work-up allowed the parallel synthesis of a 48-membered library of dihydropyrimidinones quickly and efficiently in good yields. 相似文献
3.
Prapti Saxena Sankar P. Sanyal 《Physica E: Low-dimensional Systems and Nanostructures》2004,24(3-4):244-248
We report a detailed study of the phonon properties of hexagonal boron nitride (BN) monolayers as well as nanotubes by using De Launay type of angular force model. The force constants used for calculation of phonon dispersion relations of the nanotube are derived from those for the monolayers of hexagonal by employing force constant method. These force constants have been modified to include the effect of curvature of the tubule. The results are then used to derive the phonon dispersion relations for (10,10) BN nanotubes using ‘zone-folding’ method. Calculated phonon modes are in good agreement with the experimental values obtained so far, for (10,10) armchair BN nanotubes. 相似文献
4.
5.
Venkatapuram Padmavathi Mudigonda Rajagopala Sarma Adivireddy Padmaja Dandu Bhaskar Reddy 《Journal of heterocyclic chemistry》2003,40(5):933-937
Novel 2‐pyrazolines were obtained by the cycloaddition of diazomethane to bis(arylsulfonylethenyl)‐sulfones ( 3 ) and 1‐arylsulfonyl‐2‐styrylsulfonylethenes (7). Dehydrogenation of 2‐pyrazolines with chloranil gave pyrazoles. 相似文献
6.
An enantioselective synthesis of (+)-prelactone B 1 has been achieved on a multigram scale starting from a known bicyclic precursor 2. The key feature of the strategy is the generation of 3-stereogenic centres from a single bicyclic precursor, which has been utilized as a chiral building block for the synthesis of various natural products. 相似文献
7.
N. K. Sanyal A. N. Pandey H. S. Singh B. P. Singh 《Journal of Quantitative Spectroscopy & Radiative Transfer》1970,10(12):1343-1345
The generalized mean-square amplitudes of vibration and mean amplitudes of vibration have been computed for CrO3-4, Mn18O-4, MoSe2-4 and WSe2-4 ions at three temperatures, T = 0°K, T = 298°K, T = 500°K, employing Cyvin's method. The results have been discussed in the light of atomic weight and electronegativity of the atom in the ionic system. 相似文献
8.
9.
Koteswara Rao Y Vijaya Bhaskar Reddy M Venkata Rao C Gunasekar D Blond A Caux C Bodo B 《Chemical & pharmaceutical bulletin》2002,50(9):1271-1272
Two new 5-deoxyflavones, 7,8-dimethoxy-3',4'-methylenedioxyflavone (1) and 7,2',4'-trimethoxyflavone (2) together with a known flavone, 7,4'-dimethoxy-3'-hydroxyflavone (3) were isolated from the rootbark of Albizia odoratissima. The structures of these new compounds were elucidated by electrospray ionization mass spectrometry (ESI-MS) and 1D and 2D-NMR spectral studies including (1)H-(1)H correlation spectroscopy (COSY), heteronuclear single quantum coherence (HSQC), heteronuclear multiple bond connectivity (HMBC) and nuclear Overhauser enhancement spectroscopy (NOESY). 相似文献
10.
J.S. Yadav B.V.Subba Reddy B. Padmavani Ch. Venugopal A.Bhaskar Rao 《Tetrahedron letters》2007,48(26):4631-4633
Enzymatic kinetic resolution of (±)-hydroxytetrahydropyrans has been achieved for the first time by means of lipase-mediated transesterification to afford optically active (2S,4R)-tetrahydropyranyl acetates and (2R,4S)-tetrahydropyranols in excellent yields with high enantioselectivity. Absolute configurations of the tetrahydropyranyl acetates were assigned as (S) by chemical correlation. 相似文献