Syntheses and mesomorphic properties of new oxygen-bridged dicopper complex homologous derived from azo-containing salicylaldimine Schiff base ligands

The synthesis, characterization and liquid crystal properties of a homologous series of new tridentate 5-((4-ⁿalkoxyphenyl) azo)-N-(3-ydroxypropyl) salicylaldimine ligands (alkoxy = octloxy, decyloxy, dodecyloxy and tetradecyloxy) and their dicopper(II) complexes are reported. These ligands were prepared by the condensation of the 5-((4-ⁿalkoxyphenyl)azo)salicylaldehydes homologous with 3-amino-1-propanol. The ligands and their dicopper complexes have been characterized by IR, ¹H NMR, mass spectroscopy and elemental analyzes. The liquid crystalline properties of the ligands and the related dicopper complexes were studied by differential scanning calorimetry (DSC) and by using a polarizing microscope equipped with a heating and cooling stage. None of the free ligands exhibit liquid crystalline behavior but all of the dicopper complexes demonstrate a smectic A mesophase.     

Global existence and boundedness of classical solutions for a chemotaxis model with consumption of chemoattractant and logistic source

This paper deals with the following chemotaxis system: under homogeneous Neumann boundary conditions in a bounded domain with smooth boundary. Here, δ and χ are some positive constants and f is a smooth function that satisfies with some constants a ?0,b  > 0, and γ  > 1. We prove that the classical solutions to the preceding system are global and bounded provided that Copyright © 2016 John Wiley & Sons, Ltd.     

Enhancement of convective heat transfer by electrically-induced swirling effect in laminar and fully-developed internal flows

A computational and experimental approach is undertaken to study the enhancement of convective heat transfer in fully-developed internal flows by an electrically-induced secondary flow field. Using longitudinal flat electrodes along a parallel-plate configuration, the corona discharge is employed to generate an electrically induced secondary flow on the cross section of the flow passage. The electrically-induced secondary flow forms a swirling flow field in the fully-developed condition and enhances the heat transfer significantly. The flow field was solved computationally and the results were verified and validated by grid refinement study and computational error analysis.