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1.
A method using capillary gel electrophoresis with laser-induced fluorescence detection is described which permits complete sequence determination of antisense DNA analogues of unknown sequence. This method, originally created as a tool to confirm the sequence of antisense oligonucleotides being developed as therapeutic drugs, utilizes data collected under a range of experimental conditions described by the Ogston model as applied to gel electrophoresis. A linear relationship independent of experimental conditions between the relative electrophoretic migration time and the oligonucleotide base number was observed and is shown to be consistent with a simplified version of this model and can be used to facilitate the sequence determination. 相似文献
2.
The contacts of single carbon nanotubes and bundles of carbon nanotubes with superconducting and metallic electrodes are investigated in order to create bolometers and electron coolers. Tunneling contacts of the carbon nanotubes with aluminum electrodes are obtained. The current-voltage characteristics of junctions are analyzed for temperatures from room temperature to 300 mK. The resistance of individual nanotubes is primarily determined by defects and is too large for applications. The use of the bundles of carbon nanotubes makes it possible to considerably reduce the resistance of the bolometer, which is determined by a small number of conducting tubes with good tunneling contacts with the electrodes. The energy gap is equal to hundreds and tens of millivolt in the former and latter cases, respectively. Structures containing bundles of carbon nanotubes can be described in a model with a Schottky barrier. The samples with bundles of carbon nanotubes exhibit the bolometric response to external high-frequency radiation at a frequency of 110 GHz with an amplitude up to 100 μV and a temperature voltage response to 0.4 mV/K. 相似文献
3.
Marcelino Maneiro Manuel R. Bermejo M. Isabel Fernndez Ana M. Gonzlez‐Noya Alexei M. Tyryshkin Robin G. Pritchard 《无机化学与普通化学杂志》2003,629(2):285-290
A new MnIII‐Schiff base complex, [MnL(OH2)](ClO4) ( 1 ) (H2L = N, N′‐bis‐(3‐Br‐5‐Cl‐salicylidene)‐1, 2‐diimino‐2‐methylethane), an inorganic model of the catalytic center (OEC, Oxygen Evolving Complex) in photosystem II (PSII), has been synthesized and characterized by elemental analysis, IR and EPR spectroscopy, mass spectrometry, magnetic susceptibility measurement and the study of its redox properties by cyclic and normal pulse voltammetry. This complex mimics reactivity (showing a relevant photolytic activity), and also some structural characteristics (parallel‐mode MnIII EPR signal from partially assembled OEC cluster) of the natural OEC. The complex 1 was found to rearrange in solution into a crystallographically solved square‐pyramidal complex, [MnLL′] ( 2 ) (HL′ = 6‐bromo‐4‐chloro‐2‐cyanophenol), through a process, which probably liberates radical species (detected by EPR), and provokes a C—N bond cleavage in the ligand. A photo‐radical mechanism is discussed to explain this rearrangement. 相似文献
4.
Early stages of rare-earth metal (Yb and Eu) growth on a vicinal, single-domain Si(1 0 0)2 × 1 surface have been studied in the coverage range of 0.1-0.3 monolayer (ML) by low energy electron diffraction, scanning tunneling microscopy, and synchrotron radiation photoemission spectroscopy. We show that Yb induces the 2 × 3 periodicity in the whole range of coverage studied. The 2 × 3 reconstruction coexists with the local 3 × 2/4 × 2 structure at about 0.2 ML of Yb. In contrast, Eu forms the 3 × 2 periodicity at 0.1-0.2 ML, whereas this structure is converted into the 2 × 3 phase at about 0.3 ML. The atomic arrangement and electronic properties of these reconstructions and the adsorbate-mediated modification of surface morphology are investigated. 相似文献
5.
6.
Florin Radu Alexei Nefedov Johannes GrabisGregor Nowak Andre BergmannHartmut Zabel 《Journal of magnetism and magnetic materials》2006
We have used soft X-ray resonant magnetic scattering (XRMS) to search for the presence of an effective ferromagnetic moment belonging to the antiferromagnetic (AF) layer which is in close contact with a ferromagnetic (F) layer. Taking advantage of the element specificity of the XRMS technique, we have measured hysteresis loops of both Fe and CoO layers of a CoO(40 Å)/Fe (150 Å) exchange bias bilayer. From these measurements we have concluded that the proximity of the F layer induces a magnetic moment in the AF layer. The F moment of the AF layer has two components: one is frozen and does not follow the applied magnetic field and the other one follows in phase the ferromagnetic magnetization of the F layer. The temperature dependence of the F components belonging to the AF layer is shown and discussed. 相似文献
7.
S. G. Barsov A. L. Getalov S. L. Ginsburg V. P. Koptev S. P. Kruglov L. A. Kuzmin S. V. Maleyev E. I. Maltsev S. M. Mikirtychyants N. A. Tarasov G. V. Shcherbakov V. G. Grebinnik V. N. Duginov A. B. Lazarev V. G. Olshevski S. N. Shilov V. A. Zhukov I. I. Gurevich B. F. Kirillov A. I. Klimov B. A. Nikolski A. V. Pirogov A. N. Ponomarev V. A. Suetin 《Hyperfine Interactions》1991,64(1-4):415-419
The zero field μSR-method has been used to study the magnetism in the disordered magnetic alloy Fe82−xNixCr18 near the three-critical, pointx=25. The dynamic and static local field distributions are analyzed. The difference between spin-glass states obtained either
from the paramagnetic or after the double transition is discussed. 相似文献
8.
P.A. Kuzmin 《Journal of Mathematical Analysis and Applications》2007,330(1):744-750
This note is devoted to construction of the domain of the regular representation of Diff+(S1). We consider a subgroup of diffeomorphism group such that the Malliavin-Shavgulidze measure is quasi-invariant with respect to the left action of the subgroup. The measure appears to be quasi-invariant with respect to the left action of diffeomorphisms with discontinuous second derivative. We derive an expression for quasi-invariance density and obtain an additional PSL(2,R) symmetry breaking term. 相似文献
9.
10.
Phil Diamond Peter Kloeden Victor Kozyakin Alexei Pokrovskii 《Mathematische Nachrichten》1998,191(1):59-81
The finiteness of computer arithmetic can lead to some dramatic differences between the behaviour of a continuous dynamical system and a computer simulation. A thorough rigorous theoretical analysis of what may or what does happen is usually extremely difficult and to date little has been done even in relatively simple contexts. The comparative behaviour of a rotation mapping in the plane and on a uniform lattice in the plane is one such example. Simulations show that the rounding operator applied to a planar rotation mapping more or less preserves the qualitative behaviour of the original mapping, whereas the application of the truncation operator to a planar rotation can lead to quite different dynamical features. In this paper a theoretical justification of the properties of the planar rotation mappings under truncation to a, uniform integer lattice is provided, in particular properties of boundedness and dissipativity are investigated. 相似文献