基于AsP/MoS2异质结的偏振光电探测器

线偏振光的探测能力是评价偏振光电探测器件的重要指标。黑砷磷(AsP)是一种较为稳定的平面内各向异性材料,由于其面内结构各向异性,其对线偏振光较为敏感,在偏振探测领域有着重要的应用潜力。本文介绍了一种基于AsP/MoS2的高度偏振敏感光电探测器。由于AsP各向异性的光吸收、MoS2有效的载流子收集和输运能力以及范德华异质结对暗电流的抑制作用,该光电探测器实现了大于300的电流开关比,0.27 A/W的电流光响应度以及2×10^10 Jones的比探测率。更重要的是,此类光电探测器在638 nm波段实现了高达3.06二向色性比的偏振特性。这些实验结果表明AsP/MoS2异质结构在偏振光电探测领域有着广阔的应用前景。     

低维半导体偏振光探测器研究进展

偏振光探测在遥感成像、环境监测、医疗检测和军事设备等领域都具有很好的应用价值,目前已经有一系列偏振探测和成像产品.随着信息器件进一步小型化、集成化,基于新型低维材料的偏振光探测器可以直接利用材料本征的各向异性对偏振光进行感知,在未来偏振光探测领域有很好的应用前景.很多二维/一维半导体材料,例如:黑磷, ReS_2, GaTe, GeSe, GeAs及ZrS_3等,都具有较强的本征面内各向异性,可以用于高性能偏振光探测器.基于此类低维半导体材料设计的不同结构类型的偏振光探测器已经覆盖了紫外、可见以及红外等多个波段.本文总结了近年来相关领域的研究进展和我们课题组的一些工作.     

Ⅳ-Ⅵ族低维半导体材料与器件研究进展

二维Ⅳ族金属硫属化合物作为二维层状材料的重要组成部分,由于其晶格结构具有较低的对称性且与核心半导体工艺具有很好的兼容性,在电学、光学、磁性等方面具有优异的性能,并且在地球上资源丰富且具有低成本、环保的特性,因此在光电器件领域具有很大的应用潜力.基于本课题组近年来的研究进展,本文首先介绍了二维Ⅳ族金属硫属化合物及相关异质...     

The 2D InSe/WS_2 Heterostructure with Enhanced Optoelectronic Performance in the Visible Region

Two-dimensional(2D)InSe and WS_2 exhibit promising characteristics for optoelectronic applications.However,they both have poor absorption of visible light due to wide bandgaps:2D InSe has high electron mobility but low hole mobility,while 2D WS_2 is on the contrary.We propose a 2D heterostructure composed of their monolayers as a solution to both problems.Our first-principles calculations show that the heterostructure has a type-Ⅱband alignment as expected.Consequently,the bandgap of the heterostructure is reduced to 2.19 eV,which is much smaller than those of the monolayers.The reduction in bandgap leads to a considerable enhancement of the visible-light absorption,such as about fivefold(threefold)increase in comparison to monolayer InSe(WS_2)at the wavelength of 490 nm.Meanwhile,the type-Ⅱ band alignment also facilitates the spatial separation of photogenerated electron-hole pairs;i.e.,electrons(holes)reside preferably in the InSe(WS_2)layer.As a result,the two layers complement each other in carrier mobilities of the heterostructure:the photogenerated electrons and holes inherit the large mobilities from the InSe and WS_2 monolayers,respectively.     

一类含吡咯和吩噻嗪环的n型有机半导体的设计、合成和性质

PBBTZ (6H-吡咯[3,2-b:4,5-b´]双[1,4]苯并吩噻嗪) 是我们刚刚报道的一类高场效应性能p型有机半导体材料。本文用简单的一锅合成法制备了两种三氟甲基取代的 PBBTZ衍生物3a和3b, 用1H NMR, IR, HRMS (EI-TOF), 元素分析等手段进行了表征,并描述和讨论了3b的晶体结构。用UV-Vis 和荧光光谱法研究了它们的光学性质,用循环伏安法研究了电化学性质,用热重分析法研究了热力学性质。研究表明,3a和3b的能隙由光谱最大吸收峰起峰位置估算分别为 2.45和2.48 eV, 溶液具有绿色荧光。3a的LUMO 和HOMO能级分别为-5.73和-3.28 eV,3b的LUMO 和HOMO能级分别为-5.67和-3.19 eV,均比PBBTZ有所下降。低能级使它们具有良好的空气稳定性,并且可能作为有前途的n型有机半导体材料应用于有机电子器件。     

Electronic and optical properties of an intrinsic type-I band alignment ZrS_2/SnS_2 van der Waals heterostructure for optoelectronic devices

The electronic and optical properties of the ZrS_2/SnS_2 van der Waals heterostructure have been investigated.We find out that the formed heterostructure has an intrinsic type-I band alignment. Moreover, the characteristics of optical absorption in the heterostructure can be enhanced to the amount of 106 in the ultraviolet light region. In addition, the tuning electronic properties of ZrS_2/SnS_2 heterostructure are very interesting, due to the transitions from type-I to type-II band alignment that can occur by applying an external electric field.These results suggest that the atomically thin materials ZrS_2/SnS_2 heterostructure will be utilized for flexible optoelectronic applications.     

基于二维材料异质结的光探测器研究进展

二维材料异质结因其特有的层状结构和优异的光响应性质,被认为具有应用于新一代光探测器件的潜力.二维材料家族具有丰富的种类,因其能带带隙范围分布广,光电响应可覆盖从紫外到红外的波谱范围.另外二维材料层间通过范德瓦尔斯力相结合,因此理论上可以利用不同二维材料层间的范德瓦尔斯力相互作用制备出多种性能优异的二维材料异质结.近年来有多种二维材料异质结通过机械堆叠法及CVD生长法被制备出来,且二维材料异质结光探测器在可见光至远红外波段表现出优异的性质.在这样的研究背景之下,本文从二维材料异质结的制备、器件制备与器件性能等几个方面综述了近年来二维材料异质结光探测器的研究进展.