排序方式: 共有9条查询结果,搜索用时 15 毫秒
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Zhengwei Xiong 《中国物理 B》2021,30(12):128201-128201
Size and morphology are critical factors in determining the electrochemical performance of the supercapacitor materials, due to the manifestation of the nanosize effect. Herein, different nanostructures of the CrN material are prepared by the combination of a thermal-nitridation process and a template technique. High-temperature nitridation could not only transform the hexagonal Cr2O3 into cubic CrN, but also keep the template morphology barely unchanged. The obtained CrN nanostructures, including (i) hierarchical microspheres assembled by nanoparticles, (ii) microlayers, and (iii) nanoparticles, are studied for the electrochemical supercapacitor. The CrN microspheres show the best specific capacitance (213.2 F/g), cyclic stability (capacitance retention rate of 96% after 5000 cycles in 1-mol/L KOH solution), high energy density (28.9 Wh/kg), and power density (443.4 W/kg), comparing with the other two nanostructures. Based on the impedance spectroscopy and nitrogen adsorption analysis, it is revealed that the enhancement arised mainly from a high-conductance and specific surface area of CrN microspheres. This work presents a general strategy of fabricating controllable CrN nanostructures to achieve the enhanced supercapacitor performance. 相似文献
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陶瓷作为应用非常广泛的一种材料,其电击穿问题一直是研究的重点和热点.由于击穿过程涉及热、光、电多场耦合效应,目前还没有一个普适的模型能够解释陶瓷击穿问题.针对此问题进行分析,实验中采用脉冲高压发生装置击穿陶瓷,通过对陶瓷击穿过程中等效电阻的研究,揭示了PZT95/5陶瓷样品体击穿和沿面闪络形成过程的异同.结果显示,在两种击穿模式下,陶瓷样品内部均会在40 ns左右形成导电通道,陶瓷等效电阻急剧下降至10~5?量级;然后体击穿与沿面闪络的导电通道以不同的速率继续扩展;电阻减小速率与导电通道上载流子的浓度有关,二者的等效电阻以不同速率减小,直至导电通道达到稳定. 相似文献
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以驻马店幼专五年制学前教育专业物理课程改革为例,基于OBE理念,在调研的基础上重新制定专业针对性强的课程大纲,依托C30教育云平台、智慧教室开展混合式教学,采取“线上学习”+“线下研讨”+“技能展示”+“课程思政”+“创新拓展”的形式反向设计课程,并构建多元化的考核评价体系.这种基于OBE理念,针对高职物理课程的线上线下混合式教学改革实践,可以为高职物理课程改革提供新的思路. 相似文献
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Zhangyang Zhou 《中国物理 B》2021,30(12):126803-126803
Manipulating metal-insulator transitions in strongly correlated materials is of great importance in condensed matter physics, with implications for both fundamental science and technology. Vanadium dioxide (VO2), as an ideal model system, is metallic at high temperatures and shown a typical metal-insulator structural phase transition at 341 K from rutile structure to monoclinic structure. This behavior has been absorbed tons of attention for years. However, how to control this phase transition is still challenging and little studied. Here we demonstrated that to control the Ag nanonet arrays (NAs) in monoclinic VO2(M) could be effective to adjust this metal-insulator transition. With the increase of Ag NAs volume fraction by reducing the template spheres size, the transition temperature (Tc) decreased from 68° to 51°. The mechanism of Tc decrease was revealed as:the carrier density increases through the increase of Ag NAs volume fraction, and more free electrons injected into the VO2 films induced greater absorption energy at the internal nanometal-semiconductor junction. These results supply a new strategy to control the metal-insulator transitions in VO2, which must be instructive for the other strongly correlated materials and important for applications. 相似文献
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目前金属软磁粉芯材料在高频电感等电子元件的应用前景广阔,然而其主要的构成元素属于过渡金属,表面易形成致密的氧化层,影响其软磁性能的调控.为了解决这些问题,本文引入H2/Ar混合气体高温预处理工艺对FeNiMo原粉进行还原,证实了还原性气氛高温处理可以有效地去除材料表面的金属氧化物,增加金属单质的含量,进而显著提升FeNiMo原粉的有效磁导率.对预处理后的FeNiMo粉末进行SiO2绝缘包覆,所获得的FeNiMo/SiO2软磁复合材料表面包覆均匀;与未处理FeNiMo原粉包覆SiO2所形成的软磁复合粉芯相比, H2/Ar混合气体高温预处理后的FeNiMo/SiO2具有更高的有效磁导率、更低的损耗.与同类其他软磁复合粉芯相比,通过H2/Ar混合气体高温预处理工艺和绝缘包覆工艺的协同效应,所制备的FeNiMo/SiO2复合粉芯具有优异的软磁性能.因此经过还原性气氛高温预处理工艺后的绝缘包覆可以更大程度地提升软磁粉芯复合... 相似文献
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Na0.5K0.5NbO3是一种不含铅的新型压电材料。理解该物质在高压下的晶体结构变化,有助于深入认识并提高其材料的稳定性及压电性能。然而目前关于该物质在高压下的相结构演化过程还缺少实验研究。本工作采用基于金刚石对顶砧(DAC)的高压拉曼光谱技术,研究了Na0.5K0.5NbO3的高压拉曼光谱特性与压致相变行为。研究发现Na0.5K0.5NbO3在高压环境下由于NbO6八面体的振动模式发生改变,会依次发生正交相到四方相和四方相到立方相的可逆相变过程,其相变压力分别为4.0~5.5 GPa和5.5~6.4 GPa。 相似文献
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构建论证式教学模式及流程,着力搭建联系物理概念课教学与培养学生科学论证能力之间的“桥梁”,文章从营造论证氛围、显化论证语言、丰富论证资料、提升论证能力4个维度阐述在物理概念课上进行论证式教学的策略. 相似文献
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