KTiOAsO4晶体的铁电畴与位错的多种实验方法研究

利用原子力显微镜,同步辐射X射线形貌术和化学腐蚀光学显微等方法深入研究了KTiOAsO4晶体缺陷中的铁电畴和位错.首次用原子力显微镜给出了用两种腐蚀剂腐蚀过的KTA晶体表面的铁电畴和位错蚀坑的照片及定量信息,如发现铁电畴的明区要高于暗区,且两者的粗糙度明显不同.这为研究各种晶体的生长缺陷开辟了一条新的途径.     

Cs^＋-K^＋ Exchange in Z-Cut KTiOPO4 Crystal Covered with Chromium Masking Layer

Cs^＋-K^＋ ion exchanges are performed on z-cut KTiOPO4 crystals with chromium coating covered. The temperature of ion exchange is 430℃, and the time range from 15min to 30min. The dark mode spectra of the samples are measured by the prism coupling method. The channel structures on the samples are observed by a microscope and the near field pattern of the channel waveguides are measured by the end-fire coupling method. The refractive index of the samples increases and the increments at surface are modulated due to the existence of Cr film. In the region covered by Cr film, the refractive index of the samples at the surface increases dramatically in a shallow layer. The results of energy dispersive x-ray spectra indicate that in the region covered with Cr film, Cr ions participate in the ion exchange process, and enhance the refractive index. The results may provide a possibility that achieves index enhancement and Cr doping synchronically.     

LiNd(PO3)4晶体的热分析研究

对LiNd(PO₃)₄晶体分别在N₂气和空气下进行了TG和DTA热分析研究,给出TG和DTA曲线,讨论了LNP晶体在N₂气和空气下不同的热分解机理.得到分解产物分别为Nd₄(P₂O₇)₃和NdP₂O₇.     

LiNdP4O12晶体的生长缺陷

LiNdP4O12(LNP)晶体是一种新型的激光材料.本文报道了用同步辐射X射线白光形貌术和光学显微法研究由助熔剂籽晶旋转法生长的LNP晶体的生长缺陷,观察到了圆形生长台阶及精细的系列台阶结构,对晶体中的包裹物和位错缺陷等进行了详细的观察描述,还发现了一种比较奇特的腐蚀沟槽,分析了这种腐蚀沟槽的形成机理及各种缺陷的成因和克服办法.     

Optical Planar Waveguides in KTiOPO4 Crystals by MeV Oxygen Ion Implantation

We report on the optical planar waveguide formation in KTiOPO4 crystals by single or double oxygen ion implantation at energies of 2.4-3.0 MeV and doses of 1015 ions/cm^2. The dark-line spectroscopy properties are investigated by a prism-coupling method. With an effective refractive index method, the refractive index profiles of the waveguides are reconstructed. The program code TRIM＇98 （transport of ions in matter） is used to simulate the implantation process of oxygen ions into the KTiOPO4 crystal. It is found that an inherent relationship exists between the nuclear damage and the refractive index changes induced by the ion-beam implantation.     

多用非经典光场产生系统的实验研究

由α-切割KTP晶体组成的半整块非简并光学参量振荡腔，以倍频Nd:YAP激光器作抽运源，可在不同运转条件下获得两类非经典光场.低于振荡阈值，该系统输出最大压缩度为3.7dB的双模正交压缩真空态；高于阈值，产生强度差压缩度为7dB的量子相关孪生光子对.系统能在锁定状态下持续稳定运转半小时以上. 关键词：     

原子吸收光谱法检测市售功能饮料中锌钠钾离子含量——推荐一个仪器分析基础型设计实验

功能饮料是一类具有保健作用的饮品,通过调整饮料中天然营养素的成分和含量,以适应某些特殊人群的营养需求。饮料中成分含量是否达标直接关系到民众的健康生活,也是国家食品质量监测工作的重要一环。基于山东大学化学与化工学院仪器分析实验课程,学生自主设计实验方案,教师审阅指导监督,联系密切关乎健康的实际问题强化和拓展了实验学习的意义和应用价值——借助原子吸收光谱法对市售功能饮料中锌钠钾离子含量进行检测,并与包装上标明的参考离子含量对比,鉴定其是否存在食品质量问题。本实验能充分发挥学生主观能动性,让学生在实践中加强理论知识学习、提高实操能力、深化对原子吸收光谱法的理解和应用。该实验充分体现了理论源于实践、理论指导实践,灵活运用课程中掌握的知识解决实际问题,使学生切身体会到化学与生活密切联系。     

光参量振荡伴生拉曼激光

利用调QNd∶YAG倍频激光泵浦KTP非线性晶体为介质的参量振荡器,产生了608.3nm~903.1nm宽带参量调谐激光,线宽1.4nm,光-光转换效率30%。当泵浦光增强到12mJ时,在参量激光谱线的近傍,长波方向出现了一条新谱线,与参量调谐激光谱线同步移动,谱线间隔随参量激光波长的增加而增加,两条谱线波数(能量)差(720cm-1)是一个定值,这是参量激光激发出斯托克斯拉曼激光典型特征。     

Modal Characterization of a Planar Waveguide in Bismuth Borate Crystal

We report on the fabrication and modal property studies of planar waveguide structure in x-cut bismuth borate biaxial crystal formed by He ion implantation with triple energies. The prism coupling method is used to measure the effective refractive indices of this waveguide. We reconstruct the refractive index distribution of this waveguide by the reflectivity calculation method. Our results indicate that a broadened optical barrier is produced by the multiple He ion implantations. The so-called tunneling effect of the non-stationary mode in this type of barrier waveguide is presented by the well-known finite difference beam propagation method.     

利用同步辐射形貌术研究晶体缺陷的实验方法探讨

利用同步辐射X射线形貌术研究晶体缺陷,是近年来发展起来的一种优良的实验方法,本文在研究LNP等晶体缺陷的同时,对这种实验方法进行了系统的探讨,讨论了散射光的消除,焦距的选择,样品的透明度与厚度,曝光的时间,底片的冲洗等问题,以及在缺陷研究中对晶体衍射的劳厄斑点的选取依据。