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作者用燃烧法制备了8nm-50nm的系列纳米晶Y2O3:Eu3+,利用XRD谱确定了纳米晶的晶体结构及晶粒大小。利用两套由不同波长的激光所激发的拉曼光谱,指认了纳米晶Y2O3:Eu3+的拉曼振动模,研究其拉曼光谱。与传统的拉曼光谱学相比较,光谱呈现出明显的反常,其一,是斯托克斯与相对应的反斯托克斯谱峰波数不相等;其二,随晶粒的减小,拉曼谱有明显的变化,包括谱峰的微移、半高宽的增加,以及谱峰强度比的强烈变化;其三,随着激发波长的变化,光谱也呈现出峰位移动的明显变化。这些反常的散射光谱的变化源于纳米结构的本征缺陷。 相似文献
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利用第一性原理研究了覆盖度分别为1.00, 0.50和0.25 ML时CO分子单层膜在Cu(100)表面的吸附系统. 计算表明CO分子对不稳定. 获得了CO分子单层膜在虚拟Cu(100)表面的原子结构, 以及CO分子单层膜在Cu(100)表面吸附系统的原子结构. 当CO分子单层膜在Cu(100)表面的三个吸附位吸附, 覆盖度为1.00 ML时, 顶位和桥位都稳定, 而空心位不稳定; 覆盖度为0.50和0.25 ML时, 三个吸附位都稳定.比较吸附前后CO分子单层膜的原子结构, 可知CO分子和Cu(100)表面的相互作用强于CO分子单层膜之间的相互作用.
关键词:
CO分子单层膜
自组装
CASTEP
Cu(100) 相似文献
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A theoretical study of the oxygen K-edge near-edge X-ray absorption fine structure of N20/Ir(110) 下载免费PDF全文
A multiple-scattering chtster method is employed to calculate the oxygen K-edge near-edge X-ray absorption fine structure of N20/Ir(110) and its monolayer. Two peaks and one weak resonance appear in both cases. The self- consistent field DV-Xa calculations of the peaks and resonance show that the physical origin of the pre-edge peak x is different from those of the main peak 1 and the other weak resonance al. This setup is intrinsic to the N20 monolayer, owing to the interaction between the neighbouring molecular chains in the monolayer and partly to the adsorbed atomic oxygen, according to both the theoretical and experimental data. 相似文献
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A formula for the threshold energy of a four-level-system laser in Tm^{3+} doped fluoride glass is derived. The formula contains the parameters of the interaction between the ions and the up-conversion rate of the pump-light. It is discussed that the Tb^{3+} ions and the up-conversion pump-light have an influence on the laser performance of Tm^{3+} ions around 1.47μm wavelength. We draw the following two conclusions. (1) The laser threshold descends obviously due to the doping of Tb^{3+} ions, but the descending gradually flattens out with the increase of the content of Tb^{3+} ions. Its suitable content is (1-2)×10^{20}cm^{-3}. (2) When pump-lights both from the up-conversion and from the ground state excite simultaneously the single-doped Tm^{3+} ions, the threshold energy can reduce and the output energy can increase. In this paper, the energy conversion efficiency from the up-conversion pump-light to the output energy of laser is estimated. 相似文献
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A theoretical study of the oxygen K-edge near-edge X-ray absorption fine structure of N2O/Ir(110) 下载免费PDF全文
A multiple-scattering cluster method is employed to calculate the oxygen K-edge near-edge X-ray absorption fine structure of N2O/Ir(110) and its monolayer. Two peaks and one weak resonance appear in both cases. The self-consistent field DV-Xα calculations of the peaks and resonance show that the physical origin of the pre-edge peak x is different from those of the main peak 1 and the other weak resonance σ 1 . This setup is intrinsic to the N2O monolayer, owing to the interaction between the neighbouring molecular chains in the monolayer and partly to the adsorbed atomic oxygen, according to both the theoretical and experimental data. 相似文献
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