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1.
Application of multiple scattered-wave X_α method with overlapping atomic-sphere to ionization potentials is reported for benzene, pyridine, pyrazine, pyrrole and imidazole. The calculated results show that the orbital charges in the intersphere region are non-negative and the energy levels get improvements in orderings.  相似文献   
2.
用无火焰原子吸收光谱测定家兔从肝动脉注射顺氯氨铂前后的血药浓度及在体内分布情况。  相似文献   
3.
仪晓凤  杨环  王义  王璐璐  桑瑞利  徐立 《结构化学》2014,33(11):1697-1702
A new mixed-valence heterometal cluster Mo8VW2VIO26(C5H5N)8·2H2O has been synthesized under solvothermal conditions and characterized by X-ray single-crystal diffraction, IR, UV-vis and XPS spectroscopy. The title compound crystallizes in the triclinic system, space group P1 with a = 11.708(3), b = 12.018(4), c = 13.316(4) , a = 112.184(4), β = 97.844(4), r = 110.043(3)o, V = 1551.9(8) 3 and Z = 1 at 293(2) K. The final full-matrix least-squares refinement converged to R = 0.0414 for 4460 observed unique reflections with I 2σ(I) and w R = 0.1290 for all data(5352) and S = 1.015. In addition, its thermal stability and fluorescent property have also been investigated.  相似文献   
4.
王义  秦茜  桑瑞利  徐立 《结构化学》2014,33(7):995-1000
A new complex K0.5[K(18-crown-6)]1.5Ge9·1.5en(1) which contains unprecedented "up" and "down" chain arrangement of unit [-(Ge-9-K-Ge9)3-] has been prepared by the reaction of K4Ge9 with HgS in ethylenediamine(en) in the presence of 18-crown-6(1,4,7,10,13,16-hexaoxacyclooctadecane), and characterized by X-ray structure analysis. The color of the title crystals(black), which is darker than that of the reported three compounds with chains of germanium clusters, may result from the naked K+ and their interactions with the chain. And the structure differences between 1 and the reported three compounds with chains of germanium have also been discussed.  相似文献   
5.
    
Six-gap resistive plate chamber (MRPC) prototypes with semiconductive glass electrodes (bulk resistivity ~ 10^10Ω·cm) were studied for suitability in time-of-flight (TOF) applications at high rates. These studies were performed using a continuous electron beam of 800 MeV at IHEP and an X-ray machine. Time resolutions of about 100 ps and efficiencies larger than 90% were obtained for flux densities up to 28 kHz/cm^2.  相似文献   
6.
王义  徐南仙 《计算物理》1997,14(6):808-814
采用有限元方法研究了球形弹丸对铝和碳酚醛平板靶冲击,给出了动态响应的理论计算和图形分析结果。  相似文献   
7.
    
The variation in environmental scattering background is a major source of systematic errors in X- ray inspection and measurement systems. As the energy of these photons consisting of environmental scattering background is much lower generally, the Cerenkov detectors having the detection threshold are likely insensitive to them and able to exclude their influence. A thickness measurement experiment is designed to verify the idea by employing a Cerenkov detector and an ionizing chamber for comparison. Furthermore, it is also found that the application of the Cerenkov detectors is helpful to exclude another systematic error from the variation of low energy components in the spectrum incident on the detector volume.  相似文献   
8.
本文介绍了新型kagomé 晶格化合物 Yb3Cu9 (OH)19Cl8 单晶的生长及磁性质研究. 利用水热法制备了高品质的 Yb3Cu9 (OH)19Cl8 单晶,X 射线衍射的精修结果表明,Cu2+ 离子在ab 面内形成kagomé 结构,Yb3+ 离子处在kagomé 六角晶格的中心. 磁化率结果表明 Yb3Cu9 (OH)19Cl8 在温度低至2 K 仍没有磁有序转变, 表现出明显的顺磁行为. 居里-外斯拟合结果显示, 磁性离子间具有强的反铁磁耦合相互作用. 温度低至2 K 的比热曲线上没有明显的磁相变行为的出现, 而是表现出典型的肖特基特征  相似文献   
9.
    
Multi-gap Resistive Plate Chamber (MRPC) is a new generation of gas detector with good timing and spacial resolution, whose technique is widely applied in some recent high energy (nuclear) physics experiments. In this letter, we report a long-strip two-end readout MRPC and its test beam performance. The measurements show that the long-strip performs a transmission line characteristic and the impedance is independent of the length of strip. The MRPC module we developed is presented to gain a timing resolution of -80 ps and a spacial resolution of -6.4 mm. The possible application of the MRPC is also discussed.  相似文献   
10.
使用MP2/6-311G方法得到了四硫富瓦烯自由基正离子二聚体(TTF·^+ -TTF·^+)能量极小点的结构.这显示这种正离子间的吸引作用存在.这种新的吸引作用是望远镜形状的20中心2电子分子间共价π/π键.这种共价π/π键的键能约为-21kcal·mol^-1,它被正离子间的库伦排斥作用掩盖.有负离子围绕的四硫富瓦烯自由基正离子二聚体(TTF·^+ -TTF·^+)体系是稳定的.  相似文献   
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