苦丁茶冬青挥发油成分的GC-MS分析

采用乙醚超声萃取-水蒸气蒸馏方法提取苦丁茶冬青的挥发油，用气相色谱-质谱联用分析，鉴定了挥发油中的57个成分，其中主要成分是醇、醛、酮、醚、脂肪酸、脂肪酸酯及含氧萜类等化合物。     

Quantum reflection of a Bose-Einstein condensate with a dark soliton from a step potential

We study dynamical behaviors of a Bose-Einstein condensate (BEC) containing a dark soliton reflected from potential wells and potential barriers, respectively. The orientation angle of the dark soliton and the width of the potential change play key roles on the reflection probability R_s. Variation of the reflection probability with respect to the orientation angle θ of the dark soliton can be well described by a cosine function R_s~cos[λ(θ-π/2)], where λ is a parameter determined by the width of the potential change. There are two characteristic lengths which determine the reflection properties. The dependence of the reflection probability on the width of the potential change shows distinct characters for potential wells and potential barriers. The length of the dark soliton determines the sensitive width of potential wells, whereas for potential barriers, the decay length of the matter wave in the region of the barrier qualifies the sensitive width of the barrier. The time evolution of the density profiles of the system during the reflection process is studied to disclose the different behaviors of matter waves in the region of the potential variation.     

氨基酸对映体的手性薄层色谱拆分

设计并制备了３,５－二硝基苯甲酰基取代的β－环糊精薄层色谱键合固定相,用于拆分丹磺酰化氨基酸对映体。该键合相合成方法简单,性能稳定,适用于正相和反相液相色谱。以乙腈－１％（ψ）乙酸三乙胺－乙酸为展开系统,８对丹磺酰化氨基酸对映体得到良好分离,对映异构体之间的相对比移植α为１．１８～１．６３。该文对色谱拆分机理及色谱分离条件进行了较详细的讨论。     

一类非线性压缩生成的不变集的局部维数

本文以有界变差原理和有界畸变原理为工具,讨论了满足开集条件,且二次可微的一族递增的非线性压缩映射所产生的不变集的局部维数。     

人卵透明带3基因片断hZ3.3的克隆及其在毕赤酵母中的表达

为了探讨透明带与精子的作用机制,人卵透明带3(human Zona Pellucida 3,hZP3)第19l位氨基酸到319位氨基酸之间的cDNA序列通过PCR方法扩增后,克隆到表达载体pPICZαA上,构建成重组质粒pPICZαA-hZ3．3。该质粒经SacⅠ线性化后电打孔转入Pichia pastoris酵母X-33中,用YPDS Zeocin^ 筛选高拷贝转化子,并用PCR分析鉴定目的基因片断与酵母基因组的整合,阳性转化子用0．5％甲醇诱导,表达目的蛋白。经SDS-PAGE凝胶电泳和Western-blot鉴定分析,结果表明目的基因成功表达,表达产物大小约为37kD。     

Quench Dynamics of Bose–Einstein Condensates in Boxlike Traps

By quenching the interatomic interactions, we investigate the nonequilibrium dynamics of two-dimensional Bose–Einstein condensates in boxlike traps with power-law potential boundaries. We show that ring dark solitons can be excited during the quench dynamics for both concave and convex potentials. The quench’s modulation strength and the steepness of the boundary are two major factors influencing the system’s evolution. In terms of the number of ring dark solitons excited in the condensate, five...     

DM-UKF混沌拟合破译混沌直接序列扩频通信

针对已有混沌直接序列扩频通信系统的破译算法在低扩频因子和较大多径衰落下无法有效破译信息码的问题,提出了一种基于双模型无迹卡尔曼滤波混沌拟合的破译算法.所提算法联合多模型滤波原理,利用信息符号为有限集的特点,针对其不同取值分别建立对应的滤波模型.各模型下滤波器并行工作,利用广义同步系统同时拟合原混沌系统并估计混沌直扩信号,通过估计误差确定最佳匹配滤波模型,从而得到信息符号的估计.进一步通过引入误差控制因子,增大了不同模型下估计误差的距离,不仅有利于信息符号判定,并且减小了噪声和多径衰落对破译结果的影响.理论推导和仿真结果均证明提出的算法优于已有破译算法.     

分歧点的多项式算子

针对在分歧点的计算过程中如何选择合适的扩展系统这一问题,本文通过研究折叠点,音叉式分歧点的多项式算子,利用逐项求导的方式,比较了它们的多项式算子,从而得出一个判断高阶折叠点和音叉点的统一的多项式算子,为解决分歧点计算过程中选择扩展系统的困难创造了条件.     

LD Side-Pumped Passive Mode-Locked TEM_00 Nd:YAG Laser Based on SESAM

We report an LD side-pumped continuous-wave passive mode-locked Nd：YAG laser with a Z-type folded cavity based on a semiconductor saturable absorber mirror （SESAM）. The average output power 2.95 W of mode-locked laser with electro-optical conversion efficiency of 1.3% and high beam quality （Mx2=1.25 and My2=1.22） is achieved. The repetition rate of mode-locked pulse of 88 MHz with pulse energy of 34 nJ is obtained.     

超高效液相色谱-串联质谱法同时测定保健食品中丙磺舒、别嘌醇和苯溴马隆

建立了基于QuEChERS前处理的超高效液相色谱-串联质谱（UPLC-MS/MS）同时测定抗痛风类保健食品中别嘌醇、丙磺舒和苯溴马隆3种药物的检测方法。样品经含0.1%（v/v）氨水的乙腈溶液超声提取后，采用乙二胺-N-丙基硅烷（PSA）和十八烷基键合硅胶（C₁₈）吸附剂净化，用C₁₈色谱柱进行分离，0.1%（v/v）甲酸水溶液和甲醇为流动相进行梯度洗脱，采用电喷雾电离源、正负离子切换模式和多反应监测（MRM）模式检测。结果表明，别嘌醇、丙磺舒和苯溴马隆的检出限分别为5、25和25 μg/kg，定量限分别为17、80和80 μg/kg。抗痛风类保健食品中3种药物的平均加标回收率为76.8%~116.6%，相对标准偏差（RSD）为2.7%~14.6%。应用该法对68批次保健食品进行分析，其中1批次样品检出别嘌醇药物。该法操作简单，灵敏度高，可用于抗痛风类保健食品中别嘌醇、丙磺舒和苯溴马隆的测定。