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排序方式: 共有62条查询结果,搜索用时 15 毫秒
1.
Photoluminescence of green nanophosphors Sr2MgSi2O7 doped with Tb3+ under 374-nm excitation 下载免费PDF全文
A series of Sr2MgSi2O7:Tb3+ nanophosphors is prepared using a high-temperature solid-state reaction. The x-ray diffraction patterns show that the crystal structure of the sample is not significantly affected by Tb3+ ions. However, the images of the scanning electron microscope illustrate that the average size of nanoparticles becomes larger with the increase of Tb3+ concentration. Unlike earlier investigations on down-conversion emission of Tb3+ ion excited by deep ultraviolet light, in this work, the photoluminescence characteristics of Sr2MgSi2O7 nanophosphors doped with different Tb3+ concentrations are analyzed under 374-nm excitations. The intense green emission at 545 nm is observed at an optimal doping concentration of 1.6 mol%. The main reason for the concentration quenching is due to the electric dipole-electric dipole interaction among Tb3+ ions. 相似文献
2.
Green and red up-conversion emissions and thermometric application of Er^3+-doped silicate glass 总被引:2,自引:0,他引:2 下载免费PDF全文
The green and red up-conversion emissions centred at about 534, 549 and 663 nm of wavelength, corresponding respectively to the ^2H11/2 → ^4I15/2, ^4S3/2 → ^4I15/2 and ^4F9/2 → ^4I15/2 transitions of Er^3+ ions, have been observed for the Er^3+-doped silicate glass excited by a 978 nm semiconductor laser beam. Excitation power dependent behaviour of the up-conversion emission intensity indicates that a two-photon absorption up-conversion process is responsible for the green and red up-conversion emissions. The temperature dependence of the green up-conversion emissions is also studied in a temperature range of 296-673 K, which shows that Er^3+-doped silicate glass can be used as a sensor in high-temperature measurement. 相似文献
3.
本文研究Bi系超导体高Tc(2223)相的形成机制。提出Bi系氧化物超导体高Tc相的形成过程是:首先Sr-Ca-Cu氧化物(Ca_(0.85)Sr_(0.15)CuO_2)与低Tc(2212)相反应形成高Tc相的核,然后样品内2223相核通过象结晶学中晶体生长那样的方式长大成2223相晶粒。2223相成核过程中Sr-Ca-Cu氧化物的形成途径有两条:一条是通过固相反应从Ca_2CuO_3和SrCaCu_5O_8的平衡中形成;另一条是通过液相反应从2212相,Ca_2PbO_4和CuO之间的反应直接形成。固相反应的速度远小于液相反应的速度,从而2223相核的形成速度在液相反应下得到加快。通过高Tc相的形成机制,提出Pb对Bi系超导体高Tc相形成的作用是:它只加速2223相的成核,而对2223相的成长不起作用。最后利用2223相形成机制,烧制出具有织构的样品。 相似文献
4.
5.
Er^3 -doped Al2O3 films were deposited on silicon substrates by reactive closed-field unbalanced magnetron sput-tering. The process parameters, such as target bias voltage, substrate bias voltage, O2 gas flows, sputtering gas pressure, were studied. The 1.53μm photoluminescence characteristics from Er^3 were measured. The relations among the PL peak intensity, annealing temperatures, and pump power were experimentally investigated. 相似文献
6.
利用高温烧结法制备了铕/铋铕共掺硼硅酸盐玻璃系列样品,测量了样品的激发光谱、发射光谱和声子边带谱,利用Eu3+离子作为探针进一步研究了敏化剂Bi3+的掺入对Eu3+发光的影响.结果表明:本文制作的玻璃样品的电子-声子耦合系数比以往报道过的硼铅等玻璃材料的值都要小,但在硼硅酸盐玻璃中掺入Bi3+会使Eu3+的无辐射跃迁概率增加;Bi3+对Eu3+有敏化作用,Bi3+的掺入使材料的共价性增强,对称性降低,这又使得Eu3+的发光整体变强.所以,在硼硅酸盐玻璃体系中,Eu3+发光的增强不仅仅是由于Bi3+对Eu3+的能量传递,而是以上各因素综合作用的结果. 相似文献
7.
Up-conversion photoluminescence characteristics of Yb3+:Er3+:Tm3+ co-doped borosilicate glasses 下载免费PDF全文
Yb3+:Er3+:Tm3+ co-doped borosilicate glasses are prepared.Their strong up-conversion photoluminescence spectra in a range from ultra-violet to near-infrared,which are excited by a 978-nm laser diode,are measured,and the mechanisms of energy transfer among Yb3+,Er3+ and Tm3+ ions are discussed.The results show that there is an unexpected wavelength at 900-nm emission from Yb3+ Stark splitting levels to pump Tm3+ ions and there exists an optimum pump power.The concentration of the Tm3+ dopant gives rise to a prominent effect on the intensity of visible and near-infrared emissions for the Yb3+:Er3+:Tm3+ co-doped borosilicate glasses. 相似文献
8.
Er~(3+)∶Yb~(3+)∶Tm~(3+)共掺硼硅酸盐玻璃光致发光温度特性和能级劈裂 总被引:1,自引:0,他引:1
高温固相烧结法制备了Er^3+:Yb^3+:Tm^3+共掺硼硅酸盐玻璃.在978nm半导体激光器抽运下,测量了样品在300~573K下光致发光谱强度随温度的变化,讨论了室温时上转换绿光和红光等波段的光谱劈裂.分析了Er^3+:Yb^3+和Tm^3+之间的能量传递机制.研究结果表明,当温度升高时,Er^3+:Yb^3+:Tm^3+共掺硼硅酸盐玻璃的481nm蓝光、517和534nm绿光、以及657nm红光等光致发光强度单调下降,在490K时几乎消失.但900nm左右的近红外光谱则随温度的升高而持续增强,而且其中心波长向短波方向移动.在室温时,光谱劈裂明显,高温时劈裂逐渐消失. 相似文献
9.
Intense up-conversion emissions of Yb3+/Dy3+ co-doped Al2O3 nanopowders prepared by non-aqueous sol—gel method 下载免费PDF全文
Yb3+/Dy3+ co-doped Al2O3 nanopowders have been prepared by the non-aqueous sol-gel method and their up-
conversion photoluminescence spectra are measured under excitation by 980-nm semiconductor laser. The results show
that there are comparatively abundant spectra of up-conversion emissions centered at 378, 408, 527 and 543, and 663
nm, corresponding to 4G9/2 → 6H13/2, 4G9/2 → 6H11/2, 4I15/2 → 6H13/2, and 4F9/2 → 6H11/2 transitions of Dy3+,
respectively. Two-photon and three-photon processes are involved in ultraviolet, violet, green, and red up-conversion
emissions. The energy transition between Yb3+ and Dy3+ is discussed. 相似文献
10.