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激光诱导玻璃内部金纳米颗粒的析出及光谱 总被引:4,自引:0,他引:4
使用钛宝石飞秒激光引发和热处理相结合,实现了在含有金离子的硅酸盐玻璃内部,有空间选择性地析出金纳米颗粒。对吸收光谱的研究表明,随着热处理温度的升高,吸收峰强度增大且红移;随着激光功率密度的增大,金纳米颗粒也增大。在特定的激光和热处理条件作用下,可以在玻璃内部有空间选择性的使金离子还原后聚集,形成金纳米颗粒,具有量子尺寸效应。改变激光功率和热处理温度可以控制所析出的金属纳米粒子的尺寸,从而实现多色显示,飞秒激光诱导金纳米颗粒具有稳定性,颜色具有持久性。 相似文献
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Near Infrared Broadband Emission from Bismuth-Dysprosium Codoped Chalcohalide Glasses 总被引:1,自引:0,他引:1
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We investigate the broadband infrared emission of bismuth doped and bismuth/dysprosium codoped chalcohalide glasses. It is found that the bismuth/dysprosium codoping can drastically enhance the f/uorescence as compared with either bismuth or dysprosium doped glasses. Meanwhile, the full width at half maximum of bismuth/dysprosium codoped glasses is over 170 nm, which is the largest value among all the reported rare-earth doped chalcohalide g/asses. An ideal way for energy consumption between bismuth and dysprosium ions is supposed. Such improved gain spectra of both bismuth and dysprosium ions may have potential applications in developing broadband fibre amplifiers. 相似文献
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Femtosecond laser-induced long-lasting phosphorescence in Pr^3+-doped ZnO-B2O3-SiO2 glass 总被引:1,自引:0,他引:1
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This paper studies the phenomenon of long-lasting phosphorescence induced by a femtosecond laser in Pr3 -doped ZnO-B2O3-SiO2 glass. With the glass irradiated by a focused femtosecond laser for a short time, the emission of strong reddish long-lasting phosphorescence from the irradiated part of the glass can be observed. The emission peaks are located at 495 and 603 nm in wavelength, showing that the long-lasting phosphorescence originates from the emission of Pr^3 . The intensity of the phosphorescence decreases in inverse proportion to time after the removal of the laser. By analysing the absorption and electron spin resonance spectra of the glass, we find that colour-centres are induced in the glass matrix after the irradiation of the femtosecond laser. A possible mechanism has been provided to account for the generation of long-lasting phosphorescence. 相似文献
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