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1.
芳香酮与芳香醛及芳香胺的Mannich反应 总被引:6,自引:0,他引:6
醛、酮与芳香醛及芳香胺的 Mannich 反应,文献[1]曾报道在 HCl-EtOH 溶液中苯乙酮及甲醛与芳香胺的 Mannich 反应。本文在此基 相似文献
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A new quasi-one-dimensional organic ferromagnet model is proposed. Magnon excitations for finite and infinite on-site repulsion of electrons on main carbon chain are investigated. It is found that the lowest branch of spectrum preserves the characteristics of the ferromagnetic magnon. It is also shown that with increasing of the on-site repulsion energy, the itinerant π-electrons become tightly localized. 相似文献
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First-principles study on the electronic structure and optical properties of T12Cd2(SO4)3 and Rb2Cd2(SO4)3 下载免费PDF全文
With the help of ab initio full-potential linearized augmented plane wave (FPLAPW) method, calculating the electronic structure and linear optical properties is carried out for XCd2(SO4)3 (X =Tl, Rb). The results show that Tl2Cd2(SO4)3 (TlCdS) has a larger band gap than Rb2Cd2(SO4)3 (RbCdS) and the energy bands for RbCdS are more dispersive than those of TlCdS. From their partial densities of states (PDOS), we have observed that the hybridization between S ionic 2p and O atomic 2p orbitals forms SO4 ionic groups. The remarkable difference between RbCdS and TlCdS is, however, the degree of hybridization between cation (Tl and Rb) and its surrounding oxygen atoms. In the view of quantum chemistry, the strong p-d hybridization indicates the existence of their cation ionic bonds (Cd-O, Rb-O, and Tl-O). The calculations of TlCdS and RbCdS show their optical properties to be less anisotropic. Their anisotropies in the optical properties mainly occur in a low photon energy region of 5-16 eV. 相似文献
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First-principle calculations are performed to study the infrared optical and electronic properties of the tetragonal CaTiO3. We find that dielectric function and reflectivity exhibit a new single-peak infrared spectrum. It is shown that strong orbital hybridization can form the dipole distribution of covalent bonds (Ti-O1 and Ti-O2)and can result in anomalous optical behaviour. The tetragonal structure that determines the dipole configuration and leads to the optical dipole-dipole transition forbidden is therefore realized to be vital to cause such optical phenomena with the insulator feature. 相似文献
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The F-expansion technique and the homogeneous nonlinear balance principle have been applied for solving a general (19-1)-dimensional nonlinear Schrodinger equation (NLSE) with varying coetficients and a harmonic potential. A family of (1+1)D spatial solitons has been obtained. The evolution features of exact solutions have been investigated. 相似文献
7.
Effects of electron temperature on dielectric function and localization of laser beams in underdense collisional plasma 下载免费PDF全文
Effects of electron temperature on dielectric function and localization of laser beams in underdense collisional plasmas are investigated. Simulation results show that the electron temperature has a strong effect on the dielectric constant and the laser beam localization. It is observed that due to the influence of the electron temperature, the dielectric function presents some interesting and complicated nonlinear variations, and gives rise to the laser beam localization. Moreover, the amplitudes of the beam width and the beam intensity are subjected to continuously oscillatory variation in the region of localization. In addition, the effects of several parameters on the dielectric function and the beam localization are discussed. 相似文献
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对螺旋型旋风分离器进行了两相流场的三维数值模拟.气体流场通过求解三维N-S方程得到,湍流模型采用了雷诺应力模型.计算结果表明,旋风分离器内部的流场分为两部分:螺旋通道内比较稳定的流场和筒体中心区域的复合涡结构流场.对颗粒运动轨迹的计算表明,颗粒在入口处的初始位置对颗粒分离有比较显著的影响.同时得到了不同入口速度下颗粒的分级效率曲线,并给出了气体流量对旋风分离器性能的影响,结果显示:气体流量的增加会提高分离效率,但同时导致压力损失的急剧增加. 相似文献
9.
A new combination Monte Carlo (MC) technique of the classical Metropolis algorithm and the Swendsen Wang cluster algorithm is proposed. Upon application of the MC technique, the thermodynamic properties of a generalized two-dimensional XY model with chiral Dzyaloshinski-Moriya (DM) interactions are simulated for various DM interactions. The specific heat, order parameter and the integrated correlation time are simulated, We find that there exists a high-temperature Kosterlitz-Thouless-type phase transition related to strong DM spin ehiralities. As the DM strength increases the critical temperature of the Kosterlitz-Thouless phase transition increases, It is shown that the combination algorithm is faster than the Metropolis algorithms. 相似文献
10.
With the help of the decimation ansatz of the renormlization group, the dependence of critical temperature on a transverse magnetic field is calculated analytically for a quasi-one-dimensional disordered superconductor model, based on the de Gennes-Skal-Shklovskii (dGSS) picture of the large cluster in a percolation system. Our results are in good agreement with those given by Halley's scaling theory. 相似文献