ROOM TEMPERATURE LIGHT-THERMO-DETECTOR MADE OF HIGH-Tc SUPERCONDUCTOR

Based on the anisotropic Seebeck tensor coefficients, a light-thermo-radiation detector made of high-T_c superconductor (YBa₂Cu₃O_7-δ) was fabricated, which can function at room temperature. The induced voltaic signals at various modulation frequencies for radiation from He-Ne laser and from a 500 K black body were measured. The noise ratio for detecting He-Ne laser radiation and the D^* for black body were evaluated. Compared with bolometer made of high-T_c superconductor which functions at liquid nitrogen, and with pyroelectric detector, it was found that the advantages of this new device are that the device can work at room temperature with very low noise and very fast response. Although having a lower D^* value than that of bolometer for the present device construction, we point out the possibility and the direction for improving the D^* value, hence the promising prospect of this kind of device.     

两个多胺铜配合物的合成，晶体结构以及DNA切割活性

本文以配体N,N′-二(3-氨丙基)-4-甲氧基苄胺(amba)与4,4′-联吡啶,铜盐反应合成了两种多胺Cu(Ⅱ)配合物[Cu(amba)Cl2](1)和[Cu(4,4′-bipy)(amba)(ClO4)]ClO4(2),通过红外光谱、质谱和X-射线单晶衍射对其结构进行了表征。利用紫外吸收光谱、分子荧光,电化学以及粘度试验研究了配合物与小牛胸腺DNA(CT-DNA)的相互作用方式。通过紫外吸收光谱得到配合物1和2与DNA的结合常数Kb分别为1.3×104 mol-1.L和1.7×104 mol-1.L,荧光光谱得到配合物1和2的荧光淬灭常数分别为1.04×103mol-1.L和1.81×103 mol-1.L,表明了配合物1和2与CT-DNA结合方式均为静电模式。凝胶电泳实验的结果表明配合物对pBR322 DNA的切割均为水解切割。     

用308nm准分子激光对几种卷烟用纸打标的研究

激光打标由于具有快速、精度高及非接触等优点，是激光在工业领域的又一应用。准分子激光是一种大功率高重复率的紫外激光器，与ＣＯ２、ＹＡＧ等红外激光相比，一般具有打标效率高、热效应小、图案更精密等优点。近年来国内外均对准分子激光打标进行了一些研究，主要集中在对金属、高分子聚合物及陶瓷等硬脆材料的打标的研究。本文研究了用３０８ｎｍ准分子激光对几种卷烟用纸打标。用适当能量密度的３０８ｎｍ准分子激光对印有数种颜色的烟盒纸、过滤嘴纸打标，获得了清晰可见的图案标记。分析了该打标过程的作用机理，通过实验得出了对几种不同的卷烟用纸打标的能量密度阈值条件及优化条件。     

308nm激光作用下V2O5非晶薄膜的变异

研究了在308nm准分子激光辐照下，V₂O₅非晶薄膜性质的变化-利用X射线衍射、X射线光电子能谱及扫描电子显微镜等多种测试方法进行了分析比较，确定V₂O₅非晶薄膜性质的变化是由于高功率密度的准分子激光作用，造成V₂O₅薄膜的快速升温熔化和快速冷凝重构，使其中的氧产生缺位，引起化学配比偏离所致- 关键词：     

TIME-RESOLVED PHOTOLUMINESCENCE OF SINTERED ZnO CERAMICS

The time-resolved photoluminescence (TRPL) of sintered ZnO ceramics was measured at low temperatures. A broad luminescence band was observed in the visible region. The TRPL experiment shows that photoluminescence decay behaviour can be depicted as t^-n(r). The decay rate n(r) and lifetime are wavelength dependent, and the former varies exponentially with wavelength. The power-lowering behaviour of the luminescence intensity indicates that the luminescence band originates from the recombination of donor-acceptor pairs.     

准分子激光作用下二氧化钛的表面变性

适当能量密度的准分子激光作用于二氧化钛时，电导性能发生了显著的变化，室温下从原来的绝缘体转变为半导体，同时表面颜色也发生了变化．利用X射线衍射、X射线光电子能谱及显微分析等多种测试方法进行了分析、比较，确定了该过程是由于短脉冲的准分子激光作用，造成了二氧化钛的快速升温熔化和快速冷凝重构，导致氧的缺位，引起了化学配比偏离．用热传导方程对能量密度阈值进行了近似估算，结果与实验基本相符 关键词：     

准分子激光激发的快速光谱分析

本文介绍了采用准分子激光作为激发源，结合光学多道分析仪（ＯＭＡ）的并行检测及同时谱扩展技术，自编数据采集软件、对中低合金钢样进行采谱并给出１５０ｎｍ同时谱采集结果。     

ROOM TEMPERATURE LIGHT-THERMO-DETECTOR MADE OF HIGH-Tc SUPERCONDUCTOR

Based on the anisotropic Seebeck tensor coefficients, a light-thermo-radiation detector made of high-T_c superconductor (YBa₂Cu₃O_7-δ) was fabricated, which can function at room temperature. The induced voltaic signals at various modulation frequencies for radiation from He-Ne laser and from a 500 K black body were measured. The noise ratio for detecting He-Ne laser radiation and the D^* for black body were evaluated. Compared with bolometer made of high-T_c superconductor which functions at liquid nitrogen, and with pyroelectric detector, it was found that the advantages of this new device are that the device can work at room temperature with very low noise and very fast response. Although having a lower D^* value than that of bolometer for the present device construction, we point out the possibility and the direction for improving the D^* value, hence the promising prospect of this kind of device.     

一种双光路单探头吸收光谱同时测量方法

本文介绍一种带源补偿的吸收光谱测量方法，利用锁相放大器选频放大和相干接收的特点，和双光路分光，由单探头同时接收源光强和透射光强。