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1.
2.
Jnos Szanyi Ja Hun Kwak Sarah Burton Jose A. Rodriguez Charles H.F. Peden 《Journal of Electron Spectroscopy and Related Phenomena》2006,150(2-3):164-170
Adsorbed ionic NOx species formed upon the interaction of NO2 with dehydrated or hydrated Na- and Ba-Y, FAU zeolites were characterized using FT-IR/TPD, solid state NMR, and XANES techniques. NO2 disproportionates on both dehydrated catalyst materials forming NO+ and NO3− species. These ionic species are stabilized by their interactions with the negatively charged zeolite framework and the charge compensating cations (Na+ and Ba2+), respectively. Although the nature of the adsorbed NOx species formed on the two catalysts is similar, their thermal stabilities are strongly dependent on the charge compensating cations. In the presence of water in the channels of these zeolite materials new paths open for reactions between NO+ and H2O, and NO2 and H2O, resulting in significant changes in the adsorbed ionic species observed. These combined spectroscopic investigations afforded the understanding of the interactions between water and NO2 on these zeolite catalysts. 相似文献
3.
We study dynamic self-reconfiguration of modular metamorphic systems. We guarantee the feasibility of motion planning in a
rectangular model consisting of square modules that are allowed to slide along or rotate about one another. That is, we show
that any two connected configurations of the same number of modules can be transformed into each other by a sequence of moves
so that all intermediate configurations are connected. This settles a conjecture formulated in [6]. 相似文献
4.
5.
A quick sample preparation method was used for the determination of sulphur and trace metals in oil and oily products by the ICP with a minitorch. Stable aqueous emulsions of oils and oil products were made by using two kinds of emulsifiers (one with low sulphur content, the other sulfonated). Aqueous standard solutions can be used for the preparation of calibration solutions. The contents of S, Al, Cr, Cu, Fe, Mg, Ni and Pb in aqueous emulsions were determined and the results were in good agreement with the composition of oil standard solutions used for control analysis procedure. 相似文献
6.
Let F denote a family of pairwise disjoint convex sets in the plane. F is said to be in convex position if none of its members is contained in the convex hull of the union of the others. For any fixed k≥ 3 , we estimate P
k
(n) , the maximum size of a family F with the property that any k members of F are in convex position, but no n are. In particular, for k=3 , we improve the triply exponential upper bound of T. Bisztriczky and G. Fejes Tóth by showing that P
3
(n) < 16
n
.
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Received March 27, 1997, and in revised form July 10, 1997. 相似文献
7.
János Komlós 《Order》1990,7(2):107-113
Using Ramsey theory, we establish the following pigeon-hole type principle: From a large number of random variables (functions, vectors, etc.) one can always select two, X and Y, such that P(X < Y) 1/2. We apply the principle for a poset problem. 相似文献
8.
We give an asymptotically sharp estimate for the error term of the maximum number of unit distances determined byn points in
d, d4. We also give asymptotically tight upper bounds on the total number of occurrences of the favourite distances fromn points in
d, d4. Related results are proved for distances determined byn disjoint compact convex sets in 2.At the time this paper was written, both authors were visiting the Technion — Israel Institute of Technology. 相似文献
9.
Summary Motivated by different mean value properties, the functional equationsf(x) – f(y)/x–y=[(x, y)], (i)xf(y) – yf(x)/x–y=[(x, y)] (ii) (x y) are completely solved when, are arithmetic, geometric or harmonic means andx, y elements of proper real intervals. In view of a duality between (i) and (ii), three of the results are consequences of other three.The equation (ii) is also solved when is a (strictly monotonic) quasiarithmetic mean while the real interval contains 0 and when is the arithmetic mean while the domain is a field of characteristic different from 2 and 3. (A result similar to the latter has been proved previously for (i).) 相似文献
10.
János?W?lfling Angéla?Magyar Gyula?SchneiderEmail author 《Monatshefte für Chemie / Chemical Monthly》2003,134(10):1387-1393
Summary. A new synthetic route was developed for the preparation of trans-3-hydroxy-16,17-seco-pregna-5,17(20)-dien-16-al, using Grob fragmentation as the key step. This seco-steroid contains a formyl group and an unsaturated side-chain in a sterically favourable position, and is therefore a promising starting material for the synthesis of novel condensed steroid heterocycles.Received March 22, 2003; accepted April 22, 2003
Published online September 25, 2003 相似文献