In the present research, magnesium aluminate spinel was prepared as catalyst support using a novel, facile, and efficient mechanochemical method. The Co-promoted catalysts with 20 wt.% of Ni were fabricated using an impregnation route and the samples were analyzed by the X-ray diffraction (XRD), N2 adsorption/desorption (BET), temperature-programmed reduction and desorption (H2-TPR and O2-TPD), and field emission scanning electron microscopy (FESEM) tests. The results confirmed that all samples have a mesoporous structure with a high specific surface area and the presence of cobalt caused complete CH4 oxidation at low temperatures, and no side reactions were observed. The results indicated that the 3%Co-20%Ni/MgAl2O4 catalyst was the optimal sample among the prepared catalysts, owing to the improvement of reduction features and oxygen mobility. The 50 and 90% of methane conversion was obtained at 530 and 600 °C, respectively. Also, the influence of calcination temperature, GHSV, and feed ratio was determined on the catalytic activity. The obtained outcomes revealed that the calcination temperature has a significant effect on the textural properties and catalytic efficiency. The sample calcined at 700 °C showed the weakest performance, which was related to the sintering of particles at high temperatures. The catalytic stability showed that the 3%Co-20%Ni/MgAl2O4 has acceptable stability during 600 min time of reaction.
Journal of Analytical Chemistry - The present study reports the development of a magnetic polyethylene glycol nanocomposite based on graphite reinforcement carbon paste electrode for the sensitive... 相似文献
Journal of Thermal Analysis and Calorimetry - Artificial neural network/kriging interpolation method optimization method which is evaluated concerned the hybrid nanofluid composed of iron oxide... 相似文献
We demonstrate a three orders of magnitude increase and stability in the backscattered fluorescence signal from nitrogen molecules
by terawatt femtosecond laser pulse induced air filaments using a new method. The method is based on squeezing the initial
beam diameter using a telescope. The effect of laser shot-to-shot fluctuations was included in numerical simulations by a
random distribution of the initial intensity in both squeezed and non-squeezed beams. Statistical processing of the simulation
results shows that the average diameter of plasma channels as well as the total amount of free electrons generated in a bunch
of multiple filaments in air is larger in the squeezed beam. Shot-to-shot stability of the simulated plasma density increases
in the squeezed beam. The change of this plasma density with propagation distance is in good qualitative agreement with the
change of the range-corrected nitrogen fluorescence signal with distance.
PACS 42.65.Jx; 42.60.Jf; 42.68.Ay; 42.68.Wt 相似文献
A new series of potent uridine phosphorylase inhibitors have been prepared from barbituric acid. Among them, 1-[(2-hydroxyethoxy)methyl]-5-)(m--benzyloxy)benzylbarbituric acid ( 37 , BBBA) is the most promising having a Ki value of 1.1 ± 0.2 nM with uridine phosphorylase from human liver. The new inhibitors are easily synthesized and are better inhibitors of human uridine phosphorylase than their uracil counterparts. 相似文献
Ferroelectric thin films form an equilibrium domain structure compatible with their respective crystallographic symmetry. In tetragonal (111) PZT, 90° domains prevail; in (pseudo-tetragonal) (100) SBT both 90° and 180° domains are present. The size of 90° domains has been measured for e.g., PZT as slabs of 15 nm width. Domain size is a result of stress minimization in the film during the paraelectric (PE) → ferroelectric (FE) transition. A precise and regular domain pattern for (111) PZT and (100) SBT films has been investigated in detail by TMSFM. Single domains can be addressed mechanically with the tip of an AFM. Such single domain switching corresponds to a data storage density of 200 Gbit/inch2. Applications of ferroelectric and high- paraelectric materials for e.g., non-volatile data storage replacing DRAM devices or as sensors in infrared cameras are increasingly becoming popular. 相似文献