全文获取类型
收费全文 | 2738篇 |
免费 | 65篇 |
国内免费 | 13篇 |
专业分类
化学 | 1748篇 |
晶体学 | 95篇 |
力学 | 58篇 |
数学 | 166篇 |
物理学 | 749篇 |
出版年
2023年 | 20篇 |
2022年 | 42篇 |
2021年 | 44篇 |
2020年 | 58篇 |
2019年 | 65篇 |
2018年 | 51篇 |
2017年 | 60篇 |
2016年 | 89篇 |
2015年 | 61篇 |
2014年 | 129篇 |
2013年 | 214篇 |
2012年 | 163篇 |
2011年 | 208篇 |
2010年 | 102篇 |
2009年 | 117篇 |
2008年 | 140篇 |
2007年 | 140篇 |
2006年 | 124篇 |
2005年 | 87篇 |
2004年 | 92篇 |
2003年 | 73篇 |
2002年 | 75篇 |
2001年 | 36篇 |
2000年 | 26篇 |
1999年 | 18篇 |
1998年 | 19篇 |
1997年 | 20篇 |
1996年 | 18篇 |
1995年 | 18篇 |
1994年 | 20篇 |
1993年 | 20篇 |
1992年 | 30篇 |
1991年 | 18篇 |
1990年 | 22篇 |
1989年 | 20篇 |
1988年 | 18篇 |
1987年 | 14篇 |
1986年 | 20篇 |
1985年 | 26篇 |
1984年 | 24篇 |
1983年 | 25篇 |
1982年 | 18篇 |
1981年 | 20篇 |
1980年 | 29篇 |
1979年 | 25篇 |
1978年 | 20篇 |
1977年 | 19篇 |
1976年 | 11篇 |
1975年 | 15篇 |
1973年 | 12篇 |
排序方式: 共有2816条查询结果,搜索用时 31 毫秒
1.
Joshi Rachna 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2022,76(2):1-8
The European Physical Journal D - We investigate the two-color two-photon K-shell ionization of neutral atoms based on the relativistic second-order perturbation theory and independent particle... 相似文献
2.
Eco‐friendly ionic liquid assisted capillary electrophoresis and α‐acid glycoprotein‐assisted liquid chromatography for simultaneous determination of anticancer drugs in human fluids 下载免费PDF全文
Deia Abd El‐Hady Hassan M. Albishri Rajesh Rengarajan 《Biomedical chromatography : BMC》2015,29(6):925-934
In the current work, two eco‐friendly analytical methods based on capillary electrophoresis (CE) and reversed phase liquid chromatography (RPLC) were developed for simultaneous determination of the most commonly used anticancer drugs for Hodgkin's disease: methotrexate (MTX), vinblastine, chlorambucil and dacarbazine. A background electrolyte (BGE) of 12.5 mmol/L phosphate buffer at pH 7.4 and 0.1 µmol/L 1‐butyl‐3‐methyl imidazolium bromide (BMImBr) ionic liquid (IL) was used for CE measurements at 250 nm detection wavelength, 20 kV applied voltage and 25 °C. The rinsing protocol was significantly improved to reduce the adsorption of IL on the interior surface of capillary. Moreover, RPLC method was developed on α‐1‐acid glycoprotein (AGP) column. Mobile phase was 10 mmol/L phosphate buffer at pH 6.0 (100% v/v) and flow rate at 0.1 mL/min. As AGP is a chiral column, it was successfully separated l ‐MTX from its enantiomer impurity d ‐MTX. Good linearity of quantitative analysis was achieved with coefficients of determinations (r2) >0.995. The stability of drugs measurements was investigated with adequate recoveries up to 24 h storage time under ambient temperature. The limits of detection were <50 and 90 ng/mL by CE and RPLC, respectively. The using of short‐chain IL as an additive in BGE achieved 600‐fold sensitivity enhancement compared with conventional Capillary Zone Electrophoresis (CZE). Therefore, for the first time, the proposed methods were successfully applied to determine simultaneously the analytes in human plasma and urine samples at clinically relevant concentrations with fast and simple pretreatments. Developed IL‐assisted CE and RPLC methods were also applied to measure MTX levels in patients’ samples over time. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
3.
4.
An attempt is made to find out the suitable entrainment and exit boundary conditions in laminar flow situations. Streamfunction vorticity formulation of the Navier–Stokes equations are solved by ADI method. Two‐dimensional laminar plane wall jet flow is used to test different forms of the boundary conditions. Results are compared with the experimental and similarity solution and the proper boundary condition is suggested. The Kind 1 boundary condition is recommended. It consists of zero first derivative condition for velocity variable and for streamfunction equation, mixed derivative at the entrainment and exit boundaries. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
5.
B Ramachandra Reddy P Radhika J Rajesh Kumar D Neela Priya K Rajgopal 《Analytical sciences》2004,20(2):345-349
Cyanex 923 has been proposed as a sensitive analytical reagent for the direct extractive spectrophotometric determination of cobalt(II). Cobalt(II) forms a blue-colored complex with Cyanex 923 in the organic phase. The maximum absorbance of the complex is measured at 635 nm. Beer's law was obeyed in the range 58.9 - 589.0 microg of cobalt. The molar absorptivitiy and Sandell's sensitivity of the complex was calculated to be 6.79 x 10920 l mol(-1) cm(-1) and 0.088 microg cm(-2), respectively. The nature of the extracted species was found to be Co(SCN)2 x 2S. An excellent linearity with a correlation coefficient value of 0.999 was obtained for the Co(II)-Cyanex 923 complex. Stability and regeneration of the reagent (Cyanex 923) for reuse is the main advantage of the present method. The method was successfully applied to the determination of cobalt in synthetic mixtures and pharmaceutical samples was found to give values close to the actual ones. Standard alloy samples, such as high-speed tool BCS 484 and 485, have been tested for the determination of cobalt for the purpose of validating the present method. The results of the proposed method are comparable with atomic absorption spectrometry and were found to be in good agreement. 相似文献
6.
Simon G. Bott Alan P. Marchand Dongxia Xing Rajesh Shukla Stephen James Obrey K. Venkatesan J. Narasimha Moorthy 《Journal of chemical crystallography》1997,27(11):661-665
NaBH4 reduction of a cage dione proceeds in a stereospecific fashion to give theendo,endo-diol. This reactivity is related to the crystal structure. 相似文献
7.
Synchronized whistlers recorded at Varanasi 总被引:1,自引:0,他引:1
Some interesting events of synchronized whistlers recorded at low latitude station Varanasi during magnetic storm period of
the year 1977 are presented. The dynamic spectrum analysis shows that the component whistlers are Eckersley whistlers having
dispersion 10 s1/2 and 30 s1/2. An attempt has been made to explain the dynamic spectra using lightning discharge generated from magnetospheric sources 相似文献
8.
Rajesh Pereira 《Journal of Mathematical Analysis and Applications》2003,285(1):336-348
In 1959, Davis introduced the concept of a differentiator of an operator on a finite-dimensional Hilbert space. We prove that every such operator possesses a differentiator. We also use the theory of differentiators to solve several problems in the geometry of polynomials. For instance, we answer in the affirmative a twenty year old unsolved conjecture of Schoenberg, a related conjecture of Katsoprinakis and a fifty year old unsolved conjecture of De Bruijn and Springer. 相似文献
9.
Y. D. Kolekar S. B. Kulkarni Keka Chakraborty A. Das S. K. Paranjpe P. B. Joshi 《Pramana》2004,63(2):189-197
Nd2Sn2O7 pyrochlores with the substitution of Zr4+ were prepared by conventional ceramic double sintering technique. The single-phase formation was confirmed by X-ray diffraction
and neutron diffraction techniques. Relative intensity calculations for X-ray diffraction analysis were performed for oxygen
positional parametersx = 0.331 and 0.375, while Rietveld refinements were employed for neutron diffraction data. The neutron diffraction study revealed
that there are only two anion sites with 48f and 8b positions. This indicates that the 8a site, i.e. O(3) sublattice, is completely
vacant and the structure is a perfect cubic pyrochlore with space group Fd3m (O
h
7
). From the conductivity measurements, it is observed that the electronic conductivity dominates from room temperature up
to about 525 K and forT > 525 K, the oxygen ion conduction dominates the charge transport in these compositions. Complex impedance spectroscopy indicates
the existence of grain and grain boundary as two separate elements. 相似文献
10.
S. C. Joshi M. P. Singh V. P. Pandey B. S. Rajput 《International Journal of Theoretical Physics》2002,41(6):1107-1125
In four-dimensional N = 4 supersymmetric gauge theory, we obtain an exact metric on the moduli space of quantum vacua and analyze the spectra of BPS states in weak as well as in strong coupling regions. Identifying the hypermultiplet of the dyonic state as a string stretched between D3-brane probe and a 7-brane, we demonstrate that the two hypermultiplets, which become massless at two singularities in supersymmetric theory, correspond to open strings beginning on the D3-brane and ending on the respective 7-brane. 相似文献