Random Copolymers of 1,5-Dioxepan-2-one

ABSTRACT

Copolymers of 1,5-dioxepan-2-one (DXO) and e-caprolactone (?-CL), δ-valerolactone (δ-VL) or L-lactide (LLA) have been synthesized and characterized. High molecular weight copolymers were obtained using stannous-2-ethyl hexanoate as catalyst in bulk. Reactivity ratios for the copolymerization of DXO and δ-VL were determined at 110°C as r_VL=0.5 and r_DXO=2.3. At high conversion, depolymerization of δ-VL occurred, resulting in lower molecular weight and variations in the copolymer composition.

Physical properties, such as crystallinity and melting temperature of the DXO-copolymers proved to be strongly dependent on the choice of comonomer and on the molar composition of the copolymers. DXO appears to be incorporated into the poly-?-caprolactone (PCL) crystals and to some extent into the poly-δ-valerolactone (PVL) crystals, resulting in a more gradual decrease in crystallinity with increasing amount of DXO.     

Secondary ion yields produced by keV atomic and polyatomic ion impacts on a self-assembled monolayer surface

A suite of keV polyatomic or 'cluster' projectiles was used to bombard unoxidized and oxidized self-assembled monolayer surfaces. Negative secondary ion yields, collected at the limit of single ion impacts, were measured and compared for both molecular and fragment ions. In contrast to targets that are orders of magnitude thicker than the penetration range of the primary ions, secondary ion yields from polyatomic projectile impacts on self-assembled monolayers show little to no enhancement when compared with monatomic projectiles at the same velocity. This unusual trend is most likely due to the structural arrangement and bonding characteristics of the monolayer molecules with the Au(111). Copyright 1999 John Wiley & Sons, Ltd.     

Completions of partial metrics into value lattices

In this paper we investigate some notions of completion of partial metric spaces, including the bicompletion, the Smyth completion, and a new “spherical completion”. Given an auxiliary relation, we show that it arises from a totally bounded partial metric space, and the spherical completion of such a space is its round ideal completion. We also give an example of a totally bounded partial metric space whose bicompletion and Smyth completion are not continuous posets. Finally, we present an example of a totally bounded partial metric giving rise to the Scott and lower topologies of a continuous poset, but whose spherical completion is not a continuous poset.     

Fusion around the barrier for 7Li+12C

Fusion cross-sections for the ⁷Li + ¹²C reaction have been measured at energies above the Coulomb barrier by the direct detection of evaporation residues. The heavy evaporation residues with energies below 3 MeV could not be separated out from the α-particles in the spectrum and hence their contribution was estimated using statistical model calculations. The present work indicates that suppression of fusion cross-sections due to the breakup of ⁷Li may not be significant for ⁷Li + ¹²C reaction at energies around the barrier.     

Topologies on totally ordered sets

A well-formed ordered space is a totally ordered set equipped with any topology which possesses a subbase consisting entirely of initial and final segments of the set. The well-formed ordered spaces are the structures obtained by repeatedly taking subspaces, quotient spaces and inverse limits, starting from a collection of totally ordered sets with the interval topology, and the paper studies their properties.     

Bitopologies on Totally Ordered Sets

We study the category of ray bispaces, that is, the category whose objects are totally ordered sets with two topologies, each having a subbase of rays and so that the resulting bitopological space is pairwise weakly symmetric, and whose morphisms are the pairwise continuous functions. In contrast with the purely topological results of [5], we show that, (1) such spaces are utterly normal and hence monotonically normal (in the sense of [6]), and (2) (Intermediate Value Theorem) the pairwise continuous image of a pairwise connected bitopological space in a selective ray bispace is an interval. We also obtain conditions for the equality of the de Groot dual (see [4]) and the ray dual (see [5]) of a ray topology and show that a selective ray topology is compact if and only if it is skew compact.     

Real meromorphic functions and linear differential polynomials

We determine all real meromorphic functions f in the plane such that f has finitely many zeros, the poles of f have bounded multiplicities, and f and F have finitely many non-real zeros, where F is a linear differential polynomial given by F = f (k) +Σk-1j=0ajf(j) , in which k≥2 and the coefficients aj are real numbers with a0≠0.     

A general theory of structure spaces with applications to spaces of prime ideals

A structure space is a quadrupleX=(X, d, A, P), where for some setR, X A=2 ^R ,d:X×X A is defined byd(I, J)=J–I, andP is the family of cofinite subsets ofR. Forr P, I X, N _r (I)={J X: d(I, J) r},To(X)={Q X: if x Q there is anr P such thatN _r (x) Q}. ThenTo(X) is a (not usually Hausdorff) topology onX called the hull-kernel topology. Replacing d byd ^*, whered ^* (I, J)=d(J, I), or byd ^s, whered ^s (I, J.)=d(I, J) d ^* (I, J), and proceeding in the obvious way yields thedual hull-kernel topology To(X ^*) andsymmetric topology To(X ^s ). The latter is always a zero-dimensional Hausdorff space. When R is a commutative ring with identity andX is a collection of proper prime ideals ofR, To(X ^s ) is usually called thepatch topology. Our generality enables us to improve on known results in the case of space of prime ideals and to apply this theory to a wide variety of algebraic structures. In particular, we establish criteria for a subspace of a structure space to be closed in the symmetric topology; we establish a duality between families of maximal elements in the hull-kernel topology and families of minimal elements in the dual hull-kernel topology of subspaces that are closed in the symmetric topology; we use topological constructions to generalize certain ring theoretic notions, such as radical ideals an annihilator ideals; we use this theory to obtain new results about subspaces of the space prime ideals of a reduced, commutative ring.Presented by F. E. J. Linton.This author's research was supported by a grant from the CUNY-PSC research award program.     

Sorption of inorganic nanoparticles in woven cellulose fabrics

Titanium dioxide was deposited from aqueous suspension onto cellulosic surfaces.Titania was sourced from Degussa (P25TM,70:30 anatase:rutile).Dry uptake of particles was shown to be rapid and dominant with one-third of the deposition occurring in less than 30 s and over one-half in the first minute.Isotherms were recorded to compare the rate of titanium deposition on dry and pre-wetted cotton.In the dry case uptake reached a maximum in 30 min whereas in the pre-wetted case the uptake was seen to continue beyond 180 min.A broad trend of higher deposition occurring at lower pH was seen,corresponding to the region where surface charges were opposite and thus attractive.Dry pickup was less significant at high pH.The response to varying ionic strength was complex and was attributed to the combined effect of charge screening,particle aggregation and consequent particle entrapment or occlusion.Titania deposition into the interstices of woven cotton sheets resulted in the formation of inorganic,nanoparticulate skeletons which could be isolated by controlled combustion of the cellulose and thus cotton was suggested to have potential for the templated synthesis of high surface area semiconductor materials.