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In this article, we present results of an empirical study with 500 German students of grades 7 and 8. The study focussed on students' mathematics achievement and their interest in mathematics as well as on the relation between these two constructs. In particular, the results show that the development of an individual student's achievement between grade 7 and grade 8 depends on the achievement level of the specific classroom and therefore on the specific mathematics instruction Interest in mathematics could be regarded a predictor for mathematics achievement Moreover, our findings suggest that the students show hardly any fear of mathematics independent of their achievement level. 相似文献
3.
R. Guerrero F.G. Aliev R. Villar J. Hauch M. Fraune G. Güntherodt K. Rott H. Brückl G. Reiss 《Journal of magnetism and magnetic materials》2006
We report on tunnelling magnetoresistance (TMR), current–voltage (IV) characteristics and low-frequency noise in epitaxially grown Fe(1 1 0)/MgO(1 1 1)/Fe(1 1 0) magnetic tunnel junctions (MTJs) with dimensions from 2×2 to 20×20 μm2. The evaluated MgO energy barrier (0.50±0.08 eV), the barrier width (13.1±0.5 Å) as well as the resistance times area product (7±1 MΩ μm2) show relatively small variation, confirming a high quality epitaxy and uniformity of all MTJs studied. At low temperatures (T<10 K) inelastic electron tunneling spectroscopy (IETS) shows anomalies related to phonons (symmetric structures below 100 meV) and asymmetric features above 200 meV. We explain the asymmetric features in IETS as due to generation of electron standing waves in one of the Fe electrodes. The noise power, though exhibiting a large variation, was observed to be roughly anti-correlated with the TMR. Surprisingly, for the largest junctions we observed a strong enhancement of the normalized low-frequency noise in the antiparallel magnetic configuration. This behavior could be related to the influence of magnetostriction on the characteristics of the insulating barrier through changes in local barrier defects structure. 相似文献
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Christopher J. Chandler Leslie W. Deady James A. Reiss Vasilios Tzimos 《Journal of heterocyclic chemistry》1982,19(5):1017-1019
The preparation of a series of macrocycles, formed by reaction of HO-(-CH2-CH2-O-)nH with 1,10-phenanthroline-2,9-dicarbonyl chloride (n = 2,3,4) and 1,8-naphthyridine-2,7-dicarbonyl chloride (n = 3,4), is described. An improved synthetic route to 2,7-dimethyl-1,8-naphthyridine 9 is also reported. 相似文献
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The synthesis of [2.2](2,6,2',7')naphthalenophane -1,11 - diene 4 has been effected by pyrolysis of the bis-sulphoxide 10, in turn prepared by a ring-contraction procedure of the [3.3]dithiacyclophane 7. The diene 4 has been fully characterized by spectroscopic and chemical methods. The variable-temperature 1H NMR spectra of the diene 4 indicated that the compound undergoes conformational flipping in solution and has a conformational energy barrier ΔG≠25°. 14.9 kcal mol-1 and a coalescence temperature Tc 38° for the internal protons Hc and Hc' (at 100 MHz). These results differ from those previously recorded. A complete assignment of the pmr spectrum of the cyclophane diene 4 at 270 MHz is presented together with the spectrum of the corresponding saturated [2.2]cyclophane 3. 相似文献
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Kinetics of the title reaction catalyzed by complexes of the type (Rh(COD)L2)+(O3SC6H4CH3–p)–(L2=Ph2P(CH2)nPPh2, n=2–4, (–)-DIOP) have been studied. With all the catalysts, the reaction proceeds according to the rate law, –d(C=C)/dt=k[Rh]tot[H2] which speaks for the unsaturate route to the product.
, /Rh(COD)L2/+(O3SC6H4CH3–p)–(L2=Ph2P(CH2)nPPh2, n=2–4, (–)-DIOP). , , : –d(C=C)/dt=k[Rh]tot[H2], , .相似文献
10.
Salvador Puig-Torres Gary E. Martin Keith Smith Paul Cacioli James A. Reiss 《Journal of heterocyclic chemistry》1982,19(4):879-882
The reaction of 2-chloro-3-thiocyanatopyridine with a substituted spiroepoxycyclohexadienone, which served as a masked phenol with reversed polarity, led to the first reported synthesis of an analog of the 4-azaphenoxathiin ring system. Confirmation of the structure was obtained from the assignment of the 13C-nmr spectrum. 相似文献