全文获取类型
收费全文 | 1039篇 |
免费 | 37篇 |
国内免费 | 10篇 |
专业分类
化学 | 517篇 |
晶体学 | 11篇 |
力学 | 35篇 |
数学 | 324篇 |
物理学 | 199篇 |
出版年
2023年 | 10篇 |
2022年 | 29篇 |
2021年 | 36篇 |
2020年 | 29篇 |
2019年 | 38篇 |
2018年 | 35篇 |
2017年 | 42篇 |
2016年 | 51篇 |
2015年 | 35篇 |
2014年 | 34篇 |
2013年 | 54篇 |
2012年 | 59篇 |
2011年 | 56篇 |
2010年 | 43篇 |
2009年 | 43篇 |
2008年 | 37篇 |
2007年 | 29篇 |
2006年 | 25篇 |
2005年 | 40篇 |
2004年 | 25篇 |
2003年 | 27篇 |
2002年 | 30篇 |
2001年 | 15篇 |
2000年 | 14篇 |
1999年 | 10篇 |
1998年 | 11篇 |
1997年 | 7篇 |
1996年 | 20篇 |
1995年 | 14篇 |
1994年 | 16篇 |
1993年 | 5篇 |
1992年 | 10篇 |
1991年 | 8篇 |
1990年 | 7篇 |
1989年 | 5篇 |
1988年 | 13篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 14篇 |
1984年 | 7篇 |
1983年 | 11篇 |
1982年 | 5篇 |
1981年 | 14篇 |
1980年 | 8篇 |
1979年 | 4篇 |
1977年 | 7篇 |
1976年 | 13篇 |
1974年 | 4篇 |
1973年 | 7篇 |
1972年 | 8篇 |
排序方式: 共有1086条查询结果,搜索用时 15 毫秒
1.
2.
Tran Quang Minh Léon Christiaens Pierre Grandclaudon Alain Lablache-Combier 《Tetrahedron》1977,33(17):2225-2229
Photoirradiated in presence of acetophenone, benzo[b]selenophene and its 3-methyl derivative add to dimethyl acetylenedicarboxylate. In each ease, the primary reaction product is unstable and has not been isolated. Photoexeited in its triplet state (the energy of which is in the neighbourhood of 69 ) benzo[b]selenophene and its 2- and 3-methyl, 2,3 dimethyl, 3 acetoxy and 2-methyl-3-acetoxy derivatives add to 1,2 dichloroethylene leading to cyclobutanes. Neither cyclo-addition occurs in absence of photosensitiser. Single-crystal X-ray analysis gave the structures of the two adducts of 3-acetoxybenzo[b]selenophene with trans-1,2-dichloroethylene. In both compounds the chlorine atoms are trans. 相似文献
3.
I. K. Andronik V. S. Vavilov Vu Zoan Mien P. G. Mikhalash M. V. Chukichev 《Russian Physics Journal》1987,30(8):702-706
The results are given of studies on the edge emission of undoped and copperdoped ZnTe crystals in the temprature range 4.2–300K. The copper impurity has been found to increase the intensity of the principal edge emission band substantially. Analysis of the structure of this emission band indicated that a temprature below 160K the main role is played by the emission from excitons that are most probably bound in CuZn and LiZn centers while at higher temperatures it is played by emission during the transition of free electrons to these centers. An appreciable role is played over the entire range of temperatures by emission from free electrons with an energy of 13 MeV. The luminescence quenching energy below 160 K has a value of 7 MeV (the binding energy of a bound exciton) and at higher temperatures it is 78 MeV.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 68–73, August, 1987. 相似文献
4.
The unique advantages of quantum dot (QD) bioconjugates have motivated their application in biological assays. However, physical characterization of bioconjugated QDs after surface modification has often been overlooked. Here, biotinylated antibodies (biotin-IgG) were attached to commercial streptavidin-conjugated quantum dots (strep-QDs) at different stoichiometric ratios, and these QD bioconjugates were characterized with atomic force microscopy and discontinuous sodium dodecyl sulfate agarose gel electrophoresis (SDS-AGE). The results from these complementary analytical techniques showed that the molar ratio determined the relative sizes, molecular weights and morphologies of the QD bioconjugates. Additionally, the novel discontinuous SDS-AGE analysis confirmed specific binding between biotin-IgG and strep-QDs. Researchers who design QD bioconjugates for cell-based assays should consider stoichiometry-dependent differences in the physical properties of their QD bioconjugates. 相似文献
5.
Sofiane Ben Hamouda Quang Trong Nguyen Pierre Schaetzel 《European Polymer Journal》2006,42(11):2994-3005
Ethylene/ethane sorption characteristics were determined for dry Pebax™ (poly(amide 12-block-tetramethylenoxide) copolymer)/AgBF4 membranes by using an electronic microbalance. The membranes containing 0.7 and 22 wt.% AgBF4 showed a dual-mode sorption isotherm. The ethane isotherms for all the membranes were of the Henry-type, which is the normal sorption for gases in rubbery polymers. The abnormal presence of Langmuir sorption sites only for ethylene in the rubbery copolymer, never reported sofar, is attributed to the silver-based specific complexation sites. The silver salt which dissolved in limited amounts in the rubbery copolymer had a much smaller Langmuir sorption capacity than the salt that crystallized in the copolymer. The sorption kinetics indicate that the crystallized salt did adsorb slowly ethylene according to a zeroth-order kinetics, but not ethane. The gas uptake kinetics resulting from a step of the pressure surrounding the copolymer exhibited one stage for ethane but two stages for ethylene. For the latter, there was first a fast Fickian sorption stage, then a drift of the zeroth-order sorption of ethylene on salt crystals, which contributes for a large part to the total uptake. The zeroth-order sorption suggests that the sorbed ethylene amount in the second-stage is independent of the crystal-surface coverage. The value of the Fickian diffusion coefficient calculated by fitting the kinetics with a solution of the second Fick’s law was 5 × 10−12 m2/s for both ethylene (the first stage) and ethane, and is typical for small organic compounds in a rubbery material. 相似文献
6.
Colloidal palladium nanocatalysts prepared by in situ reductions of palladium chloride were immobilized and protected by either of two water-soluble polymers. The particle sizes and size distributions of the palladium colloids were determined by transmission electron microscopy. Their selectivities as catalysts were determined by comparing the extents of hydrogenation of carefully chosen pairs of small-molecule olefins. There was found to be high hydrogenation selectivity with regard to cyclic vs. noncyclic olefins. Selectivity was relatively low, however, among olefins that differed only in size (such as hexene vs. octene), or olefins differing only with regard to the positions of the double bonds (such as 1-octene vs. 3-octene). Selectivity could be improved by careful choice of the immobilizing polymer, and by its use at relatively high concentrations. 相似文献
7.
Castro C Karney WL Valencia MA Vu CM Pemberton RP 《Journal of the American Chemical Society》2005,127(27):9704-9705
Density functional and coupled cluster calculations show that facile thermal configuration change in [12]annulene occurs via a twist-coupled bond-shifting mechanism. The transition state for this process is highly aromatic with M?bius topology. At the CCSD(T)/cc-pVDZ//BH&HLYP/6-311+G** level, the isomerization of tri-trans-[12]annulene 1a (CTCTCT) to its di-trans isomer 2 (CCCTCT) via such a mechanism has a barrier of 18.0 kcal/mol, in good agreement with earlier experiments. Two other aromatic M?bius bond-shifting transition states were located that result in configuration change for other [12]annulene conformers. This mechanism contrasts sharply with diradical configuration change for acyclic polyenes and with planar bond-shifting mechanisms generally assumed for annulenes. This constitutes evidence that neutral M?bius aromatic annulenes play a role in the dynamic processes of neutral [4n]annulenes. 相似文献
8.
We provide a direct computational proof of the known inclusion
where
is the product Hardy space defined for example by R. Fefferman and
is the classical Hardy space used, for example, by E.M. Stein. We
introduce a third space
of Hardy type and analyze the interrelations among these spaces. We give simple sufficient conditions for a given function
of two variables to be the double Fourier transform of a function in
and
respectively. In particular, we obtain a broad class of multipliers on
and
respectively. We also present analogous sufficient conditions in the case of double trigonometric series and, as a by-product,
obtain new multipliers on
and
respectively. 相似文献
9.
10.