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1.
The isolation of (2S,1'S,2'S)-2-(2'-carboxycyclopropyl)glycine (CCG I, 2) from Blighia sapida (Akee) was achieved through column chromatography on deactivated silica gel followed by ion-exchange chromatography. A HPLC method has also been devised in order to assess the purity of the isolated product. 相似文献
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We study incomplete blowup of entropy solutions to first-order quasilinear hyperbolic balance laws. A general procedure to continue solutions beyond the blowup time, which makes use of monotonicity methods, is given. The continuations thus obtained are possibly unbounded and satisfy suitable generalized entropy and Rankine-Hugoniot conditions. Then the uniqueness of continuations satisfying such conditions is proved. 相似文献
3.
Natalini B Marinozzi M Sardella R Macchiarulo A Pellicciari R 《Journal of chromatography. A》2004,1033(2):363-367
The chromatographic resolution of enantiomeric amino acids is accomplished on a reversed phase column using aqueous mobile phase containing the chiral reagent N,N-dimethyl-S-phenylalanine-Cu(II). The separation is a result of the whole interaction between the diastereomeric complex surface and the mixed stationary phase realized by the dynamic coating of the RP-18 carbon chains layer. The elution order seems to be related to the different water coordination capability on copper ion in the formation of the mixed ternary complexes. 相似文献
4.
B. Natalini R. Sardella E. Camaioni S. Natalini R. Pellicciari 《Chromatographia》2006,64(5-6):343-349
With the aim of optimizing the chromatographic process by avoiding any preliminary derivatizing step, we examined the chromatographic behaviour of a selected set of unconjugated bile acids looking at the dominant factors that affect the performances of three different stationary phases: RP-8, RP-18 and RP-18 Base Deactivated (RP-18-BD). Accordingly to its structural peculiarity, the RP-18-BD column combined with a specific mobile phase has proved to be the most suitable one, in enhancing both separation factor α and resolution R
S
within the selected set of analytes. Pronounced changes in the chromatographic profiles by only slightly changing the mobile phase composition (pH, buffer concentration, percentage and kind of organic modifier) prompted us to achieve satisfactory results in the separation and resolution of the selected set of bile acids.Presented at: CE in the Biotechnology & Pharmaceutical Industries: 7th symposium on the practical applications for the analysis of proteins, nucleotides and small molecules, Montreal, Canada, August 12–16, 2005.An erratum to this article can be found at 相似文献
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Denis Bonheure Patrick Habets Franco Obersnel Pierpaolo Omari 《Journal of Differential Equations》2007,243(2):208-237
We discuss existence and multiplicity of positive solutions of the one-dimensional prescribed curvature problem depending on the behaviour at the origin and at infinity of the potential . Besides solutions in W2,1(0,1), we also consider solutions in which are possibly discontinuous at the endpoints of [0,1]. Our approach is essentially variational and is based on a regularization of the action functional associated with the curvature problem. 相似文献
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A symbolic algorithm based on the generalized Lucas polynomials of first kind is used in order to compute the Newton sum rules for the zeros of polynomial eigenfunctions of linear differential operators with polynomial coefficients. 相似文献
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In conformal geometry, the Compactness Conjecture asserts that the set of Yamabe metrics on a smooth, compact, aspherical Riemannian manifold $\left( M,g\right) $ is compact. Established in the locally conformally flat case by Schoen (Lecture Notes in Mathematics, vol. 1365, pp. 120–154. Springer, Berlin 1989, Surveys Pure Application and Mathematics, 52 Longman Science, Technology, pp. 311–320. Harlow 1991) and for $n\le 24$ by Khuri–Marques–Schoen (J Differ Geom 81(1):143–196, 2009), it has revealed to be generally false for $n\ge 25$ as shown by Brendle (J Am Math Soc 21(4):951–979, 2008) and Brendle–Marques (J Differ Geom 81(2):225–250, 2009). A stronger version of it, the compactness under perturbations of the Yamabe equation, is addressed here with respect to the linear geometric potential $\frac{n-2}{4(n-1)} {{\mathrm{Scal}}}_g,\, {{\mathrm{Scal}}}_g$ being the Scalar curvature of $\left( M,g\right) $ . We show that a-priori $L^\infty $ –bounds fail for linear perturbations on all manifolds with $n\ge 4$ as well as a-priori gradient $L^2$ –bounds fail for non-locally conformally flat manifolds with $n\ge 6$ and for locally conformally flat manifolds with $n\ge 7$ . In several situations, the results are optimal. Our proof combines a finite dimensional reduction and the construction of a suitable ansatz for the solutions generated by a family of varying metrics in the conformal class of $g$ . 相似文献