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1.
Leandro Coghi Maurizio Lanfranchi Giancarlo Pelizzi Pieralberto Tarasconi 《Transition Metal Chemistry》1978,3(1):69-76
Summary Crystals of the title compounds are both monoclinic, with unit cell dimensions:a = 9.293(5),b = 10.122(5),c = 16.737(7) Å. = 103.44(3)°,Z = 4, space groupP21/c for the cobalt derivative;a = 13.1ß5(7),b = 17.546(ß),c = 6.871(3) Å, = 107.01(4)°Z = 4, space groupP21/n for the copper derivative. The structures were solved from diffractometer data by the heavy-atom technique for the first compound and by direct methods for the second compound. Refinement by block diagonal least-squares gaveR = 5.9% for 3511 independent reflections andR = 8.8% for 2885 independent reflections for the cobalt and copper compound respectively. In both compounds the biguanide moiety behaves as a bidentate chelating ligand in a symmetrical tautomeric form, but it is deprotonated in the octahedral cobalt compound and neutral in the square planar copper compound. 相似文献
2.
Baldini M Belicchi-Ferrari M Bisceglie F Pelosi G Pinelli S Tarasconi P 《Inorganic chemistry》2003,42(6):2049-2055
Two new 5-formyluracil thiosemicarbazone (H(3)ut) derivatives, Me-H(3)ut (1) and Me(2)-H(3)ut (2), were synthesized by reacting thiosemicarbazides, mono- and dimethylated on the aminic nitrogen, with 5-formyluracil and were subsequently characterized. These ligands, treated with copper chloride and nitrate, afforded three complexes: [Cu(Me-H(3)ut)Cl(2)].H(2)O (3), [Cu(Me(2)-H(3)ut)Cl(2)].H(2)O (4), and [Cu(Me-H(3)ut)(NO(3))(OH(2))(2)]NO(3) (5). The crystal structures of these complexes have been determined by single-crystal X-ray diffraction. In 3 and 4, a similar pentacoordination is present; the copper atom is surrounded by the ligand SNO donor atoms and by two chloride ions. The structure of 5 consists of [Cu(Me-H(3)ut)(NO(3))(OH(2))(2)](+) cations and nitrate anions. The copper coordination (4 + 2) involves the SNO ligand atoms and a water oxygen in the basal plane; the apical positions are occupied by a second water oxygen and by an oxygen of a monodentate nitrate group. Two biochemical techniques, namely DNA titration in the UV-vis region and thermal denaturation, have been employed to probe the details of DNA binding of these compounds. Analysis of the results suggests that our compounds are able to interact with DNA by electrostatic and groove binding but not by intercalation. The compounds have been also tested in vitro on human leukemic cell line U937, but they are not able to inhibit significantly cell proliferation. 相似文献
3.
We further develop the quantization of topological solitons in two-dimensional quantum field theory in terms of Euclidean region functional integrals. Our approach is nonperturbative and mathematically rigorous. We apply it to construct physical states with fractional fermion number in models of interacting bosons and fermions without recurring to a semiclassical approximation. A related issue discussed in this paper is two-dimensional chiral bosonization. 相似文献
4.
Sandra Ianelli Corrado Pelizzi Giancarlo Pelizzi Pieralberto Tarasconi 《Journal of chemical crystallography》1996,26(3):195-201
Manganese(II), nickel(II), and copper(II) complexes of 2,6-diacetylpyridine bis (acetylhydrazone) (H2dapac) have been synthesized and structurally characterized by X-ray diffraction methods. [Mn(H2dapac) (OH2)2](NO3)2 crystallizes in the monoclinic space groupP21/c witha=11.145(3),b=10.723(4),c=17.189(2) Å, =92.81(2)° andZ=4; [Ni(H2dapac)(OH2)2] (NO3)2·H2O crystallizes in the monoclinic space groupP21 witha=9.994(3),b=14.423(4),c=7.697(2)Å, =100.37(2)°, andZ=2; [Cu(H2dapac)(OH2)2](NO3)2·H2O crystallizes in the orthorhombic space groupPbcn witha=20.986(5),b=14.552(3),c=6.905(1)Å andZ=4. In each case the metal atom has a slightly distorted pentagonal bipyramidal environment, the equatorial positions being occupied by three nitrogen and two oxygen atoms from the hydrazone ligand and the apices by two water molecules. The crystalline cohesion in ensured by a three-dimensional network of hydrogen bonds involving the complex cations, the nitrate anions, and, where present, the uncoordinate water molecules. 相似文献
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6.
Let be a (locally) Lipschitz function and a domain whose boundary is unbounded and connected. If there exists a positive bounded solution to the overdetermined elliptic problem we prove that Ω is a half‐plane. In particular, we obtain a partial answer to a question raised by H. Berestycki, L. Caffarelli, and L. Nirenberg in 1997.© 2017 Wiley Periodicals, Inc. 相似文献
7.
Marisa Belicchi-Ferrari Franco Bisceglie Giorgio Pelosi Silvana Pinelli Pieralberto Tarasconi 《Polyhedron》2007
In the course of a research on metal-based compounds active on white blood cell cancers (leukemia, lymphoma and myeloma) nine aliphatic thiosemicarbazones and their nickel complexes have been synthesized with the aim to test their effect on histiocytic lymphoma U937 cell proliferation. All compounds were characterized by elemental, IR and NMR spectra analyses and for five of the complexes also by X-ray crystallography diffraction analysis. Heptanal thiosemicarbazone and the corresponding nickel complex were chosen after a solubility/stability test to carry out preliminary experiments in vitro on human leukemia cell line U937. The complex possesses a remarkable biological activity in inhibiting cell growth and in inducing apoptosis. 相似文献
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9.
Marisa Belicchi-Ferrari Franco Bisceglie Enrico Buluggiu Giorgio Pelosi Pieralberto Tarasconi 《Polyhedron》2010
The syntheses of four compounds, obtained by the reaction of methylpyruvate thiosemicarbazone (Hmpt) and its methyl (Me-Hmpt) and allyl (Allyl-Hmpt) derivatives with bis(triphenylphosphine)copper(I) acetate, are reported. The compounds [Cu(PPh3)2(ptc)(Hptc)]·H2O (1), [Cu(PPh3)2(Me-ptc)] (2), [Cu2(PPh3)2μ-S(Me-pt)μ-S(Me-ptc)]·H2O (3) and [Cu(PPh3)2(Allyl-ptc)] (4) [H2pt = pyruvic acid thiosemicarbazone and Hptc = cyclized pyruvic acid thiosemicarbazone, Me = methyl and Allyl are radical substituents on the amino nitrogen] were characterized by elemental analysis, IR, 1H NMR, and by X-ray crystallography. Compound 3 was also studied by EPR because of the presence in the compound of two copper atoms in two different oxidation states. During the complexation reaction, the thiosemicarbazone ligands tend to undergo a cyclization reaction that leads to the formation of a six-member heterocyclic ring. All four compounds present the [Cu(PPh3)2]+ fragment and constant but different coordination situations. Compound 1 contains two cyclic ligand molecules, one protonated and the other deprotonated, bound as monodentate through the sulfur. Compounds 2 and 4 present a single deprotonated cyclic SN bidentate ligand molecule, while compound 3 contains copper(I) and copper(II), and two ligand molecules, one of which is linear and behaves as SNO tridentate and the other is cyclic and behaves as bridging μSN. 相似文献
10.
Pieralberto Sicbaldi 《Calculus of Variations and Partial Differential Equations》2010,37(3-4):329-344
We prove the existence of nontrivial compact extremal domains for the first eigenvalue of the Laplacian in manifolds ${\mathbb{R}^{n}\times \mathbb{R}{/}T\, \mathbb{Z}}$ with flat metric, for some T > 0. These domains are close to the cylinder-type domain ${B_1 \times \mathbb{R}{/}T\, \mathbb{Z}}$ , where B 1 is the unit ball in ${\mathbb{R}^{n}}$ , they are invariant by rotation with respect to the vertical axe, and are not invariant by vertical translations. Such domains can be extended by periodicity to nontrivial and noncompact domains in Euclidean spaces whose first eigenfunction of the Laplacian with 0 Dirichlet boundary condition has also constant Neumann data at the boundary. 相似文献