全文获取类型
收费全文 | 442篇 |
免费 | 5篇 |
国内免费 | 1篇 |
专业分类
化学 | 258篇 |
力学 | 4篇 |
数学 | 43篇 |
物理学 | 143篇 |
出版年
2015年 | 4篇 |
2013年 | 11篇 |
2012年 | 5篇 |
2011年 | 8篇 |
2010年 | 4篇 |
2009年 | 7篇 |
2008年 | 7篇 |
2007年 | 13篇 |
2006年 | 4篇 |
2005年 | 6篇 |
2004年 | 3篇 |
2003年 | 3篇 |
2002年 | 5篇 |
2001年 | 5篇 |
2000年 | 11篇 |
1999年 | 5篇 |
1997年 | 6篇 |
1996年 | 8篇 |
1995年 | 8篇 |
1994年 | 10篇 |
1993年 | 10篇 |
1992年 | 8篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 11篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 10篇 |
1984年 | 6篇 |
1981年 | 3篇 |
1980年 | 8篇 |
1979年 | 3篇 |
1978年 | 5篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1974年 | 7篇 |
1973年 | 8篇 |
1965年 | 3篇 |
1964年 | 6篇 |
1963年 | 3篇 |
1960年 | 3篇 |
1958年 | 3篇 |
1956年 | 26篇 |
1955年 | 55篇 |
1954年 | 35篇 |
1942年 | 3篇 |
1940年 | 3篇 |
1929年 | 3篇 |
1902年 | 3篇 |
排序方式: 共有448条查询结果,搜索用时 15 毫秒
1.
2.
3.
4.
5.
6.
Studies of extractions of yttrium from aqueous solution into chloroform, benzene, methyl isobutyl ketone, and mixtures of these solvents, containing thenoyltrifluoroacetone are described. The effects of reagent concentration, added n-butylamine, and added fluoride were investigated. Values of pH and Pe were determined, and identifications of the involved species are suggested. 相似文献
7.
The application of parallel processing techniques to molecular mechanics calculations is evaluated. Using the standard molecular mechanics package, MM2, four different parallel versions of the program are implemented in a four-processor computing environment. A set of 529 test structures is used to compare the efficiency of the parallel versions of MM2 to a standard serial version of the program. Statistics describing execution times and program execution cycles are gathered and analyzed. The effects of parallel processing overhead and computer system load are explored, and the practical utility of parallel processing in molecular mechanics is estimated. The results of these parallelization experiments indicate that for geometry optimizations requiring significant amounts of computing time an improvement in program execution speed approaching 50% is realizable. © 1993 John Wiley & Sons, Inc. 相似文献
8.
Mg2Ru5B4 and Mg5Ru13B11, Two Ternary Magnesium Ruthenium Borides with Channel Structures The ternary borides Mg2Ru5B4 and Mg5Ru13B11, crystallizing in the orthorhombic space group Pbam, were prepared by reaction of the elementary components in sealed tantalum ampoules. Mg2Ru5B4 (a = 1000.0(2) pm, b = 837,6(1) pm, c = 295.42(3) pm, Z = 2, RW = 0.027 for 563 reflections) is homeotypic with Sc2Ru5B4. The structure contains BRu6-trigonal prisms, connected by faces and edges to form pentagonal channels filled with chains of magnesium atoms. Mg5Ru13B11 (a = 2190.1(2) pm, b = 996.7(2) pm, c = 294.65(3) pm, Z = 2, RW = 0.031 for 959 reflections) has a similar but so far unknown structure in which parts of the magnesium and boron atoms are disordered. 相似文献
9.
The intramolecular and long-range ferromagnetic coupling between p-phenylenediamine radical cations in head-to-tail coupled oligo(1, 4-phenyleneethynylene)s and oligo(1,4-phenylenvinylene)s between neighbors and next-nearest neighbors is described. UV/vis/near-IR experiments show that the radical cations are localized in the pendant p-phenylenediamine units of the conjugated oligomers. The ESR spectra of these oligo(1,4-phenyleneethynylene) and oligo(1, 4-phenylenvinylene) di(radical cation)s are consistent with those of a triplet state. A linear behavior is observed for the doubly integrated ESR intensity of the DeltaM(s) = +/-1 and DeltaM(s) = +/-2 signals with the inverse temperature (I approximately 1/T), consistent with Curie's law. This behavior indicates a triplet ground-state diradical with a large triplet-singlet energy gap or possibly a degeneracy of singlet and triplet states. 相似文献
10.
Extraction of radiolabeled cobalt(II) from aqueous solution into one or more solvents using 25 reagents was studied. Both reagent concentration and pH variation were investigated. The relevant association and partition constants for several of the better reagent-solvent systems were determined. These systems were hexanoic acid in I-hexanol, octanoic acid in I-octanol, and thenoyltrifluoroacetone in benzene. 相似文献