首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1516篇
  免费   278篇
  国内免费   148篇
化学   1044篇
晶体学   10篇
力学   138篇
综合类   27篇
数学   180篇
物理学   543篇
  2024年   6篇
  2023年   42篇
  2022年   71篇
  2021年   50篇
  2020年   72篇
  2019年   64篇
  2018年   41篇
  2017年   45篇
  2016年   74篇
  2015年   74篇
  2014年   84篇
  2013年   101篇
  2012年   143篇
  2011年   127篇
  2010年   103篇
  2009年   95篇
  2008年   95篇
  2007年   81篇
  2006年   92篇
  2005年   48篇
  2004年   57篇
  2003年   43篇
  2002年   38篇
  2001年   19篇
  2000年   26篇
  1999年   14篇
  1998年   26篇
  1997年   21篇
  1996年   24篇
  1995年   20篇
  1994年   10篇
  1993年   19篇
  1992年   23篇
  1991年   10篇
  1990年   12篇
  1989年   13篇
  1988年   5篇
  1987年   6篇
  1986年   11篇
  1985年   12篇
  1984年   9篇
  1983年   8篇
  1982年   2篇
  1981年   3篇
  1980年   1篇
  1979年   2篇
排序方式: 共有1942条查询结果,搜索用时 0 毫秒
1.
In this note we study how the Chern-Simons invariant behaves when two hyperbolic 3-manifolds are glued together along incompressible
thrice-punctured spheres. Such an operation produces many hyperbolic 3-manifolds with different numbers of cusps sharing the same volume and the same Chern-Simons invariant. The results in this note, combined with those of Meyerhoff and Ruberman, give an algorithm for determining the unknown constant in Neumann's simplicial formula for the Chern-Simons invariant of hyperbolic 3-manifolds.

  相似文献   

2.
Band bending at the Ni/Si(100)-2×1 interface has been monitored by using Si 2p core level photoemission spectra. Two nickel-induced Si 2p components appear in the initial interaction between Ni and Si(100)-2×1, which is confined at the top surface and the first subsurface layers. At Ni coverage less than 0.0375 ML, Ni atoms prefer the adamantane interstitial sites on the first subsurface, but switch to the pedestal sites on Si dimer rows at higher Ni coverage. The change in the preferred occupation sites of Ni atoms on the Si(100)-2×1 surface strongly affects the amount of band bending shift. The shift towards higher binding energy, when Ni atoms occupy the adamantane interstitial sites, is attributed to metal-induced-gap states. While Ni atoms occupy the pedestal sites, the band bending shift is reduced which is attributed to the passivation of surface states.  相似文献   
3.
Montmorillonite (MMT) was modified with the acidified cocamidopropyl betaine (CAB) and the resulting organo‐montmorillonite (O‐MMT) was dispersed in an epoxy/methyl tetrahydrophthalic anhydride system to form epoxy nanocomposites. The intercalation and exfoliation behavior of the epoxy nanocomposites were examined by X‐ray diffraction and transmission electron microscopy. The curing behavior and thermal property were investigated by in situ Fourier transform infrared spectroscopy and DSC, respectively. The results showed that MMT could be highly intercalated by acidified CAB, and O‐MMT could be easily dispersed in epoxy resin to form intercalated/exfoliated epoxy nanocomposites. When the O‐MMT loading was lower than 8 phr (relative to 100 phr resin), exfoliated nanocomposites were achieved. The glass‐transition temperatures (Tg's) of the exfoliated nanocomposite were 20 °C higher than that of the neat resin. At higher O‐MMT loading, partial exfoliation was achieved, and those samples possessed moderately higher Tg's as compared with the neat resin. O‐MMT showed an obviously catalytic nature toward the curing of epoxy resin. The curing rate of the epoxy compound increased with O‐MMT loading. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1192–1198, 2004  相似文献   
4.
在光伏晶体两端外加一恒定的直流偏压,背景光的光伏效应对形成屏蔽-光伏孤子的空间电荷场没有影响,但对晶体中的电流有影响.如果外电源的电动势是恒定的,则背景光的光伏效应与外电路的电阻协同起作用,可以通过晶体两端的电压降影响晶体中的空间电荷场,进而影响空间孤子的宽度.在一定的条件下甚至可以实现亮、暗孤子的转换. 关键词: 屏蔽-光伏 空间孤子 孤子宽度 亮暗孤子转换  相似文献   
5.
2,5‐Bis(2‐bromofluorene‐7‐yl)silole was prepared by a modified one‐pot synthesis with a reverse addition procedure, from which novel silole‐containing polyfluorenes with binary random and alternating structures (silole contents between 4.5 and 25% and high Mw up to 509 kDa were successfully synthesized. The well‐defined repeating unit of the alternating copolymer comprises a terfluorene and a silole ring. Optoelectronic properties including UV absorption, electrochemistry, photoluminescence (PL), and electroluminescence (EL) of the copolymers were examined. The different excitation energy transfers from fluorene to silole of the copolymers in solution and in the solid state were compared. The films of the copolymers showed silole‐dominant green emissions with high absolute PL quantum yields up to 83%. EL devices of the copolymers with a configuration of ITO/PEDOT/copolymer/Ba/Al displayed exclusive silole emissions peaked at around 543 nm and the highest EL efficiency was achieved with the alternating copolymer. Using the alternating copolymer and poly(9,9‐dioctylfluorene) as the blend‐type emissive layer, a maximum external quantum efficiency of 1.99% (four times to that of the neat film) was realized, which was a high efficiency so far reported for silole‐containing polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 756–767, 2007  相似文献   
6.
High longitudinal selectivity of the shifting multiplexing with spherical reference wave is proposed and demonstrated. A simplified method based on wave optics is used for calculating the selectivity, and the result fits well the experimental measurement. Under the paraxial condition, a simple formula for the longitudinal selectivity is introduced. With use of an object lens with effective NA=0.817, we obtain that an FWHM of selectivity is as small as 1 μm.  相似文献   
7.
多层光子晶体滤波器研究   总被引:34,自引:6,他引:28  
从双层结构出发研究了一种由多块不同的单周期光子晶体组合而成的多层结构的滤波器,论述了这种滤波器的工作原理,研究表明这种结构适于制作带通、窄带通过、带阻、宽带带阻、高通以及其它各种性能的滤波器。实验和理论研究的结果相一致。  相似文献   
8.
Bi2O3/SrTiO3 composite powders have been prepared and their photocatalytic activities were investigated by photooxidation of methanol. These powders were characterized by UV-Visible diffuse reflectance spectra, SEM and X-ray diffraction (XRD). The results revealed that all the Bi2O3/SrTiO3 composite powders exhibited higher photocatalytic activity than pure SrTiO3, Bi2O3 and TiO2 (P25) under visible light irradiation (λ>440 nm). The effects of the Bi2O3 contents on the photocatalytic activities of the composite powders were examined, the photocatalytic activities increased with the content of Bi2O3 increasing to a maximum of 83% and then decreased under visible light irradiation. The effects of the calcination temperatures on the photocatalytic activities of the composite powders were also investigated.  相似文献   
9.
The singularly perturbed boundary value problem for a class of semilinearsingular equation is considered. Using a simple and special method the asym-ptotic behavior of solution is studied.  相似文献   
10.
57Fe Mössbauer effect study has been performed on intercalated compound 2H?Fe0.5TaSe2 over a temperature range between 14K and 500K. The highly concentrated intercalation samples 2H?FexTaSe2 with Fe atoms (x up to 2) are prepared by the electrochemical method for the first time. The Mössbauer measurement shows that iron is in Fe3+ high spin state and with the same probability occupies both octahedral and tetrahedral interstices of the Van der Waals gap. The fact that effective masses of iron ions in both sites are close to 57 amu and characteristic temperatures (ΘM =130K, 107K respectively) are found to be relatively small is attributed to the weak forces on Fe3+.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号