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排序方式: 共有196条查询结果,搜索用时 15 毫秒
1.
An extremely efficient asymmetric synthesis of a pyrrolidine azasugar was completed in only four steps in water, without the use of protecting groups and in 60% overall yield from a simple, achiral bis-electrophile. 相似文献
2.
The determination of residual amounts of bromide in a local anaesthetic hydrochloride by capillary electrophoresis was developed. Direct UV detection at 200 nm was used for the determination of the bromide content. The separation capacity of the system must be sufficient when bromide is determined in the presence of a large excess of chloride since electromigration dispersion of the highly concentrated chloride peak may impair the resolution. The background electrolyte (BGE) contained both acetonitrile and methanesulphonic acid in order to improve the selectivity and minimise the electromigration dispersion. The system was optimised with respect to resolution of the chloride and the bromide peaks by statistical experimental design using a multivariate optimisation program. The developed method was validated in accordance with the ICH guidelines and proved to be suitable for its intended use. 相似文献
3.
Olle Nilsson 《Journal of separation science》1982,5(1):38-44
The total length-based second moment contribution from longitudinal sample diffusion in both phases on a column, σD , is derived by adding individual partial differential contributions to a partial differential equation accounting for the longitudinal diffusion processes only. Although each diffusion-dispersed sample part is equilibrated between two phases, the resulting σ,D (= 2D mt m + 2D st s) can be interpreted as the sum of two independent contributions in accordance with the variance addition rule. (D m and D s are the mean diffusion coefficients and t mand t s the mean residence times of the sample in the mobile and stationary phases, respectively.) The same σD expression is derived from the random walk model of Giddings by treating the diffusional process in each phase as statistically independent of the other processes. Under these conditions the broadening contribution from longitudinal diffusion in the mobile phase is shown to be independent of the velocity profile. 相似文献
4.
The extracellular β-xylosidase (EC 3.2.1.37) excreted by the thermophilic eubacteriumRhodothermus marinus when grown on xylan has been investigated. The enzyme has been partially purified by ultrafiltration and gel filtration, and some of its characteristics are presented.Rhodothermus marinus grew on xylan with μmax= 0.4 h? and the α-xylosidase activity was 50 nkat/mL after 24 h in a batch fermentation. The α-xylosidase activity had a half-life of more than 1 h at 90°C and of 14 h at 85 °C. At 80°C, 80% of the initial activity remained after 24 h. The initial activity increased with increasing temperature, showing maximal activity at 90°C. The β-xylosidase had a pH-optimum of 6 and was stable in the range between pH 5 and 9. At pH 10 and 11, 82 and 66%, respectively, of the initial activity remained after 24 h when incubated at 65°C. The molecular weight was estimated to be 169,000 dalton by gelfiltration. 相似文献
5.
Iterative extended Hükel calculations for all valence electrons and iterative PPP calculations in the variable electronegativity formalism for -electrons were performed on benzene, pyridine, fluorobenzene, and the pyrylium ion. The charge distributions for all compounds were found more uniform and plausible with the iteration procedures than without. Polarization effects from the-electrons were found to be of importance for the -electrons. The lone-pair picture of the highest occupied MO in pyridine is preserved in the iterative extended Hückel method, and two lone-pairs were obtained on the fluorine atom of fluorobenzene. The results indicate that this atom is not hybridized.
Sponsored in part by King Gustaf VI Adolfs 70-Years Fund for Swedish Culture, Knut and Alice Wallenberg's Foundation, and in part by the Swedish National Research Council. 相似文献
Zusammenfassung Benzol, Pyridin, Fluorbenzol und Pyriliumion wurden mit einer iterativen EH-Methode und einer iterativen PPP-VE-Methode berechnet. Es zeigte sich, daß Ladungsverteilungen bei Benutzung des Iterationsverfahrens besser beschrieben werden. Polarisationseffekte der-Elektronen auf die -Elektronen stellen sich als wichtig heraus. Auch in der IEH-Methode bleibt das oberste besetzte MO des Pyridins ein einsames Elektronenpaar. Am Fluoratom im Fluorbenzol werden zwei einsame-Elektronenpaare erhalten. Die Resultate führen zu der Annahme, daß dieses Atom nicht hybridisiert ist.
Resumé Des calculs par les méthodes itératives de Hückel étendu pour tous les électrons de valence et de PPP avec électronégativité variable pour les électrons ont été effectués pour le benzène, la pyridine, le fluorobenzène et l'ion pyrylium. Les distributions de charge pour tons ces composés sont plus uniformes et plus plausibles avec les procédés itératis que sans. Les électrons ont un effet de polarisation important sur les électrons . La plus haute orbitale occupée dans la pyridine reste identifiable comme la paire libre dans la méthode de Hückel étendue, et l'on obtient deux paires libres sur l'atome de fluor du fluorobenzène. Cet atome n'est pas hybride.
Sponsored in part by King Gustaf VI Adolfs 70-Years Fund for Swedish Culture, Knut and Alice Wallenberg's Foundation, and in part by the Swedish National Research Council. 相似文献
6.
A differential scanning calorimetric and sorption calorimetric study of two alkyl maltosides, C8G2 and C10G2, was performed. In the dry state, C8G2 and C10G2 do not form solid crystals but undergo a glass transition upon temperature change. The glass is partly ordered and has the same lamellar structure as the liquid crystals formed by the two maltosides. To reflect the presence of the glass transition and the structure, the terms "glassy crystals" and "glassy liquid crystals" can be used. A mechanism of the relaxation of the glassy crystals based on the results of small-angle X-ray scattering experiments is proposed. Experiments on water sorption showed that the glassy crystals turn into lyotropic liquid crystals upon sorption of water at constant temperature. This isothermal glass transition can be characterized by water content and change of partial molar enthalpy of mixing of water. A method to calculate the phase diagram liquid crystals-glassy liquid crystals is proposed. 相似文献
7.
The effect of polymers on the phase behavior of balanced microemulsions: diblock-copolymer and comb-polymers 总被引:1,自引:0,他引:1
The effect of some amphipilic diblock-copolymers and comb-polymers on a balanced Winsor III microemulsion system is investigated with the quaternary system n-octyl-β-d-glucoside/1-octanol/n-octane/D2O as basis system. The diblock-copolymers are polyethyleneoxide-co-polydodecenoxide (PEO
x
PEDODO
y
) and polyethyleneoxide-co-polybutyleneoxide (PEO
x
PEBU
y
), constituted of a straight chain hydrophilic part and a bulky hydrophobic part. Addition of the diblock-copolymer leads to an enhancement of the swelling of the middle phase by uptake of water and oil; a maximum boosting factor of 6 was obtained for PEO111PEDODO25. Nuclear magnetic resonance diffusometry yields the self-diffusion coefficients of all the components in the system. The diffusion experiments provide information on how the microstructure of the bicontinuous microemulsion changes upon addition of the polymers. The reduced self-diffusion coefficients of water and oil are sensitive to the type of polymer that is incorporated in the film. For the diblock-copolymers, as mainly used here, the reduced self-diffusion coefficient of oil and water will respond to how the polymer bends the film. When the film bends away from water, the reduced self-diffusion of the water will increase, whereas the oil diffusion will decrease due to the film acting as a barrier, hindering free diffusion. The self-diffusion coefficient of the polymer and surfactant are similar in magnitude and both decrease slightly with increasing polymer concentration. 相似文献
8.
Abstract Platinum is studied, theoretically, under very high compression. The calculated equation of state is found to agree well with the recent experimental data. At V/V0 = 0.4, where V0 is the experimental equilibrium volume, we find a transition from the face centered cubic structure (fcc), found at ambient pressure, to the body centered cubic structure (bcc). The calculated transition pressure is 26 Mbar. The stabilization of the bcc structure is explained by the eigen value sum. 相似文献
9.
Three block copolymers of poly(ethylene succinate) and poly(tetramethylene glycol) with about 20, 54, and 59 mol% polyether have been prepared and subjected to hydrolytic degradation at 37°C. The sample containing 59 mol% showed drastic changes in the properties after 3 months of degradation, whereas the other samples exhibited only minor changes. The tensile strength was completely lost, the molecular weight had decreased to 7% of the original value, and the crystallinity (measured as heat of fusion) had more than doubled. IR and 1H-NMR analyses showed that the rates of release of the different polymeric blocks varied throughout the period of hydrolytic degradation. Fibers of the block copolymer poly(ethylene succinate)/poly(tetramethylene glycol) with poly(tetramethylene glycol) fractions ranging from 20 to 50 mol% have been analyzed by 13 C NMR to determine the molecular weights of the PES blocks and by reflection IR, ESCA, and SEM to investigate the surface composition. The molecular weights of the polyester blocks were inversely proportional to the mol% of polyether, and the values were in agreement with theoretical calculated values. The surface concentration of the polyether was found to be higher than that in the bulk and also independent of the mol% polyether in the range of study. A degradation mechanism is proposed which involves a combined effect of surface erosion and hydrolytic attack on the ester linkages connecting the amorphous polyether and the crystalline polyester blocks. 相似文献
10.