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排序方式: 共有221条查询结果,搜索用时 15 毫秒
1.
Ching Sum Hui Lillian Sze Man Lam Chun Yin Wai Kin Chan Aleksandra B. Djurii 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1708-1715
Polyurethanes incorporated with rhenium diimine complexes were synthesized. The polymers exhibited interesting morphologies and solution properties. Results from gel permeation chromatography suggested the formation of polymer aggregates in solutions. The polymers could act as probes for metal ions. The addition of metal ions to polymer solutions led to significant changes in the electronic absorption properties of the polymer solutions. This was attributed to the interactions between the polyether moieties and metal ions. The metal complexes could also act as efficient photosensitizers. After doping with charge‐transport viologens, the photoconductivity of the polymers was greatly enhanced. The experimental quantum efficiency was simulated with Onsager's theory. The thermalization distances and the primary yields were typically 12–14 Å and 10?3, respectively. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1708–1715, 2003 相似文献
2.
The sessile-drop method is used to measure the surface tension and density of liquid indium and uranium under high vacuum. Measurements are made over the temperature range 156–500°C for In and at the melting point for U. Surface oxides are efficiently removed with a glow discharge system. Drop profiles are captured by photograph and processed using nonlinear regression to yield the surface tension and density. In this regression procedure, normal distances from calculated profiles to data points are minimized. For indium, the density and surface tension measurements yield mp = 7.05 × 103kg/m3, d/dT = −0.776 kg/m3·°C, and γmp = 0.568 N/m, dγ/dT = −9.45 × 10−5 N/m·°C. The results for uranium at the melting point are mp = 17.47 × 103 kg/m3 and γmp = 1.653 N/m. 相似文献
3.
4.
Paul S. Pregosin S. N. Sze Piero Salvadori Raffaello Lazzaroni 《Helvetica chimica acta》1977,60(8):2514-2521
13C- and 195Pt-NMR. spectra for the complexes trans-PtCl2(amine)(CH2?CH2) have been measured. For amine = (S)-N-methyl-α-methylbenzylamine the two diastereomers present may be distinguished from the values 3J(Pt,C). The 195Pt-chemical shift is shown to be sensitive to subtle differences stemming from intramolecular non-bonded interactions. 相似文献
5.
Inner- and valence-shell electron energy loss spectra of gaseous SF6, SeF6 and TeF6 have been measured at high impact energy (2.0–3.7 keV) and zero degree scattering angle. The resulting inner-shell excitation spectra include F 1s, S 2s and 2p in SF6: F 1s, Se 3s, 3p and 3d in SeF6 and F 1s, Te 4s, 4p, 4d and 3d in TeF6. The results for each of these hexafluorides are interpreted, in the framework of the potential barrier model, as excitations to resonances involving a common manifold of virtual valence (inner-well) orbitals and also to Rydberg (outer-well) orbitals. The below-edge shape resonances in corresponding inner-shell excitation spectra of these hexafluorides show very similar variations in intensities in accord with expectations based on electric-dipole selection rules. This is an indication that these below-edge resonances in SeF6 and TeF6 are of the same symmetry as those in SF6 (i.e. a1g and t1u). The continuum (above-edge) shape resonances in SeF6 also show similar spectral behavior to those of SF6 and can be understood by including Se 4d and S 3d orbitals in the basis for the respective MO schemes. However, in TeF6 completely different spectral behavior is observed for the continuum resonances. In particular, there is a dramatic series of intense resonances observed above the Te 3d and 4d edges. The TeF6 spectrum can only be understood by extending the MO basis set to include the Te 4f orbitals which are even lower lying than the Te 5d orbitals. Therefore, these continuum resonances which are also seen in the F 1 s and Te 3p spectra of TeF6 are assigned to l=3 (f-type) continuum shape resonances due to involvement of the 4f orbitals rather than the l=2 (d-type) continuum resonances observed in SF6 and SeF6. This is the first reported observation of such f-type continuum shape resonances and such considerations will likely prove to be important in the understanding of near-edge spectra of heavy atom containing species. The VSEELS spectra which are very similar for the three hexafluorides also show significant continuum shape resonances. A consideration of both the ISEELS and the VSEELS spectra indicates that there is a weakening of the potential barrier in going through the series from SF6, SeF6 to TeF6. 相似文献
6.
Facile fabrication of AgCl@polypyrrole-chitosan core-shell nanoparticles and polymeric hollow nanospheres 总被引:1,自引:0,他引:1
A one-step sequential method for preparing AgCl@polypyrrole-chitosan core-shell nanoparticles and subsequently the formation of polypyrrole-chitosan hollow nanospheres is reported. The formation of the core and the shell is performed in one reaction medium almost simultaneously. Transmission electron microscopy (TEM) images show the presence of core-shell nanoparticles and hollow nanospheres. Ultraviolet-visible (UV-vis) studies reveal that AgCl was formed first followed by polypyrrole. X-ray diffration (XRD) and UV-vis studies show that AgCl was present in the core-shell nanoparticles and could be removed completely from the core. 相似文献
7.
The Mitsunobu reaction is a widely used and versatile method for the dehydrative oxidation–reduction condensation of an acid/pronucleophile usually with a primary or secondary alcohol that requires the combination of a reducing phosphine reagent together with an oxidizing azo reagent. The utility of this reaction stems from the fact that it is generally highly stereoselective and occurs with inversion of the stereochemical configuration of the alcohol starting material. Furthermore, as carboxylic acids, phenols, imides, sulfonamides, and other compounds can be used as the acid/pronucleophile, this reaction is useful for the preparation of a wide variety of functional groups. This Focus Review of the Mitsunobu reaction summarizes its origins, the current understanding of its mechanism, and recent improvements and applications. 相似文献
8.
The chiral resolving ability of a novel single-isomer cationic β-cyclodextrin (CD), mono-6A-propylammonium-6A-deoxy-β-cyclodextrin chloride (PrAMCD), as a chiral selector in capillary electrophoresis (CE) is reported in this work for the enantioseparation of hydroxy, carboxylic acids and amphoteric analytes. The effect of chiral selector concentration on the resolution was studied. Good resolutions were achieved for hydroxy acids. Optimum resolutions were obtained even at 3.5 mM CD concentration for carboxylic acids. The electrophoretic method showed good linearity and reproducibility in terms of migration times and peak areas, which should make it suitable for routine analysis. In addition, baseline chiral separation of a six-acid mixture was achieved within 20 min. PrAMCD proved to be an effective chiral selector for acidic analytes. 相似文献
9.
[reactions: see text] [(Ph3P)CuH]6 effectively catalyzes the hydrostannation of activated alkynes with exclusive regioselectivity for alpha-stannation. Syn hydrostannation is observed exclusively for alkynoates. Anti or syn hydrostannation adducts are obtained as products for alkynone substrates. 相似文献
10.
The effect of p-toluenesulfonic acid and phosphoric acid on the cyclodehydration of quinazolone prepolymers has been investigated. Isothermal weight loss during the curing process was monitored closely to follow the extent of cyclization. The optimum weight loss corresponding to 2 mol water is used as an indication of the formation of a fully cyclized quinazolone structure without concurrent decarboxylation. This can be achieved by incorporating the catalyst at 2 wt% concentration, which permits a lower curing temperature than those previously reported. The polymers formed in the presence of catalyst have thermal stability superior to those prepared without catalyst. The glass transition temperature is also raised. This we conclude to be a direct result of the decrease in the amount of incomplete quinazolone rings along the polymer backbone as a result of more efficient cyclization catalyzed by the acids. 相似文献