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Mikhail Andramonov 《Journal of Global Optimization》2002,24(2):115-132
We consider applications of disjunctive programming to global optimization and problems with equilibrium constraints. We propose a modification of the algorithm of F. Beaumont for disjunctive programming problems and show its numerical efficiency. 相似文献
5.
Tatiana B. Mikenas Vladimir A. Zakharov Lyudmila G. Echevskaya Mikhail A. Matsko 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5057-5066
The effects of polymerization temperature, polymerization time, ethylene and hydrogen concentration, and effect of comonomers (hexene‐1, propylene) on the activity of supported catalyst of composition LFeCl2/MgCl2‐Al(i‐Bu)3 (L = 2,6‐bis[1‐(2,6‐dimethylphenylimino)ethyl] pyridyl) and polymer characteristics (molecular weight (MW), molecular‐weight distribution (MWD), molecular structure) have been studied. Effective activation energy of ethylene polymerization over LFeCl2/MgCl2‐Al(i‐Bu)3 has a value typical of supported Ziegler–Natta catalysts (11.9 kcal/mol). The polymerization reaction is of the first order with respect to monomer at the ethylene concentration >0.2 mol/L. Addition of small amounts of hydrogen (9–17%) significantly increases the activity; however, further increase in hydrogen concentration decreases the activity. The IRS and DSC analysis of PE indicates that catalyst LFeCl2/MgCl2‐Al(i‐Bu)3 has a very low copolymerizing ability toward propylene and hexene‐1. MW and MWD of PE produced over these catalysts depend on the polymerization time, ethylene and hexene‐1 concentration. The activation effect of hydrogen and other kinetic features of ethylene polymerization over supported catalysts based on the Fe (II) complexes are discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5057–5066, 2007 相似文献
6.
Jürgen Kurths M. Carmen Romano Marco Thiel Grigory V. Osipov Mikhail V. Ivanchenko István Z. Kiss John L. Hudson 《Nonlinear dynamics》2006,44(1-4):135-149
We present two different approaches to detect and quantify phase synchronization in the case of coupled non-phase coherent
oscillators. The first one is based on the general idea of curvature of an arbitrary curve. The second one is based on recurrences
of the trajectory in phase space. We illustrate both methods in the paradigmatic example of the R?ssler system in the funnel
regime. We show that the second method is applicable even in the case of noisy data. Furthermore, we extend the second approach
to the application of chains of coupled systems, which allows us to detect easily clusters of synchronized oscillators. In
order to illustrate the applicability of this approach, we show the results of the algorithm applied to experimental data
from a population of 64 electrochemical oscillators. 相似文献
7.
Young C. Kim Mikhail A. Anisimov Jan V. Sengers Erik Luijten 《Journal of statistical physics》2003,110(3-6):591-609
The character of critical behavior in physical systems depends on the range of interactions. In the limit of infinite range of the interactions, systems will exhibit mean-field critical behavior, i.e., critical behavior not affected by fluctuations of the order parameter. If the interaction range is finite, the critical behavior asymptotically close to the critical point is determined by fluctuations and the actual critical behavior depends on the particular universality class. A variety of systems, including fluids and anisotropic ferromagnets, belongs to the three-dimensional Ising universality class. Recent numerical studies of Ising models with different interaction ranges have revealed a spectacular crossover between the asymptotic fluctuation-induced critical behavior and mean-field-type critical behavior. In this work, we compare these numerical results with a crossover Landau model based on renormalization-group matching. For this purpose we consider an application of the crossover Landau model to the three-dimensional Ising model without fitting to any adjustable parameters. The crossover behavior of the critical susceptibility and of the order parameter is analyzed over a broad range (ten orders) of the scaled distance to the critical temperature. The dependence of the coupling constant on the interaction range, governing the crossover critical behavior, is discussed. 相似文献
8.
We show that the existence of a non-metrizable compact subspace of a topological group G often implies that G contains an uncountable supersequence (a copy of the one-point compactification of an uncountable discrete space). The existence of uncountable supersequences in a topological group has a strong impact on bounded subsets of the group. For example, if a topological group G contains an uncountable supersequence and K is a closed bounded subset of G which does not contain uncountable supersequences, then any subset A of K is bounded in G?(K?A). We also show that every precompact Abelian topological group H can be embedded as a closed subgroup into a precompact Abelian topological group G such that H is bounded in G and all bounded subsets of the quotient group G/H are finite. This complements Ursul's result on closed embeddings of precompact groups to pseudocompact groups. 相似文献
9.
R. F. Klevtsova L. A. Glinskaya V. G. Shchukin S. V. Larionov 《Journal of Structural Chemistry》2002,43(1):133-141
Single crystals of the mixed-ligand complex compounds of Cd(i-Bu2PS2)2 with Phen and 2,2-Bipy have been obtained. The crystal structures of the complexes [CdPhen{(i-C4H9)2PS2}2] (I) and [Cd(2,2-Bipy){(i-C4H9)2PS2}2] (II) were determined by X-ray diffraction (CAD-4 diffractometer, MoK
radiation, 1739 F
F
hkl
, R = 0.0417 for I and 2612 F
hkl
, R = 0.0442 for II). Monoclinic crystals with unit cell parameters a = 15.640(3), b = 20.797(4), c = 11.559(2) , = 111.21(3)°, V = 3505(1) 3, Z = 4, d
calc = 1.348 g/cm3, space group
(I); a = 14.737(3), b = 20.918(4), c = 11.517(2) , = 105.53(3)°, V = 3421(1) 3, Z = 4, d
calc = 1.334 g/cm3, space group
(II). The structures consist of discrete monomer molecules. The coordination polyhedra of the Cd atoms are distorted octahedra formed by four S atoms of two cyclic bidentate ligands i-Bu2
and two N atoms of the cyclic bidentate ligands — Phen or 2,
-Bipy molecules. The interaction between molecules I and II in the structures and the packing modes are considered. 相似文献
10.
Rigorous definitions are presented for the kinematic angular momentum K of a system of classical particles (a concept dual to the conventional angular momentum J), the angular momentum L(xi) associated with the moments of inertia, and the contributions to the total kinetic energy of the system from various modes of the motion of the particles. Some key properties of these quantities are described-in particular, their invariance under any orthogonal coordinate transformation and the inequalities they are subject to. The main mathematical tool exploited is the singular value decomposition of rectangular matrices and its differentiation with respect to a parameter. The quantities introduced employ as ingredients particle coordinates and momenta, commonly available in classical trajectory studies of chemical reactions and in molecular dynamics simulations, and thus are of prospective use as sensitive and immediately calculated indicators of phase transitions, isomerizations, onsets of chaotic behavior, and other dynamical critical phenomena in classical microaggregates, such as nanoscale clusters. 相似文献