全文获取类型
收费全文 | 847篇 |
免费 | 113篇 |
国内免费 | 81篇 |
专业分类
化学 | 590篇 |
晶体学 | 9篇 |
力学 | 37篇 |
综合类 | 4篇 |
数学 | 89篇 |
物理学 | 312篇 |
出版年
2024年 | 2篇 |
2023年 | 27篇 |
2022年 | 39篇 |
2021年 | 47篇 |
2020年 | 53篇 |
2019年 | 44篇 |
2018年 | 26篇 |
2017年 | 22篇 |
2016年 | 38篇 |
2015年 | 39篇 |
2014年 | 45篇 |
2013年 | 48篇 |
2012年 | 78篇 |
2011年 | 77篇 |
2010年 | 51篇 |
2009年 | 51篇 |
2008年 | 53篇 |
2007年 | 40篇 |
2006年 | 46篇 |
2005年 | 36篇 |
2004年 | 30篇 |
2003年 | 18篇 |
2002年 | 26篇 |
2001年 | 16篇 |
2000年 | 11篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 11篇 |
1996年 | 7篇 |
1995年 | 7篇 |
1994年 | 8篇 |
1993年 | 4篇 |
1992年 | 8篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1983年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有1041条查询结果,搜索用时 437 毫秒
1.
In this work, the beam splitter with two input ports and two output ports in two-dimensional photonic crystals is studied through the finite-difference time-domain method. The beam splitter consists of two orthogonally cross line defects. The diameter of the two diagonal air holes at the intersection of the two line defects was modified. The input light can be identically divided into the two output ports. The beam splitters can be applied in the photonic crystal Mach-Zehnder interferometers or photonic crystal optical switches. 相似文献
2.
In the present paper, some new almost fixed point theorems and fixed point theorems for lower semicontinuous type multivalued mappings are obtained in metrizable H-spaces. 相似文献
3.
Dendritic nanocrystalline CdS film was deposited at liquid-liquid interface of surfactants and an electrolyte containing 4 mmol L−1 cadmium chloride (CdCl2) and 16 mmol L−1 thioacetamide (CH3CSNH2) with an initial pH value of 5 at 15 °C by electrochemical synthesis. The nanofilm was characterized by transmission electron microscopy (TEM), field emission scanning electron microscope (FE-SEM), atomic force microscopy (AFM), ultraviolet visible (UV-vis) absorption spectroscopy and fluorescence spectroscopy. The surface morphology and particle size of the nanofilm were investigated by AFM, SEM and TEM, and the crystalline size was 30-50 nm. The thickness of the nanofilm calculated by optical absorption spectrum was 80 nm. The microstructure and composition of the nanofilm was investigated by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), showing its polycrystalline structure consisting of CdS and Cd. Optical properties of the nanofilm were investigated systematically by UV-vis absorption and fluorescence spectroscopy. A λonset blue shift compared with bulk CdS was observed in the absorption spectra. Fluorescence spectra of the nanofilm indicated that the CdS nanofilm emitted blue and green light. The nanocomposites film electrode will bring about anodic photocurrent during illumination, showing that the transfer of cavities produces photocurrent. 相似文献
4.
In this paper, by the use of a fixed point theorem, many new necessary and sufficient conditions for the existence of positive solutions in C[0,1]∩C1[0,1]∩C2(0,1) or C[0,1]∩C2(0,1) are presented for singular superlinear and sublinear second-order boundary value problems. Singularities at t=0, t=1 will be discussed. 相似文献
5.
理想气体的温度、体积和压强三个状态参量之间的关系由气体状态方程pV/T=恒量决定。当气体状态发生变化时,判断某一个参量的变化趋势是一个比较复杂的问题。如图1,为p—T图中的状态变化曲线,状态由A变化到B,判断体积的变化趋势。 相似文献
6.
基于Karhunen-Loève变换和小波谱特征矢量量化的三维谱像数据压缩 总被引:1,自引:1,他引:0
提出了基于Karhunen Lo埁ve变换的小波谱特征矢量量化三维谱像数据压缩方法耍幔颍瑁酰睿澹?Lo埁ve变换 /小波变换 /小波谱特征矢量量化方法应用了Karhunen Lo埁ve变换的消除谱相关性优良性能 ,应用二维小波变换消除空间相关性 ,在小波变换域内应用二维集分割嵌入块编码和一维谱特征矢量量化对三维谱像数据压缩 ,获得较高的压缩性能。实验结果表明 :Karhunen Lo埁ve变换 /小波变换 /小波谱特征矢量量化编码比Karhunen Lo埁ve变换 /小波变换 /改进对块零树编码和Karhunen Lo埁ve变换 /小波变换 /快速矢量量化编码方法在同样压缩比条件下 ,峰值信噪比提高 2dB和 1dB以上 ,而速度提高了 1.5和 8倍 ,整体压缩性能有较大的提高 相似文献
7.
ZHANG Liangmin SHAO Zongshu ZHANG Jingwen MU Xiaodong CHEN Huanchu JIANG Minhua 《Chinese Journal of Lasers》1996,5(3):235-241
Mutually Pumped Phase Conjugation of Three Incoherent Beams with a Novel Photorefractive CrystalMutuallyPumpedPhaseConjugatio... 相似文献
8.
9.
VOCs控制催化剂的研制 总被引:5,自引:1,他引:5
以堇青石蜂窝陶瓷体为第一载体、γ-Al2O3为第二载体,制成的含稀土La和过渡金属元素的复合氧化物催化剂,在连续流动的反应体系上评价了催化剂对苯、氰氢酸、乙酸和氯苯等VOCs的氧化反应活性.结果表明: 采用LaCuMn组合制备的催化剂,La的含量在7%~10%左右、Cu的含量在5.5%左右、Mn的含量在7.5%左右时,第二载体γ-Al2O3的负载以采用半胶、pH值4~5、加入某些活性剂、负载量以7%~10%、活化温度为400~500 ℃时制成的催化剂的活性最好,研制的VOCs控制催化剂对各种VOCs均具有很高的催化活性. 相似文献
10.
Bakhtar Ullah Yuli Zhou Jingwen Chen Zongbi Bao Yiwen Yang Qiwei Yang Qilong Ren Zhiguo Zhang 《Tetrahedron letters》2019,60(4):348-351
Thiourea itself has been introduced as a mild and efficient organocatalyst for the oxidative α -cyanation of N-aryltetrahydroisoquinolines (THIQs) with trimethylsilyl cyanide (TMSCN), giving the corresponding products in good to excellent yields. Experimental investigations demonstrated that thiourea acts as a radical initiator by abstracting hydroxyl radical (OH) from tert-butyl hydroperoxide (TBHP) directly instead of non-covalent hydrogen bondings (H-bondings) activation. The use of thiourea as a radical initiator offers a new avenue for innovative chemical transformations in organocatalyzed radical chemistry. 相似文献