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排序方式: 共有182条查询结果,搜索用时 31 毫秒
1.
双二茂铁甲氨基异丙醇的合成与晶体结构 总被引:1,自引:0,他引:1
双二茂铁甲醇与BF3在CH2Cl2中与BF3作用形成的双二茂铁甲基碳正离子, 无需从溶液中分离出来, 便可直接与异丙醇胺反应得到双二茂铁甲氨基异丙醇,且产率较高。由乙醇重结晶得到的单晶经X射线衍射法测试表明, 该化合物晶体属三斜晶系, P空间群, 化学式为2[C24H27Fe2NO]CH3CH2OH, Mr = 960.40。晶胞参数: a = 10.6825(7), b = 14.463(1), c = 15.794(1) , ?= 69.593(1), b = 75.535(1), g = 81.302(1)? V = 2208.9(3) 3, Z = 2, Dc = 1.444 g/cm3, m(MoKa) = 1.332 mm-1, F(000) = 1004, 对于I > 2(I)的4742个衍射点, 最终的R = 0.0525、wR = 0.0704。晶体结构由2分子双二茂铁甲氨基异丙醇和1分子乙醇通过氢键缔合组成。 相似文献
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The chemical constituents of the fungus Verticillium psalliotae were studied. Two new aromadendrane sesquiterpenes inonotin M (1) and inonotin N (2) were isolated from the EtOAc extract of the fungal culture broth. The structures of compounds were elucidated mainly by HRESIMS experiments, and 1D, 2D-NMR spectroscopy analysis. 相似文献
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Antennal morphology, structure and sensilla distribution in Microplitis pallidipes (Hymenoptera: Braconidae) 总被引:2,自引:0,他引:2
Microplitis pallidipes (Hymenoptera: Braconidae) is an important larval parasitoid of noctuid larval pests. In this study, we describe the morphology, ultrastructure and distribution of sensilla on the antennae of both male and female adults using scanning electron microscopy; complemented with transmission electron microscopy. Observations determined that the antennae of M. pallidipes were threadlike and the flagella were composed of 16 sub-segments. Totally, there were six types of sensilla found on the antennae. They were identified as Sensilla trichodea, Sensilla chaetica, Sensilla basiconica type I, S. basiconica type II, Sensilla coeloconicum, and elongated Sensilla placodea, respectively. The S. trichodea were the most abundant sensilla and distributed over the entire antennae, while S. basiconica I and II, S. coeloconicum, and elongated S. placodea were limited to the flagellum. S. chaetica were found on the scape and pedicle in very low numbers. The S. basiconica II and elongated S. placodea walls were full of pores as evident in transmission electron micrographs. Though the shape and structure of antennae between male and female adults were not basically different, the length and width of the antennae on male wasps were significantly greater than that of females. Also, the number, size and density of S. placodea of the male were significantly greater than those of females. The morphology and structure of these sensilla were compared with that found in other braconid wasps. Their possible functions are discussed in light of previously published literature. 相似文献
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This paper presents a modified descent method for solving co-coercive variational inequalities. Incorporating with the techniques of identifying descent directions and optimal step sizes along these directions, the new method improves the efficiencies of some existing projection methods. Some numerical results for an economic equilibrium problem are reported. 相似文献
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Two-dimensional photon counting imaging detector based on a Vernier position sensitive anode readout 总被引:1,自引:0,他引:1
A two-dimensional photon counting imaging detector based on a Vernier position sensitive anode is reported. The decode principle and design of a two-dimensional Vernier anode are introduced in detail. A photon counting imaging system was built based on a Vernier anode. The image of very weak optical radiation can be reconstructed by image processing in a period of integration time. The resolution is superior to 100 μm according to the resolution test. The detector may realize the imaging of very weak particle flow of high-energy photons, electrons and ions, so it can be used for high-energy physics, deep space exploration, spectral measurement and bio-luminescence detection. 相似文献
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The trace quotient problem or the trace ratio problem (TRP) is to find an orthogonal matrix \(V\in \mathbb{R }^{m\times \ell } ~(m\ge \ell )\) that maximizes the quotient \({{\mathrm{tr}}}(V^\top BV)/{{\mathrm{tr}}}(V^\top WV)\) for a given symmetric matrix \(B\in \mathbb R ^{m\times m}\) and a symmetric positive definite matrix \(W\in \mathbb R ^{m\times m}.\) It has a crucial role in linear discriminant analysis and has many other applications in computer vision and machine learning as well. In this short note, we first establish the classical first and second order optimality conditions for TRP. As a straightforward application of these optimality conditions, we contribute a simple proof for the property that TRP does not admit local non-global maximizer, which is first proved by Shen et al. (A geometric revisit to the trace quotient problem, proceedings of the 19th International Symposium of Mathematical Theory of Networks and Systems, 2010) based on Grassmann manifold. Without involving much knowledge of the underlying differential geometry, our proof primarily uses basic properties in linear algebra, which also leads to an effective starting pointing strategy for any monotonically convergent iteration to find the global maximizer of TRP. 相似文献