全文获取类型
收费全文 | 258篇 |
免费 | 5篇 |
国内免费 | 128篇 |
专业分类
化学 | 261篇 |
力学 | 23篇 |
综合类 | 1篇 |
数学 | 19篇 |
物理学 | 87篇 |
出版年
2018年 | 1篇 |
2013年 | 2篇 |
2011年 | 48篇 |
2010年 | 20篇 |
2009年 | 26篇 |
2008年 | 2篇 |
2007年 | 2篇 |
2006年 | 5篇 |
2005年 | 23篇 |
2004年 | 76篇 |
2003年 | 28篇 |
2002年 | 15篇 |
2001年 | 25篇 |
2000年 | 2篇 |
1999年 | 4篇 |
1998年 | 3篇 |
1997年 | 6篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 12篇 |
1992年 | 23篇 |
1991年 | 11篇 |
1990年 | 13篇 |
1989年 | 13篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 5篇 |
1985年 | 1篇 |
1984年 | 4篇 |
1983年 | 3篇 |
排序方式: 共有391条查询结果,搜索用时 31 毫秒
1.
The polyacrylic acid functionalized polystyrene nanospheres were synthesized and self-assembled into irregular, densely packed monolayers in non-aqueous media. The polymer nanoparticles were chemically adhered to substrates. The morphologies of the resulting films were investigated. The impact of the volume fraction of alcohol in the mixed solvents on the particle adsorption and fabrication of nanosphere assembled films was examined. 相似文献
2.
QuanXiangwu YanPingSHI LiYANG 《中国化学快报》2004,15(12):1441-1444
From the alcoholic extract of the whole plant of Ligularia virgaurea spp. oligocephala, three novel eremophilane sesquiterpene lactones, 6α, 10α-dihydroxy- 1-oxoeremophila-7(11), 8(9)-dien-8, 12-olide, 613, 10α-dihydroxy-1-oxoeremophila-7 (ll), 8 (9)-dien-8, 12-olide and 10α-hydroxy-1-oxoeremophila-7(l 1), 8(9)-dien-8, 12-olide were isolated. Their structures were elucidated by various spectroscopic methods including intensive 2D NMR techniques (COSY,HMQC, HMBC and ^1H-^1H NOESY) and HR-MS. 相似文献
3.
4.
ErWeiLI KunGAO ZhongJianJIA 《中国化学快报》2004,15(4):425-427
Two new acetylxylosides,ent-manool-13-O-β-D-2′-acetylxylopyranoside(1)and entmanool-13-O-β-D-2′,4′-diacetylxylopyranoside(2)were isolated from Aster veitchianus.Their structures were elucidated by spectroscopic methods. 相似文献
5.
陈吉阳 《中国科学B辑(英文版)》1989,(12)
This paper introduced briefly the research results on lichenometry of the Holoceneglacial fluctuations in the headwater of the Urumqi River, in the central TianshanMountains and discussed the histories of the Holocene glaciers and the climate. It isconsidered that lichenometry is one applicable method for dating the mid- and late-Holocene deposits in the cold and mountainous regions. Rhizocarpon geographicum (L.)DCand Xanthoria elegans (Link.) Th. Fr. could be used for dating the deposits of about 4500and 500 a B.P. respectively. There existed at least four periods of glacial advances whichoccurred before about 5700, 4100, 2800 and 403- 74 a B. P. respectively with the firstperiod the longest. Little Ice Age includes three stages of glacial advances which endedbefore about 403, 208 and 74 a B. P. respectively with the second stage the maximum.During the general Holocene warming processes, there existed at least four cold peri-ods which ended before about 5700, 4100, 2800 and 420- 91 a B.P. respectively, 相似文献
6.
用密度泛函B3LYP方法研究了过渡金属钐类卡宾与乙烯的环丙烷化反应的机理。对三种不同的钐的SS试剂CH_3SmCH_2X(其中X=Cl、Br和Ⅰ)分别和CH_2CH_2反应的各反应物、中间体、过渡态和产物构型的全部结构几何参数进行了优化,用内禀反应坐标(IRC)计算和频率分析方法,对过渡态进行了验证。结果表明:CH_3SmCH_2X(其中X=Cl、Br和Ⅰ)与CH_2CH_2环丙烷化反应按亚甲基转移通道(通道A)和卡宾金属化通道(通道B)都可以进行,与锂类卡宾的反应机理相同,只是按亚甲基转移通道(通道A)进行反应较容易一些,而且此反应在较低的温度下就可以发生。 相似文献
7.
1 IntroductionForsolvingstiffinitialvalueproblemsforsystemsofODEsy′=f(y) ,y(t0 ) =y0 ,t0 <t≤T ,y0 ,y∈Rm,f :Ω Rm →Rm (1 .1 )manyparticularone blockmethodsoftheformYn+1= AYn+h( B0 F(Yn) + B1F(Yn+1) ) , A =A Im, Bi=Bi Im,A ,Bi∈Rr×r,Yn =(YTnr,… ,yT(n+1)r- 1) T,F(Yn) =(fT(ynr) ,… ,fT(y(n+1)r- 1) ) T,yj≈ y(tj) ,… 相似文献
8.
Possible triggering of solar activity to big earthquakes (Ms ≥ 8) in faults with near west-east strike in China 总被引:1,自引:0,他引:1
HAN Yanben GUO Zengjian WU Jinbing & MA Lihua . National Astronomical Observatories Chinese Academy of Sciences Beijing China . Earthquake Research Institute of Lanzhou CSB Lanzhou China Correspondence should be addressed to Han Yanben 《中国科学G辑(英文版)》2004,(2)
A big earthquake (Ms = 8.1) occurred at western Kunlun Mts gap on November 14, 2001. It is the biggest earthquake in China in the past 50 years and the only one with a magnitude bigger than 8 in China after Dangxiong Earthquake (M = 8) in Tibet in 1951. The big earthquake has drawn wide attention of scientists in seismological, geophysical, geological and astro-geodynamic circles. Scientists are interested in the occurrence regularity of the very big earthquakes and try to find out the fac… 相似文献
9.
XinMeiZHENG YanXingQI XiaoMingZHANG JiShuanSUO 《中国化学快报》2004,15(6):655-658
Jacobsen‘s catalyst was immobilized onto SBA-15 by multi-step grafting, and this heterogenized catalyst exhibited comparable catalytic performance with the corresponding homogeneous counterpart for the epoxidation of alkenes, and the catalyst could be recycled effectively several times. 相似文献
10.