全文获取类型
收费全文 | 494篇 |
免费 | 4篇 |
国内免费 | 2篇 |
专业分类
化学 | 244篇 |
晶体学 | 13篇 |
力学 | 14篇 |
数学 | 85篇 |
物理学 | 144篇 |
出版年
2023年 | 3篇 |
2022年 | 2篇 |
2021年 | 6篇 |
2020年 | 5篇 |
2019年 | 7篇 |
2018年 | 14篇 |
2017年 | 8篇 |
2016年 | 15篇 |
2015年 | 16篇 |
2014年 | 14篇 |
2013年 | 24篇 |
2012年 | 28篇 |
2011年 | 27篇 |
2010年 | 20篇 |
2009年 | 20篇 |
2008年 | 32篇 |
2007年 | 21篇 |
2006年 | 21篇 |
2005年 | 28篇 |
2004年 | 10篇 |
2003年 | 17篇 |
2002年 | 15篇 |
2001年 | 11篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1998年 | 12篇 |
1997年 | 7篇 |
1996年 | 5篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 10篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1985年 | 3篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1977年 | 4篇 |
1975年 | 2篇 |
1961年 | 1篇 |
1960年 | 2篇 |
1959年 | 8篇 |
1958年 | 10篇 |
1957年 | 9篇 |
1956年 | 2篇 |
1955年 | 8篇 |
1954年 | 4篇 |
排序方式: 共有500条查询结果,搜索用时 15 毫秒
1.
2.
The problem of calculation of Sturmian functions (positive energy Weinberg states) for nonlocal (exchange) interactions is considered. It is shown that the method of continued fractions proposed by Horáek and Sasakawa makes the calculation of Sturmian eigenfunctions and eigenvalues feasible even for complicated nonlocal interactions. As an example Sturmian functions and Sturmian eigenvalues for the low energy electron-hydrogen scattering in the static exchange approximation are calculated. In addition a very general proof of convergence of the method of continued fractions is presented.Dedicated to the memory of Professor Jozef Kvasnica. 相似文献
3.
André Luiz Tessaro Vagner Roberto Batistela Augusto César Gracetto Hueder Paulo Moisés de Oliveira Rosana Lazara Sernaglia Vagner Roberto de Souza Wilker Caetano Noboru Hioka 《Journal of Physical Organic Chemistry》2011,24(2):155-161
Benzoporphyrin monoacid derivatives, here named B3A and B3B, are promising new drugs for photodynamic therapy. Although both isomers show interesting characteristics as photosensitizing compounds, they have some distinct physicochemical properties such as the tendency to self‐aggregate in water‐rich media. Because pH drives the presence of each species, the pKa of these compounds assumes strategic importance. However, traditional micro‐titration methods and UV–Vis absorption techniques fail to give reliable pKa values due to the characteristics of this highly complex system, such as the precipitation of hydrophobic species, close pKa values, and high absorption band superposition. In the present work, chemometric tools are employed to evaluate pKa, and the kinetic tendency of monomers to undergo self‐aggregation is investigated. In solvent mixtures at low water percentage in ethanol, both B3A and B3B are stabilized in a monomeric state. However, in mixtures with a high water content, self‐aggregation takes place, mainly under a mild pH acid condition (3 < pH < 6), in which the prevalent protolytic species of both isomers is the neutral charged form, compounds with carboxylic and porphyrin free‐base groups. It is demonstrated that both isomers can undergo aggregation following a self‐catalytic mechanism, which is 2000 times slower to B3A than B3B. For B3A, the aggregation is manifested by a decrease in the monomer band with the aggregation band probably superposed to that of the monomer. For B3B, together with the decrease in the monomer band, a new band related to self‐aggregates is observed. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
4.
Progress in various fields of microscopy techniques brought up enormous possibilities to study the photosynthesis down to the level of individual pigment-protein complexes. The aim of this review is to present recent developments in the photosynthesis research obtained using such highly advanced techniques. Three areas of microscopy techniques covering optical microscopy, electron microscopy and scanning probe microscopy are reviewed. Whereas the electron microscopy and scanning probe microscopy are used in photosynthesis mainly for structural studies of photosynthetic pigment-protein complexes, the optical microscopy is used also for functional studies. 相似文献
5.
Ladislav Špaček 《Czechoslovak Journal of Physics》1955,5(3):431-433
6.
Ladislav Kopecký 《Czechoslovak Journal of Physics》1955,5(2):283-285
7.
Indrek Jõgi Rasmus Talviste Sirli Raud Jüri Raud Toomas Plank Ladislav Moravský Matej Klas Štefan Matejčík 《等离子体物理论文集》2020,60(3):e201900127
The present study compares the operation of two cold atmospheric plasma jet (CAPJ) configurations: needle-to-cylinder electrode configuration (CAPJ I) and single high-voltage cylinder electrode around the quartz tube (CAPJ II). The CAPJs were operated in argon flowing through a quartz capillary with 0.5-mm inner diameter into the ambient air, and the plasma was generated by sinusoidal kHz frequency AC power supplies. The main emphasis of the study was on the mechanism of the initiation of ionization waves for these two configurations. For both CAPJs, there appeared several ionization waves during one half-period of the applied voltage waveform, and the number of ionization waves increased at higher voltage amplitudes. However, we discovered marked differences in the initiation of the ionization waves for two different CAPJ configuration. The applied voltage controlled the initiation of consecutive ionization waves, which propagated from the grounded electrode towards the tube orifice in CAPJ I. In the case of CAPJ II, certain time had to pass for the initiation of a new ionization wave, and subsequent ionization waves within the same half-period started at the tube orifice. In addition to the differences in the initiation of the ionization waves, we observed that the CAPJ I was ignited and sustained at lower voltages, while CAPJ II produced a longer plasma jet. The observed advantages and deficiencies of investigated CAPJ configurations point out their potential in different applications. 相似文献
8.
9.
Polyakov S Malendevich R Jankovic L Stegeman G Bosshard C Gunter P 《Optics letters》2002,27(12):1049-1051
The generation of multiple quadratic spatial solitons aligned approximately along a crystal axis in a biaxial noncritically phase-matched crystal is shown theoretically and experimentally to be the consequence of anisotropic diffraction. 相似文献
10.
A polemic arose recently about the applicability of the t-expansion method to the calculation of the ground state energy E0 of the Rabi model. For specific choices of the trial function and very large number of involved connected moments, the t-expansion results are rather poor and exhibit considerable oscillations. In this Letter, we formulate the t-expansion method for trial functions containing two free parameters which capture two exactly solvable limits of the Rabi Hamiltonian. At each order of the t-series, E0 is assumed to be stationary with respect to the free parameters. A high accuracy of E0 estimates is achieved for small numbers (5 or 6) of involved connected moments, the relative error being smaller than 10−4 (0.01%) within the whole parameter space of the Rabi Hamiltonian. A special symmetrization of the trial function enables us to calculate also the first excited energy E1, with the relative error smaller than 10−2 (1%). 相似文献