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A.V. Eremin E.V. Gurentsov M. Hofmann B.F. Kock C. Schulz 《Applied physics. B, Lasers and optics》2006,83(3):449-454
Time-resolved laser-induced incandescence (TR-LII) was applied for the determination of particle sizes during carbon-particle formation from supersaturated atomic carbon vapor that was generated by laser photolysis of carbon suboxide (C3O2) at room temperature. Thus, the solid carbon particles were formed under hydrogen-free conditions. The TR-LII technique was used for in situ size measurement of growing carbon particles and samples of final particles were analyzed by transmission electron microscopy (TEM). It was found that the particles grow to a final size of 4–12 nm within 0.02–1 ms. The properties of the obtained particles depend on the initial conditions in the reaction volume, i.e. concentration of carbon suboxide, pressure and type of gas diluter, photolysis wavelength, and laser pulse energy. The comparison of TR-LII and TEM particle sizing results yields information about the effective thermal energy accommodation coefficients for He, Ar, CO, and C3O2 molecules on carbon particles. PACS 61.46.Df; 07.60.-j; 78.70.-g 相似文献
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Starting from 3-oxo-17β-hydroxy-Δ1-5α-androstene (2b) the preparation of 1-oxo-2-methoxy-4α-methyl-17β-hydroxy-Δ2-5α-androstene (9), a compound with the ring A structure of quassine (1) is described. The key problem of the reaction sequence is shown to be the monomethylation at C(4). 相似文献
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Marvin Fresia Dr. Mario Kock Prof. Dr. Thomas Lindel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(56):12733-12737
The enantioselective synthesis of (−)-dihydroraputindole D is reported. The key step is the desymmetrizing benzoylation of a prochiral 1,3-diol employing Trost′s ProPhenol catalyst system, which has been applied for the first time to a cyclic molecule carrying geminal hydroxymethyl groups. The cyclopenta[f]indoline system was assembled by Au(I)-catalyzed cyclization of an alkynylated indoline precursor. (−)-Dihydroraputindole D was obtained in 17 steps and 8% overall yield starting from dihydroxyacetone. In combination with quantum chemical calculations of the ECD spectra, our synthesis allowed us to determine the absolute configuration (5S,7R) of the natural product (+)-raputindole D from the Rutaceous plant Raputia simulans. 相似文献
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Platinum solubility of a substance designed as a model for emissions of automobile catalytic converters 总被引:3,自引:0,他引:3
D. Nachtigall H. Kock S. Artelt K. Levsen G. Wünsch T. Rühle R. Schlögl 《Fresenius' Journal of Analytical Chemistry》1996,354(5-6):742-746
Automobile catalytic converters emit nanocrystalline platinum attached to alumina particles. For investigations about the bioavailability of Pt from these particles a model substance with approx. 5% Pt on alumina has been prepared and characterized by physical methods (ESCA, XRD, TEM, DTA, TG). Measuring the platinum solubility of these samples in different solvents revealed high amounts that can be explained assuming a corrosion process. The portion of soluble platinum is dependent on the particle size distribution. For a comparative study platinum black has been used. In general the platinum determination has been carried out by electrothermal atomic absorption spectrometry (ET-AAS). The comparison of ET-AAS results with determinations by adsorptive voltammetry (formazone method) allowed to distinguish between elemental and ionic platinum; in solution samples only ionic platinum has been present. UV spectra of extracts have been used for the semi-quantitative platinum speciation in solutions. 相似文献
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MaxwellD. Cummings Jimmy Lindberg Tse‐I Lin Herman deKock Oliver Lenz Elisabet Lilja Sara Fellnder Vera Baraznenok Susanne Nystrm Magnus Nilsson Lotta Vrang Michael Edlund sa Rosenquist Bertil Samuelsson Pierre Raboisson Kenneth Simmen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2010,122(9):1552-1552
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A. Fuchs M. Bender U. Plachetka L. Kock N. Koo T. Wahlbrink H. Kurz 《Current Applied Physics》2008,8(6):669-674
In the past decade nanoimprint has been developed to a serious alternative for next generation lithography (NGL). In this work, the most recent developments of UV-nanoimprint Lithography (UV-NIL) with special emphasis to the work accomplished at AMO and the IHT-RWTH Aachen are reviewed and functional applications demonstrated. Further the potentials of various UV-NIL concepts are evaluated and possible interests in certain application areas are discussed. 相似文献
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A simple holographic arrangement utilizing the small autocorrelation function of a ground-glass has been tested as a device for detecting automatically displacements, phase distortions, vibrations, misalignments, etc. Experimental results will be given. 相似文献