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1.
A nonlocal Hamiltonian formalism for semi-Hamiltonian systems of the hydrodynamic type is constructed using the formal Baker-Akhiezer
functions for a (2+1)-dimensionaln-wave system.
Translated from Teoreticheskaya i Matematicheskaya Fizika. Vol. 116, No. 1, pp. 113–121 July, 1998. 相似文献
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3.
Vinogradov M. G. Gorshkova L. S. Chel"tsova G. V. Pavlov V. A. Razmanov I. V. Ferapontov V. A. Malyshev O. R. Heise G. L. 《Russian Chemical Bulletin》2003,52(2):471-479
Prochiral substrates (alkyl aryl ketones, cyclopropyl methyl ketone, 1-indanone, 1-tetralone, ethyl 2-oxo-4-phenylbutyrate, and N-(diphenylphosphinyl)acetophenoneimine) were subjected to asymmetric reduction with aluminum hydride reagents, which were prepared by modifications of NaAlH4 or AlH3 with chiral ,,","-tetraaryl-1,3-dioxolane-4,5-dimethanols (TADDOL). The effects of the nature of the substituents in TADDOL, the structure of the prochiral substrate, and the reaction conditions on the stereochemistry of reduction were investigated. The highest enantioselectivity (70—90% ee) was achieved upon reduction of alkyl aryl ketones and N-(diphenylphosphinyl)acetophenoneimine with NaAl(TADDOLate)H2 in THF or diglyme at a temperature from –70 to –20 °C. The mechanism of asymmetric induction in the reduction reactions of ketones with aluminum hydride reagents is discussed. The stereochemical results of reduction were explained by comparing three-dimensional models of the most probable transition states. 相似文献
4.
M. G. Vinogradov L. S. Gorshkova V. A. Ferapontov A. V. Zinenkov 《Russian Chemical Bulletin》1995,44(4):756-758
A selective method for the preparation of 5-chloropentan-2-one by interaction of 1-methylcyclobutanol with Ca(OCl)2 followed by decomposition of the hypochlorite thus obtained in the presence of FeII salt is proposed. The selectivity of the ketone formation from the alcohol is 98%, while the conversion of the alcohol is 35–40%.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 774–776, April, 1995. 相似文献
5.
Yu. A. Ferapontov D. V. Zhdanov M. A. Ul’yanova 《Russian Journal of Applied Chemistry》2007,80(7):1045-1047
Density, viscosity, and surface tension of KOH-H2O2-H2O solutions used to synthesize potassium superoxide in sprayer apparatus were studied with various relative amounts of the components in the temperature range 0–30°C. Analytical dependences of the above-mentioned quantities on temperature and solvent (water) content of the system were found. 相似文献
6.
L. L. Ferapontova N. F. Gladyshev Yu. A. Ferapontov V. V. Rodaev M. A. Umrikhina 《Russian Journal of Applied Chemistry》2013,86(5):790-792
Relationship was found between the temperature of thermal degradation of composite sorption-active materials based on fluorinated ethylene polymers and the content of NaX zeolite in these materials. 相似文献
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Vinogradov M. G. Gorshkova L. S. Chel'tsova G. V. Kurilov D. V. Ferapontov V. A. Shishk O. V. Heise G. L. 《Russian Chemical Bulletin》2003,52(8):1841-1846
An improved procedure was developed for asymmetric reduction of acetophenone and propiophenone by the chiral reagent NaAl(IPTOLate)H2. This procedure is based on isolation of the chiral alcohol that formed as a crystalline host—guest complex with the IPTOL ligand. The enantiomeric enrichment of the product was as high as 97% ee. The ability of IPTOL and its analogs to form host—guest complexes with a number of ether-type solvents, 1-phenylethanol, and 1-phenylpropan-1-ol as well as thermal stabilities of IPTOL-containing complexes with these alcohols were studied. 相似文献
10.
N. B. Ferapontov M. G. Tokmachev A. N. Gagarin 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2009,83(8):1321-1325
The properties of water in solutions of hydrophilic polymers were compared with those in solutions of their monomeric analogues.
The properties of polar groups grafted to polymeric molecules were known to remain unchanged. A comparison of the properties
of water in solutions of polymers and the corresponding monomers under equal conditions therefore allowed us to obtain information
about the influence of polymeric bonds on the properties of water in solutions of polymers. Proceeding from this, we analyzed
the influence of polymeric chains and three-dimensional polymeric network on the activity and concentration of water in solutions
of polymers. 相似文献