Kinetics of thermal dehydration of some bis-(4-aminosalicylato)-diaquo complexes of transition metal ions

The kinetics of thermal dehydration of bis-(4-aminosalicylato)-diaquo complexes of VO(II), Cu(II), Ni(II), Co(II), Fe(II) and Mn(II), were studied. The activation energies and other kinetic parameters have been evaluated. The observed kinetic parameters indicate a first-order reaction. The activation energy of the thermal dehydration decreases in the order: VO(II) > Cu(II) > Co(II) > Ni(II) > Fe(II) > Mn(II), which is also the order for the covalency in the MO bonds.     

Some constructions of two-associate class PBIB designs

Summary Two-associate class PBIB designs, having association schemes of GD orL ₂ types, are constructed by using patterned matrices and by methods of taking unions of sets of blocks.     

Symmetry and classification of certain regular group divisible designs

In this paper it is shown that a regular group divisible (GD) design, with parametersv, b, r, k, ₁, ₂ satisfyingrk – ₂ v + 1 and ₂ = ₁ + 1, must be symmetric (i.e.,v + b). Furthermore, the parameters of such symmetric regular GD designs can be expressed in terms of only two integral parameters.Supported in part by Grant 59540043 (C), Japan.     

Some constructions of PBIB designs

Summary Constructions of three series of regular GD and semi-regular GD designs are given. Furthermore, a series of rectangular PBIB designs is constructed and particular cases of this series which reduce to PBIB designs with two associate classes are also provided. Written while visiting Department of Statistics, University of Indore, India, December 1983 through February 1984.