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The properties of the negative parity states of55Fe and57Fe are investigated in the framework of the intermediate coupling model. In the model, a neutron or a quasineutron is coupled to anharmonic vibrations of the core. Anharmonicities of the vibrations are estimated through the observed properties of the core. Energy levels, spectroscopic factors and electromagnetic properties have been calculated. The results of the present calculations are also compared with available experimental results and other theoretical results. The model reasonably accounts for many of the properties of the low-lying states. 相似文献
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The histone code refers to the complex network of histone post-translational modifications that control gene expression and are of high interest as drivers of a large number of human diseases. We report here on a mix-and-match toolkit of readily available dyes and calixarene host molecules that can be combined to form dye-displacement sensors that respond to a wide variety of cationic peptides. Using the data from only two or three such simple supramolecular sensors as a chemical sensor array produces fingerprints of data that discriminate robustly among many kinds of histone code elements. "Reads" that are accomplished include the discrimination of unmethylated, mono-, di-, and trimethylated lysines on a single histone tail sequence, identification of different modifications and combinations of modifications on a single histone tail sequence, identification of a single modification type in several different sequence contexts, and identification of isomeric dimethylarginine modifications. Reads that are sometimes troublesome for antibodies are achieved. We also report on the ability of the sensor array to report simultaneously on the concentrations and identities of histone modifications. This sensor array discriminates between post-translationally modified analytes without being limited to partners that contain a single, programmed binding interaction. 相似文献
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The effect of the radiative cooling of electrons on the gravitational collapse of cold dust grains with fluctuating electric
charge is investigated. We find that the radiative cooling as well as the charge fluctuations, both, enhance the growth rate
of the Jeans instability. However, the Jeans length, which is zero for cold grains and nonradiative plasma, becomes finite
in the presence of radiative cooling of electrons and is further enhanced due to charge fluctuations of grains resulting in
an increased threshold of the spatial scale for the Jeans instability. 相似文献
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The LSD (Logic for Structure Determination) program gener-ates organic molecular structures from 1D and 2D NMR data without resorting to chemical shift databases. Its use in the res-olution of natural product structure determination problems has been already reported in the literature. This paper describes how data and structures are internally represented and pro-cessed by LSD to build solution structures. 相似文献
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B.P. Minaker 《Mathematical and Computer Modelling of Dynamical Systems: Methods, Tools and Applications in Engineering and Related Sciences》2013,19(3):288-310
In the development of the equations of motion of a rigid multibody system, particularly vehicles, it is quite common to linearize the equations after they are derived, or even to ignore the non-linear terms from the outset. When doing so, the tangent stiffness matrix, i.e., the stiffness term that results from preload of the system rather than physical flexibility, is often ignored. The motion analysis of preloaded mechanical systems, e.g., the ride quality analysis of vehicle suspensions, may be significantly altered by this omission. Explicit expressions for the tangent stiffness matrix for a few of the common constraint types, including the revolute joint and the rolling wheel, are derived in this article. These expressions are coded into software and included in an open-source linear equation of motion generator for rigid multibody systems. A sample automotive suspension system is analysed, comparing the results with and without the tangent stiffness matrix effects; additionally, a benchmark solution is developed using a commercial multibody dynamics code. The results provide confirmation of the significance of the tangent stiffness effect on motion analysis and correlate well with non-linear transient solutions. 相似文献
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Infrared-to-visible wave-length conversion in the Yb3+−Er3+ doped phosphors system has been described by a simple three level model based on two ions mechanism. The excitation in the
range of 900–1000 nm of an IR-photon is first absorbed by Yb3+ ion as a sensitizer attributed to the resonant energy transition in Er3+ ion from 4
I
3/2 → 4
S
15/2 and 1
F
9/2 → 4
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15/2, respectively for green and red emission. The essential energy transfer processes in this system i.e. upconversion from 4
I
11/2 and 1
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13/2, cross-relaxation from 4
S
3/2 and 1
F
9/2 are taken into account. The limitations of the rate-equation approach are examined with a focus on the underlying dynamics
of this rare-earth system. 相似文献