全文获取类型
收费全文 | 732篇 |
免费 | 9篇 |
国内免费 | 5篇 |
专业分类
化学 | 336篇 |
晶体学 | 7篇 |
力学 | 11篇 |
数学 | 266篇 |
物理学 | 126篇 |
出版年
2024年 | 2篇 |
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 10篇 |
2020年 | 5篇 |
2019年 | 13篇 |
2018年 | 32篇 |
2017年 | 26篇 |
2016年 | 32篇 |
2015年 | 18篇 |
2014年 | 19篇 |
2013年 | 48篇 |
2012年 | 33篇 |
2011年 | 40篇 |
2010年 | 40篇 |
2009年 | 27篇 |
2008年 | 42篇 |
2007年 | 40篇 |
2006年 | 41篇 |
2005年 | 42篇 |
2004年 | 31篇 |
2003年 | 23篇 |
2002年 | 30篇 |
2001年 | 11篇 |
2000年 | 9篇 |
1999年 | 11篇 |
1998年 | 7篇 |
1997年 | 5篇 |
1996年 | 7篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 9篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 8篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1976年 | 7篇 |
1975年 | 2篇 |
1974年 | 6篇 |
1960年 | 1篇 |
1934年 | 2篇 |
排序方式: 共有746条查询结果,搜索用时 0 毫秒
1.
Artūras Dubickas 《Proceedings Mathematical Sciences》2005,115(4):391-397
Suppose that α > 1 is an algebraic number and ξ > 0 is a real number. We prove that the sequence of fractional partsξα
n
, n = 1, 2, 3, …, has infinitely many limit points except when α is a PV-number and ξ ∈ ℚ(α). For ξ = 1 and α being a rational
non-integer number, this result was proved by Vijayaraghavan. 相似文献
2.
3.
4.
Wanpracha Art Chaovalitwongse Oleg A. Prokopyev Panos M. Pardalos 《Annals of Operations Research》2006,148(1):227-250
Epilepsy is among the most common brain disorders. Approximately 25–30% of epilepsy patients remain unresponsive to anti-epileptic
drug treatment, which is the standard therapy for epilepsy. In this study, we apply optimization-based data mining techniques
to classify the brain's normal and epilepsy activity using intracranial electroencephalogram (EEG), which is a tool for evaluating
the physiological state of the brain. A statistical cross validation and support vector machines were implemented to classify
the brain's normal and abnormal activities. The results of this study indicate that it may be possible to design and develop
efficient seizure warning algorithms for diagnostic and therapeutic purposes.
Research was partially supported by the Rutgers Research Council grant-202018, the NSF grants DBI-980821, CCF-0546574, IIS-0611998,
and NIH grant R01-NS-39687-01A1. 相似文献
5.
J. Požela A. Namajūnas A. Tamaševičius J. Ulbikas 《Applied Physics A: Materials Science & Processing》1989,48(2):181-188
A method for quantitative characterization of chaotic dynamical systems is discussed. An electronic instrument for determining the number of independent variablesk
*, involved in the motion, is described. It allows one to obtain these in real time from a single observable. The suggested technique has been applied to quantification of strange attractors underlying chaotic instabilities in semi-insulating GaAsCr, and n-Ge, irradiated with high energy electrons. In n-Ge, for instance, the measured numbersk
* range from 2 to 4 depending on control parameters. These measurements reveal the highly deterministic nature of the observed chaotic oscillations. The physical mechanisms responsible for the current instabilities and chaotic behaviour are discussed. 相似文献
6.
[reaction: see text] Catalytic, enantioselective Mannich-type reactions of alpha-imino esters bearing readily removable substituents on nitrogen are described. Several N-carbamate-protected alpha-imino esters, which are readily prepared from 2-bromoglycine esters using a polymer-supported amine, reacted with silicon enolates to afford the desired adducts in high yields with high enantioselectivity using a copper(II)-diamine complex. Easy deprotection of the product amine and transformation to free alpha-amino acid derivatives have also been demonstrated. 相似文献
7.
Gun'ko VM Villiéras F Leboda R Marciniak M Charmas B Skubiszewska-Zi&ecedil;ba J 《Journal of colloid and interface science》2000,230(2):320-327
Adsorbents synthesized by grafting of titania onto mesoporous silica gel surfaces at different temperatures were studied by means of nitrogen adsorption–desorption and water desorption. The pore size distribution f(Rp) of titania/silica gel depends on the titania concentration (CTiO2) and the temperature of titania synthesis. Nonuniformity of TiO2 phase is maximal at a low CTiO2 value (3.2 wt.% anatase deposited at 473 K), and two peaks of the fractal dimension distribution f(D) are observed at such a concentration of titania, but at larger CTiO2 values, only one f(D) peak is seen. More ordered filling of pores and adsorption sites by nitrogen, reflecting in the shape of adsorption energy distributions f(E) at different pressures of adsorbate, is observed for adsorbent with titania (rutile+anatase) grafted on silica gel at a higher temperature (673 K). 相似文献
8.
Žydrė Šaltienė Natalija Jatulienė Mudis Šalkauskas Daiva Brukštienė Asta Ruzgytė Aušra Tarasevičiūtė Julius Kalibatas 《Accreditation and quality assurance》2005,10(8):444-451
The estimation scheme of uncertainty of determination of 1-hydroxypyrene (1-OHP) in urine was developed analysing the main
stages of the analytical procedure: (1) preparation of 1-OHP standards, (2) creation of the calibration curve for the high
performance liquid chromatography (HPLC) analysis method with the evaluation of recovery, (3) measuring procedure of aliquot
of urine, (4) adjusting the pH of aliquot and hydrolysis with enzyme, (5) solid phase extraction, (6) concentration of the
extract, (7) injection of the extract to chromatograph and analysing by the HPLC method, (8) calculation of 1-OHP mass from
the calibration curve, (9) calculation of 1-OHP concentration in urine. The evaluation of the uncertainty is based on quantification
of individual components. Combined uncertainty was calculated using the law of propagation of uncertainties according to the
EURACHEM/CITAC guidelines. Level dependence of the uncertainty arises from the calibration curve.
The limits of detection and quantification were found to be equal to 0.03 and 0.1 ng/mL, respectively. The calculated expanded
level-dependent uncertainty covers 47–27–25% within the concentration range 0.03–0.1–0.4 ng/mL with the materials and equipment
used. These parameters could easily be recalculated according to the proposed scheme if there are some changes in the analysis
procedure. 相似文献
9.
Manabe K Iimura S Sun XM Kobayashi S 《Journal of the American Chemical Society》2002,124(40):11971-11978
Dehydration reactions in water have been realized by a surfactant-type catalyst, dodecylbenzenesulfonic acid (DBSA). These reactions include dehydrative esterification, etherification, thioetherification, and dithioacetalization. In these reactions, DBSA and substrates form emulsion droplets whose interior is hydrophobic enough to exclude water molecules generated during the reactions. Detailed studies on the esterification revealed that the yields of esters were affected by temperature, amounts of DBSA used, and the substrates. Esters were obtained in high yields for highly hydrophobic substrates. On the basis of the difference in hydrophobicity of the substrates, unique selective esterification and etherification in water were attained. Furthermore, chemospecific, three-component reactions under DBSA-catalyzed conditions were also found to proceed smoothly. This work not only may lead to environmentally benign systems but also will provide a new aspect of organic chemistry in water. 相似文献
10.
The present short review deals with electroanalytical aspects of electrochemical response of ascorbic acid (Vitamin C) at conducting and electrogenerated polymer modified electrodes. Two main topics are considered: (i) electrocatalytic oxidation of ascorbate at conducting polymer modified electrodes, leading to electroanalytical techniques for ascorbate assay, and (ii) retardation of ascorbate penetration through a layer of electrogenerated polymers, leading to permselective coatings and their diverse uses, especially for biosensing devices. 相似文献