全文获取类型
收费全文 | 53篇 |
免费 | 3篇 |
国内免费 | 16篇 |
专业分类
化学 | 44篇 |
力学 | 6篇 |
数学 | 15篇 |
物理学 | 7篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 1篇 |
2019年 | 2篇 |
2018年 | 3篇 |
2017年 | 2篇 |
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 3篇 |
2013年 | 2篇 |
2012年 | 2篇 |
2011年 | 4篇 |
2010年 | 5篇 |
2009年 | 5篇 |
2008年 | 4篇 |
2007年 | 2篇 |
2006年 | 4篇 |
2005年 | 5篇 |
2004年 | 1篇 |
2003年 | 2篇 |
2002年 | 2篇 |
2001年 | 1篇 |
2000年 | 5篇 |
1999年 | 4篇 |
1998年 | 4篇 |
1994年 | 1篇 |
1990年 | 1篇 |
1986年 | 1篇 |
1983年 | 2篇 |
排序方式: 共有72条查询结果,搜索用时 15 毫秒
1.
2.
The molecular structures and electron affinities of eight radicals derived from the halide benzene by removing a hydrogen atom have been determined using seven hybrid Hartree-Fock/density-functional methods. The basis set used in this work is of double-zeta plus polarization quality with additional diffuse s- and p-type functions, denoted as DZP++. These methods have been carefully calibrated [J. C. Rienstra-Kiracofe, G. S. Tschumper, H. F. Schaefer, S. Nandi, and G. B. Ellison, Chem. Rev. (Washington, D. C.) 102, 231 (2002)]. The geometries are fully optimized with each density-functional theory method and discussed, respectively. The three different types of the neutral-anion energy separations reported in this work are the adiabatic electron affinity, the vertical electron affinity, and the vertical detachment energy. The most reliable adiabatic electron affinities (with zero-point vibrational energy correction), obtained at the DZP++ B3LYP level of theory, are 1.74 eV (o-C6H4F), 1.39 eV (m-C6H4F), 1.34 eV (p-C6H4F), 1.78 eV (o-C6H4Cl), 1.53 eV (m-C6H4Cl), 1.45 eV (p-C6H4Cl), 2.06 eV (o-C6H3F2), and 2.04 eV (p-C6H3F2), respectively. Compared with the experimental values, the average absolute error of the B3LYP method is 0.03 eV. The BLYP, BP86, and BPW91 functionals also gave excellent predictions, with average absolute errors of 0.05, 0.08, and 0.08 eV, respectively. 相似文献
3.
In this paper,we establish the global existence and uniqueness of the solution of the Cauchy problem of a one-dimensional compressible isentropic Euler system f... 相似文献
4.
5.
6.
7.
屈爱芳 《数学年刊A辑(中文版)》2011,32(2):245-256
描述理想的低温等离子体中电磁波传播的模型是一个椭圆双曲混合型方程.证明了该方程闭Dirichlet问题弱解的存在唯一性.该结果关于区域的几何结构要求较少.由于这里所讨论的方程的奇异性与Keldysh方程的奇异性有相似性质,而后者的奇异性比Tricomi方程更强,因此关于其正则性的研究是很有意义的.作者给出了一个内正则性结果. 相似文献
8.
In this paper, finite groups having exactly two conjugate classes of non-subnormal subgroups of G are completely classified. 相似文献
9.
There is a growing need for cellular imaging with fluorescent probes that emit at longer wavelengths to minimize the effects of absorption, autofluorescence, and scattering from biological tissue. In this paper a series of new environmentally sensitive hemicyanine dyes featuring amino(oligo)thiophene donors have been synthesized via aldol condensation between a 4-methylpyridinium salt and various amino(oligo)thiophene carboxaldehydes, which were, in turn, obtained from amination of bromo(oligo)thiophene carboxaldehyde. Side chains on these fluorophores impart a strong affinity for biological membranes. Compared with benzene analogues, these thiophene fluorophores show significant red shift in the absorption and emission spectra, offering compact red and near-infrared emitting fluorophores. More importantly, both the fluorescence quantum yields and the emission peaks are very sensitive to various environmental factors such as solvent polarity or viscosity, membrane potential, and membrane composition. These chromophores also exhibit strong nonlinear optical properties, including two-photon fluorescence and second harmonic generation, which are themselves environmentally sensitive. The combination of long wavelength fluorescence and nonlinear optical properties make these chromophores very suitable for applications that require sensing or imaging deep inside tissues. 相似文献
10.
In this article, the measure space associated with a continuous frame is supposed to be σ-finite and positive, and a frame range is the range of the analysis operator for a continuous frame. Gabardo and Han in 2003 asked whether two frame ranges can both be contained in another one. To solve this problem, we give two decompositions of analysis operators and frame ranges for continuous frames respectively, which essentially establish a relationship between continuous frames and Hilbert-Schmidt operator valued frames. As applications, it follows that only separable Hilbert space can have a continuous frame, that there exists a continuous frame of Riesz-type if and only if the associated measure space is purely atomic, and that the sum of two frame ranges is still a frame range when the sum is closed. Finally, we construct a counterexample which shows that the Gabardo-Han problem is not necessarily true in general. 相似文献