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Katalytische Epoxidierung und 1,2‐Dihydroxylierung von Olefinen mit Bispidin‐Eisen(II)/H2O2‐Systemen
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Nathalie Charton Achim Feldermann Alexander Theis Martina H. Stenzel Thomas P. Davis Christopher Barner‐Kowollik 《Journal of polymer science. Part A, Polymer chemistry》2004,42(21):5559-5559
The original article to which this Erratum refers was published in J Polym Sci Part A: Polym Chem (2004) 42(20) 5170–5179. No abstract. 相似文献
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Reinhard Schubert Achim Ansmann Paul Bleckmann Bernhard Schrader 《Journal of Molecular Structure》1975,26(2):429-438
By using the values of the vibrational frequencies of normal and deuterated cyclopropenone (II-d0 , II-d2 ) and 16 O-and 18 O-substituted dimethylcyclopropenone (III) as -well as the infrared and Raman intensities of II a consistent set of force constants has been derived for the cyclopropenone skeleton. The derived values show that the zwitterionic form makes a substantial contribution to the electronic ground state of the molecule. The combined frequency and intensity calculation - simulation of the infrared and the Raman spectrum - is shown to be a good method for making a proper assignment of calculated and observed vibrations and deriving realistic sets of force constants. 相似文献
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Pan F Wang P Lee K Wu A Turro NJ Koberstein JT 《Langmuir : the ACS journal of surfaces and colloids》2005,21(8):3605-3612
We report a simple photolithographic approach for the creation and micropatterning of chemical functionality on polymer surfaces by use of surface-active block copolymers that contain protected photoactive functional groups. The block copolymers self-assemble at the substrate-air interface to generate a surface that is initially hydrophobic with low surface tension but that can be rendered hydrophilic and functional by photodeprotection with UV radiation. The block copolymer employed, poly(styrene-b-tert butyl acrylate), segregates preferentially to the surface of a polystyrene substrate because of the low surface tension of the polyacrylate blocks. The strong adsorption of block copolymers causes a bilayer structure to form presenting a photoactive polyacrylate layer at the surface. In the example described, the tert-butyl ester groups on the polyacrylate blocks are deprotected by exposure to UV radiation in the presence of added photoacid generators to form surface carboxylic acid groups. Surface micropatterns of carboxylic acid groups are generated by UV exposure through a contact mask. The success of surface chemical modification and pattern formation is demonstrated by X-ray photoelectron spectroscopy and contact angle measurements along with imaging by optical and fluorescence microscopy methods. The resultant chemically patterned surfaces are then used to template patterns of various biomolecules by means of selective adsorption, covalent bonding and molecular recognition mechanisms. The surface modification/patterning concept can be applied to virtually any polymeric substrate because protected functional groups have intrinsically low surface tensions, rendering properly designed block copolymers surface active in almost all polymeric substrates. 相似文献