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1.
In order to investigate the relative effects of the differences between the structures and lipophilicities of 1, 10-dioxa-4, 7, 13, 16-tetra-azacyclo-octadecane (TA-18-crown-6) and the tetrabenzyl derivative of 1,10-dioxa-4, 7, 13, 16-tetra-azacyclo-octadecane (TBTA-18-crown-6) on their extraction-abilities and -selectivities for transition metal cations, constants of the overall extraction (logK
ex) of 1:1 (M:L) complexes, the distribution (K
D) for two diluents (CH2Cl2 and CHCl3) with different dielectric constants have been determined at 25 ± 0.1 °C. The magnitude of logK
ex is largely determined by that of K
D. The equilibrium constants of TA-18-crown-6 have been compared with those of TBTA-18-crown-6. It is found that:(i) logK
ex sequences of TA-18-crown-6 and TBTA-18-crown-6 for transition metals in CH2Cl2 lie in order: Fe3+ > Cu2+ > Mn2+ > Co2+ > Cd2+ > Ni2+ > Zn2+ and Fe3+ > Cu2+ > Co2+ > Mn2+ > Ni2+ > Cd2+ > Zn2+ respectively; (ii) the stability sequences of two types of tetra-aza-crown ethers with the transition metal cations in CHCl3 are the same as follows: Fe3+ > Ni2+ > Cu2+ > Co2+ > Zn2+ > Cd2+ > Mn2+, and (iii) unusual selectivities are observed for transition metal-tetra-aza-crowns, e.g. the high Fe3+/M
n+ selectivity factors (Sf) of TA-18-crown-6, except for the competitive-extractions for the special case in CHCl3 of TBTA-18-crown-6, it was found that the Mn2+/M
n+ values were relatively higher according to the other transition metal cations. A systematic sequence in these two types of solvents is not found for a given transition metal cation in terms of the variation of selectivity with the tetra-aza-crown ethers. The results provide alternatives for the rational design of other specific ligands on the transition metal cations. 相似文献
2.
Mustafa Çelebier Ertan Şahin Nilgün Ancın Nurşen Altuntaş Öztaş Selma Gül Öztaş 《应用有机金属化学》2007,21(10):viii-viii
The article referenced above was first published online on 30 August 2007 with incorrect pagination; the pagination has now been corrected online and in print. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
3.
We consider a multiperiod mean-variance model where the model parameters change according to a stochastic market. The mean
vector and covariance matrix of the random returns of risky assets all depend on the state of the market during any period
where the market process is assumed to follow a Markov chain. Dynamic programming is used to solve an auxiliary problem which,
in turn, gives the efficient frontier of the mean-variance formulation. An explicit expression is obtained for the efficient
frontier and an illustrative example is given to demonstrate the application of the procedure. 相似文献
4.
水下光通信充分利用了海水对激光的衰减窗口效应,具有隐蔽、安全、非接触和快速机动等特性,兼具无线通信和光纤通信的优点,其关键技术在于光收发端机的研制;PPM(Pulse Position Modulation)数字脉冲位置调制具有低平均功率和高峰值功率等特性,特别适合用于无线数字光通信。两者性能的融合需要高灵敏度数字光接收机的实现。利用阵列光电检测接收、高速A/D转换和信号处理等相关技术,采用DSP处理器,高灵敏度的数字光PPM接收机得以实现,实验和测试表明它大大降低了接收机对于整个系统信噪比的要求,获得了较好的性能。 相似文献
5.
The spectral structure of two parameter unbounded operator pencils of waveguide type is studied. Theorems on discreteness
of the spectrum for a fixed parameter are proved. Variational principles for real eigenvalues in some parts of the root zones
are established. In the case of n = 1 (quadratic pencils) domains containing the spectrum are described (see Fig. 1–3). Conditions in the definition of the
pencils of waveguide type arise naturally from physical problems and each of them has a physical meaning. In particular a
connection between the energetic stability condition and a perturbation problem for the coefficients is given. 相似文献
6.
AO Sheng-Mei YAN Jia-Ren 《理论物理通讯》2007,47(1):15-18
Three types of expression in the dark-soliton perturbation theory based on squared Jost solutions are invesgigaged in ghis paper. It is shown that there are three formally different results about the effects of perturbagion on a dark soliton, and it is proved by means of a transformation between two integral variables that they are essentially equivalent. 相似文献
7.
A. Varinlioĝlu A. Köse U. Çevik A. I. Kopya M. Altunbaş H. Karal 《Journal of Radioanalytical and Nuclear Chemistry》1995,201(1):31-37
Sediment samples collected from the Eastern Black Sea in 1993 from 15 sampling stations of different depths have been analyzed. Natural and artifical radionuclide activity levels in offshore sediment samples from the Eastern Black Sea in Turkey are reported about seven years after the Chernobyl accident. The purpose of this paper is to follow up the earlier study and present results for the distributions of radionuclides in sediments of the Black Sea. 相似文献
8.
9.
α-Aspartame (L-α-aspartyl-L-phenylalanine methyl ester) is increasingly being used in wide variety of commonly consumed food products. This structure contains ester and peptide bonds. The ester linkage may hydrolyze to produce L-α-aspartyl-L-phenylalanine or cyclohydrolyze to produce the corresponding diketopiperazine ring. This ring can open to form L-α-aspartyl-L-phenylalanine and ultimately this compound can hydrolyze to L-phenylalanine and L-aspartic acid. The pH, buffer type, concentration, the presence of water and temperature are other important factors affecting its stability. Because α-aspartame can lose its sweetness under these conditions determination of aspartame and its breakdown products is extremely important for diet foods quality. The optimum mobile phase for the chromatographic separation was found to be acetonitrile-water (20:80, ν/ν) with 5.10?3 M hexanesulfonic acid and a pH of 2.6. 相似文献
10.
H. Yücel H. Karadeniz M. A. Çetiner H. Demirel Ş. Turhan 《Journal of Radioanalytical and Nuclear Chemistry》2003,258(2):445-447
The sorption behavior of 235U fission fission products 99Mo and 132Te was studied through batch and dynamic experiments when they were dissolved in 1 to 7M HNO3 solutions. It was found that 99Mo is always totally adsorbed on hydrated SnO2, while 132Te is rather weakly adsorbed, therefore they can be separated from each other although 132Te in the solution still remains contaminated with other radionuclides as well as 99Mo does in the solid. 相似文献