Chemoselective Catalytic Hydrogenation of α,β-Unsaturated Ketones and α,β-Unsaturated Carboxylic Esters

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Synthesis and Magnetism of 2-Hydroxy-1,3-propylene-bis(oxamato)-bridged Co~ⅡCu~ⅡCo~Ⅱ Complexes

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Spectroscopic Studies of a Three-dimensional, Five-coordinated Copper(Ⅱ) Complex via Hydrogen Bonds: [Cu(PDA)(H_2O)_2](H_2PDA=Pyridine-2,6-dicarboxylic Acid)

IntroductionFive- coordinated complexes with d9- configuredcations have received much attention stereochemi-cally,spectrochemically and biologically,and havebeen comprehensively discussed[1] . Usually thereare two stable configurations for the copper( )complexes with five equal coordinating atoms:anapically elongated square pyramid( SP) and a com-pressed trigonal bipyramid( TBP) ,with an obviousenergetic preference for the latter coordination.When the ligands are rigid and provide angular d…     

非均衡经济计量模型专题讲座——第二讲 样本分割未知的非均衡模型

样本分割未知,是指没有任何信息能把非均衡模型的样本分割成需求和供给两部分,这样就不能直接估计需求方程和供给方程,需要采用间接的方法,用可观察的市场成交量Qt代替不可观察的需求量Dt和供给量St,再估计参数,这时,最大似然法是估计样本分割未知模型的一种合适方法. 一、样本分割未知模型的最大似然估计 考虑下列最简单的样本分割未知的非均衡模型:这里,α0、β0是未知参数的向量,X1t、X2t是外生变量向量,μ1t、μ2t分别服从均值为零、方差为σ1 2、σ2 2的正态分布,并同期相互独立,无序列相关. 由于样本分割未知,我们不能把观测值Qt的…     

Structure of Cytochromec and Its Platinum-modified Derivatives by Fourier Transform Infrared Spectroscopy

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Interplay between phase defects and spin polarization in the specific heat of the spin-density-wave compound (TMTTF)2Br in a magnetic field

Equilibrium heat relaxation experiments provide evidence that the ground state of the commensurate spin-density-wave compound (TMTTF)2Br after the application of a sufficient magnetic field is different from the conventional ground state. The experiments are interpreted on the basis of the local model of strong pinning as the deconfinement of soliton-antisoliton pairs triggered by the Zeeman coupling to spin degrees of freedom, resulting in a magnetic-field-induced density-wave glass for the spin carrying the phase configuration.     

Influence of saccharide size on the cellular immune response to glycopeptides

Glycopeptides that bind to MHC molecules on antigen presenting cells may elicit carbohydrate selective T cells. In order to investigate how the cellular immune response depends on the size of the carbohydrate moiety, a trigalactosylated derivative of an immunogenic peptide from hen egg-white lysozyme (HEL52-61) was prepared. Synthesis was accomplished by assembly of an alpha-1,4-linked trigalactose peracetate which was coupled to Fmoc serine. After activation as a pentafluorophenyl ester the resulting building block was used in solid-phase synthesis In contrast to the corresponding mono- and digalactosylated derivatives of HEL52-61, the trigalactosylated HEL52-61 was not immunogenic. Somewhat surprisingly, this was found to be because the trigalactosyl derivative bound approximately two orders of magnitude weaker to I-Ak MHC molecules than the mono- and digalactosyl peptides. Our observation suggests an explanation for previous findings, which show that glycopeptides isolated from MHC molecules in nature usually carry small saccharides.