油水两液相一维非等温渗流的传递分析

在求解油水两液相非等温渗流的温度场、压力场基础上,以驱动功、驱动功率、驱动阻力、驱动速率为特征参数,对该过程进行(火用)传递分析。数值模拟的结果表明:含水通过降低油的相对渗透率、从而增大驱动阻力、减小驱动功率, 最终导致原油产量降低。     

Structure and Photosynthetic Mimicking of Bis(2,6-bis(benzimidazol-2-yl)pyridine)manganese(II)

Introduction　　Manganeseionsplayanimportantroleinthelight in ducedoxidationofwatertomolecularoxygeninphotosys temII (PSII)ofgreenplants.1 3Inrecentyears ,man ganesecomplexesofpolypyridineligands ,suchasbipyri dine ,1,10 phenanthrolineand 2 ,2′:6′,2″ terpyridine ,havehadconsiderableattentionasthecomplexesformedareusefulmodelsformanganese containingbimolecu lars .4 6 Therefore ,synthesisandcharacterizationofman ganeseinitsvariousoxidationstates ,withvariousligandtypesandnuclearities ,hav…     

稳定直线型硝酮加-O-·2 合物的构型因素解析

对生命体系中的氧自由基, Spin trapping-ESR方法是公认的特征分析手段[1].然而, 对超氧阴离子自由基(O-·2)而言, 其自由基加合物稳定性差.对此,人们通过改变硝酮的取代基团, 设计出更为有效的O-·2捕获探针[2,3].     

Dual-wavelength distributed Bragg reflector semiconductor laser based on a composite resonant cavity

We report a monolithic integrated dual-wavelength laser diode based on a distributed Bragg reflector (DBR) composite resonant cavity. The device consists of three sections, a DBR grating section, a passive phase section, and an active gain section. The gain section facet is cleaved to work as a laser cavity mirror. The other laser mirror is the DBR grating, which also functions as a wavelength filter and can control the number of wavelengths involved in the laser action. The reflection bandwidth of the DBR grating is fabricated to have an appropriate value to make the device work at the dual-wavelength lasing state. We adopt the quantum well intermixing (QWI) technique to provide low-absorption loss grating and passive phase section in the fabrication process. By tuning the injection currents on the DBR and the gain sections, the device can generate 0.596 nm-spaced dual-wavelength lasing at room temperature.     

基于非齐次复合Poisson过程的正交异性钢桥面板细节疲劳裂纹随机扩展研究

传统的正交异性钢桥面板疲劳损伤评估常采用确定性和可靠性分析方法,忽略了疲劳裂纹扩展的随机性影响,针对这一问题,提出钢桥面板细节疲劳随机扩展分析方法。本文以南溪长江大桥为工程背景,基于长期车辆荷载监测数据,建立了车辆荷载非齐次复合Poisson过程模型。建立钢桥面板有限元模型,采用瞬态分析方法将随机车辆荷载转化成细节疲劳应力,基于线弹性断裂力学理论推导U肋-顶板焊接细节疲劳裂纹扩展时变微分方程,实现宏观关系式疲劳应力幅次数-疲劳损伤至微观表达式应力时间序列-疲劳损伤转换,讨论了车载次序及超载对疲劳裂纹扩展的影响。研究结果表明,非齐次复合泊松过程模型能够较好描述随机车流运营状态,车辆荷载的次序对疲劳裂纹扩展速率的影响不可忽略,重车排序靠前时能够促使疲劳裂纹扩展增速,南溪长江大桥细节点的车辆超载迟滞效应修正系数取值0.804。     

荧光自旋捕获探针的合成及ESR捕获研究

设计合成了具有荧光基团的新型硝酮类自由基捕获探针并对其结构进行了表征.自由基捕获实验结果表明,该探针能实现对超氧阴离子自由基与碳中心自由基的捕获.此外,该自由基捕获探针反应产物的荧光强度与被捕获自由基浓度之间存在相关性,有望建立依据荧光强度分析被捕获自由基浓度的新方法.     

基于血红蛋白、血红素的亚硝酸盐传感器的构建及应用研究

意义：本研究为构建基于血红素蛋白的亚硝酸盐传感器打下一定基础。目的：本研究构建了包埋于壳聚糖（CS）膜中的血红蛋白（Hb）和血红素（Hemin）的亚硝酸盐传感器。研究了它们在电极表面的电化学活性。方法：在pH 4.0 PBS,利用示差脉冲伏安法（DPV）分别研究CS/Hb-GCE、CS/Hb-GCE对亚硝酸盐的电化学响应,基于此建立了对亚硝酸盐的电化学测定方法。结论： CS/Hb-GCE修饰电极对亚硝酸盐响应的线性范围为0.069～25.86 mmol/L,检测限为0.012 mmol/L。CS/Hemin-GCE对NO2-响应的线性范围0.50～16.67 mmol/L,检测限为0.25 mmol/L。发现CS/Hb-GCE修饰电极对NO2-响应具有更低的检测限和更宽的线性范围,对其可能的原因进行了探讨。     

PPV-PDMeOPV共聚物发光性质的实验和理论研究

具有优良电致发光性能的有机聚合物材料的研制及其发光性能和应用的研究是９０年代新兴的高科技领域．聚对苯乙炔［Ｐｏｌｙ（ｐ－ｐｈｅｎｙｌｅｎｅｖｉｎｙｌｅｎｅ）,缩写为ＰＰＶ,又称聚苯撑乙烯］是这一领域最先研制出来的具有代表性的材料［１,２］．为改变ＰＰ...     

油田注水系统拓扑布局优化的混合遗传算法

以投资最小为目标函数,建立了注水系统拓扑布局优化数学模型.根据模型特点,将优化问题分为两层,分别采用遗传算法和非线性优化方法进行求解.并对遗传算法的操作过程进行了改进,调整了适应函数,改进了交叉和变异操作,结合了模拟退火算法,在操作过程中使约束条件得到满足,减少了不可行解的产生,使遗传算法的优化性能得到了提高.优化算例说明了该方法的有效性.     

Lattice Boltzmann Simulation for the Optimized Surface Pattern in a Micro-Channel

Based on the Bhatangar-Gross-Krook （BGK） models, numerical simulation using the lattice Boltzmann model is performed to investigate the optimized surface pattern in a micro-channel. In order to simulate the practical situation correctly, a slip/no-slip boundary condition is applied with making several assumptions. To assess the validity and efficiency of the model, one benchmark problem with considering the surface patterns is studied. Numerical results show the value of rms velocity Vrms increases with the increasing ratio β and larger Reynolds number Re, higher fluctuation of the rms oscillating velocity. Furthermore, the results show that a good mixing effect can be obtained when Re is large enough and the ratio β is about 1.618,which is the appropriate choice, i.e. the well known golden section phenomenon.