离心力场作用下多孔介质中强制对流换热的研究

对离心流化床中空气通过多孔物料层的强制对流换热进行了理论和实验研究。获得了气流和物料间强制对流换热的准则关联式。研究结果表明,在气流速度和温度梯度方向一致的条件下,强制对流换热比通常的边界层强制对流换热有所强化,其换热的准则关联式具有 Nu=CRePr的线性形式。从而验证了改变气流方向和热流密度矢量之间夹角可以强化换热的这一强化传热新原理。     

Cyclization of β-allenyloximes as a novel method for nitrone preparation

Two different procedures for β-allenyloxime cyclization are described. One leads to substituted 1-hydroxypyrrolidines and the other represents a new route to pyrroline-N-oxides.     

Asymmetric synthesis of homo-apioneplanocin A from d-ribose

Homo-apioneplanocin A was efficiently synthesized via stereoselective hydroxymethylation, regio- and chemoselective hydroboration, and chemoselective oxidation as key steps from d-ribose.     

AAS测定纸巾中的铅和镉

本文采用原子吸收光谱法测定纸巾中铅、镉的含量。结果表明，不同纸巾中的污染元素铅、镉的含量不同。同时还对一种纸巾的铅、镉元素进行了回收实验，回收率在92％-104％之间。     

GM(1,1)的周期修正模型及其在泉水流量预测中的应用

本文阐述了 GM( 1 ,1 )的残差周期修正模型 ,并将它应用于山西神头泉的流量预测中 ,建立了神头泉流量的 GM( 1 ,1 )周期修正模型 ,对其流量进行了预测 ,为神头泉域岩溶水资源开发利用和保护提供了科学依据     

Roles of rhenium diimine complexes as metal‐ion probes and photosensitizers in functional polyurethanes

Polyurethanes incorporated with rhenium diimine complexes were synthesized. The polymers exhibited interesting morphologies and solution properties. Results from gel permeation chromatography suggested the formation of polymer aggregates in solutions. The polymers could act as probes for metal ions. The addition of metal ions to polymer solutions led to significant changes in the electronic absorption properties of the polymer solutions. This was attributed to the interactions between the polyether moieties and metal ions. The metal complexes could also act as efficient photosensitizers. After doping with charge‐transport viologens, the photoconductivity of the polymers was greatly enhanced. The experimental quantum efficiency was simulated with Onsager's theory. The thermalization distances and the primary yields were typically 12–14 Å and 10^?3, respectively. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1708–1715, 2003     

Banach空间非线性混合型微分-积分方程整体解的存在性和唯一解

研究了Banach空间中非线性混合型微分-积分方程初值问题u′=f(t,u,Tu,Su),u(0)=x0的整体解,完全没有要求f的任何增性,利用Mnch不动点定理和比较结果得到了初值问题整体解的存在性和唯一解,并且给出了一致收敛于唯一解的迭代序列,改进推广和统一了已有的许多结果.     

复注及多孔注浆理论研究

针对柱面注浆方式，研究了有关渗透注浆的单孔复注及不同方式布孔时多孔注浆的相互影响等问题，推导出一些有价值的岩体注浆理论公式，可用于指导现场注浆工程的设计与施工．