A new Sequiterpenoid from Eupatorium adenophorum Spreng

A new sequiterpenoid compound 8aα-hydroxy-1-isopropyl-4,7-dimethyl-1,2,3,4,6,8a-hexahydro-naphthalene-2,6-dione(1),together with seven known compounds anti-HH-dimer-coumarin(2),(-)-5-exo-hydroxy-bomeol(3),O-hydroxyl cinnamic acid(4),9β-hydroxy-ageraphorone(5),10Hα-9-oxo-ageraphorone(6),10Hβ-9-oxo-ageraphorone(7)and 9-oxo-10,11-dehydroageraphorone 8,was isolated from the leaves of Eupatorium adenopho-rum Spreng.The structures were elucidated by IR,~1H and ~(13)C NMR,EIMS,HMBC and single-crystal X-ray spec-tral data.     

线性权互补问题的新全牛顿步可行内点算法

基于一个连续可微函数,通过等价变换中心路径,给出求解线性权互补问题的一个新全牛顿步可行内点算法.该算法每步迭代只需求解一个线性方程组,且不需要进行线搜索.通过适当选取参数,分析了迭代点的严格可行性,并证明算法具有线性优化最好的多项式时间迭代复杂度.数值结果验证了算法的有效性.     

S空位调节扶手型二硫化钼纳米带的电子性质

二硫化钼纳米带按边界结构特征可分为锯齿型和扶手型,在制备过程中,不可避免地会存在一定的缺陷,其中硫空位(VS)最为常见,它将改变纳米结构,进而影响其电子性质。本文采用密度泛函理论来研究S空位对扶手型二硫化钼纳米带性质的影响。计算结果表明：纯扶手型二硫化钼纳米带（AMoS2NRs）为非磁性半导体,但其物性受S空位的位置及浓度所调制。当S空位出现在纳米带内部时,其性质不变。但当S空位在纳米带边缘时,AMoS2NRs被调节成半金属;并随着S空位的浓度的增加,其物性从半金属转变为稀磁半导体。这一有趣的发现将使得低维MoS2纳米材料在自旋电子学上有更宽广的应用。     

Enhanced ferroelectricity and ferromagnetism in Bi0.9Ba0.1FeO3/La2/3Sr1/3MnO3 heterostructure grown by pulsed laser deposition

Bi0.9Ba0.1FeO3(BBFO)/La2/3Sr1/3MnO3(LSMO) heterostructures are fabricated on LaAlO3(100) substrates by pulsed laser deposition. Giant remnant polarization value(～ 85 μC/cm2) and large saturated magnetization value(～ 12.4 emu/cm3) for BBFO/LSMO heterostructures are demonstrated at room temperature. Mixed ferroelectric domain structures and low leakage current are observed and in favor of enhanced ferroelectric properties in the BBFO/LSMO heterostructures. The magnetic field-dependent magnetization measurements reveal the enhancement in the magnetic moment and improved magnetic hysteresis loop originating from the BBFO/LSMO interface. The heterostructure is proved to be effective in enhancing the ferroelectric and ferromagnetic performances in multiferroic BFO films at room temperature.     

三环型波导微环谐振器无热化生物传感器

针对温度波动对生物传感器探测性能的影响,本文提出了一种三环型波导微环谐振器无热化生物传感器。传感器芯片以3个微环谐振器为一个传感单元,3个微环谐振器并联排列,且分别工作在1 500、1 550和1 580 nm波长,以其中两个为基本探测微环,另外一个作为备用微环。由于3个微环工作波长不同,可通过运算消去温度对探测谱线变化值的影响项,从而实现传感器的无热化探测。相对于传统的无热化方案,本方案制备材料不受限,且无需参考微环,不存在浪费面积,集成度更高。另外备用微环的设计可以防止部分微环工作失常时传感器无法工作情况的发生,提高了系统的稳定性及可靠性。     

不同应力下的双层钙钛矿锰氧化物La1.3Sr1.7Mn2O7薄膜输运特性研究

采用脉冲激光沉积(PLD)法分别在SrTiO3(100)、LaAlO3 (100)和MgO(100)单晶基片上制备了双层钙钛矿锰氧化物La13Sr17Mn2O7(LSMO)薄膜.X射线衍射谱表明三个样品均沿衬底的晶向择优生长;原子力显微镜显示薄膜表面均光滑致密.采用标准四探针法对薄膜的阻温特性进行了研究,发现SrTiO3 (100)和LaAlO3(100)基片上生长的薄膜呈现出明显的金属-绝缘体转变,转变温度分别为340 K和330 K.而在MgO基片上显示绝缘体态,无金属-绝缘体转变.结合阻温曲线的拟合及薄膜与衬底的晶格失配计算,从薄膜应力和激活能变化的角度分析了样品出现不同阻温特性的内在机制.     

Luminescent Enhancement in Mg- and Er-Codoped LiNbO3 Crystals

We investigate the MgO codoping-induced effect on the luminescent properties of Er^3 -doped and Er/Mg codoped LiNbO3 crystals. The emission and excitation spectra and the absorption spectra are measured. The results show that the luminescent behaviour of Er^3 ions is very sensitive to the codoping of Mg^2 ions. According to the photorefractive level theory, we propose a quench model for the Er/Mg codoped lithium niobate crystal. The quench centres are suggested to be the bipolaron (NbLi-NbNb), we attribute the luminescent enhancement to the decreasing concentration of these centres. The luminescent enhancement effect is successfully explained.     

Ferroelectricity in hexagonal YFeO3 film at room temperature

In this paper we report the leakage current,ferroelectric and piezoelectric properties of the YFe O3film with hexagonal structure,which was fabricated on Si(111)substrate by a simple sol-gel method.The leakage current test shows good characteristics as the leakage current density is 5.4×10-6A/cm2under 5 V.The dominant leakage mechanism is found to be an Ohmic behavior at low electric field and space-charge-limited conduction at high electric field region.The P–E measurements show ferroelectric hysteresis loops with small remnant polarization and coercive field at room temperature.The distinct and switchable domain structures on the nanometer scale are observed by piezoresponse force microscopy,which testifies to the ferroelectricity of the YFe O3film further.     

具有变指标的反应扩散方程组问题的熄灭解（英文）

本文研究一类具有变指标的反应扩散方程组的非齐次第一初边值问题.通过利用多个变指标的最大值给出方程组问题熄灭解的两个分量发生同时或非同时熄灭的最优判据,继而给出熄灭速率.     

Enhanced ferroelectricity and ferromagnetism in Bio.9Bao. 1FeO3/Laz/3Srl/3MnO3 heterostructure grown by pulsed laser deposition

Bi0.9Ba0.lFeO3 （BBFO）/La2/3Srl/3MnO3 （LSMO） heterostructures are fabricated on LaA103 （100） substrates by pulsed laser deposition. Giant remnant polarization value （~ 85 μC/cm2） and large saturated magnetization value （~ 12.4 emu/cm3） for BBFO/LSMO heterostructures are demonstrated at room temperature. Mixed ferroelectric domain structures and low leakage current are observed and in favor of enhanced ferroelectrie properties in the BBFO/LSMO het- erostructures. The magnetic field-dependent magnetization measurements reveal the enhancement in the magnetic moment and improved magnetic hysteresis loop originating from the BBFO/LSMO interface. The heterostructure is proved to be effective in enhancing the ferroelectric and ferromagnetic performances in multiferroic BFO films at room temperature.