全文获取类型
收费全文 | 111篇 |
免费 | 15篇 |
国内免费 | 24篇 |
专业分类
化学 | 70篇 |
力学 | 34篇 |
数学 | 19篇 |
物理学 | 27篇 |
出版年
2024年 | 1篇 |
2023年 | 4篇 |
2022年 | 4篇 |
2021年 | 3篇 |
2020年 | 3篇 |
2019年 | 6篇 |
2018年 | 6篇 |
2017年 | 5篇 |
2016年 | 7篇 |
2015年 | 12篇 |
2014年 | 9篇 |
2013年 | 8篇 |
2012年 | 8篇 |
2011年 | 10篇 |
2010年 | 9篇 |
2009年 | 3篇 |
2008年 | 7篇 |
2007年 | 2篇 |
2006年 | 5篇 |
2005年 | 5篇 |
2004年 | 4篇 |
2003年 | 2篇 |
2002年 | 1篇 |
2000年 | 3篇 |
1999年 | 7篇 |
1998年 | 4篇 |
1997年 | 5篇 |
1995年 | 2篇 |
1993年 | 3篇 |
1989年 | 2篇 |
排序方式: 共有150条查询结果,搜索用时 0 毫秒
1.
The thermal and thermo-elastic-plastic response of newly developed ceramic-metalfunctionally graded materials under a thermal shock load is studied.The materials are heated at the ce-ramic surface with a sudden high-intensity heat flux input,and cooled at the metal surface with aflowing liquid nitrogen.Emphasis is placed on two aspects:(1)the influence of the graded composi-tion of the materials on the temperature and stress response;and(2)the optimum design of the gradedcomposition from a unified viewpoint of the heat insulation property and stress relaxation property.Moreover,a comparison between the thermoelastic stress and the thermo-elastic-plastic stress is alsomade to indicate the plasticity effect. 相似文献
2.
由于场景中目标与背景的温差相对较小,红外图像会存在对比度低、视觉效果差的问题,针对这一问题,提出一种基于奇异值非线性修正的红外图像对比度实时增强方法。该方法首先对红外图像进行奇异值分解得到其原始奇异值,然后采用一个对数型非线性变换对图像奇异值进行优化,最后根据修正的奇异值重构出对比度增强的红外图像。利用对数型非线性变换修正图像奇异值不仅能够有效拉伸奇异值的动态范围,同时可优化奇异值的变化梯度,使图像的能量信息得到更充分地表达,改善红外图像不良的视觉效果。实验结果表明,该方法较几种对比方法在视觉效果和客观评价方面均具有更优的增强性能;同时体现出良好的实时性,为实现红外图像的实时增强提供了新途径。 相似文献
3.
The catalytic activity of cefia-supported Pd for selective hydrogenation of CO is well preserved in the presence of 30 ppm H2S due to the parallel oxidation of sulfur by CeO2 under standard methanol synthesis conditions. The bifunctional nature of this catalyst opens a route for the conversion of sulfur-contaminated gas streams such as the integrated gasification combined cycle syngas or biogas into liquid fuels if desulfurization by conventional means is not practical. 相似文献
4.
5.
6.
Synthesis and Catalytic Reactions of Nanoparticles formed by Electrospray Ionization of Coinage Metals 下载免费PDF全文
Anyin Li Qingjie Luo Prof. So‐Jung Park Prof. R. Graham Cooks 《Angewandte Chemie (International ed. in English)》2014,53(12):3147-3150
Noble metals can be ionized by electrochemical corrosion and transported by electrospray ionization. Mass spectrometry (MS) showed solvated metal ions as the main ionic constituent of the sprayed droplets. Collection of the electrospray plume on a surface yielded noble metal nanoparticles (NPs) under ambient conditions. The NPs were characterized by several techniques. Under typical conditions, capped‐nanoparticle sizes averaged 2.2 nm for gold and 6.5 nm for silver. The gold nanoparticles showed high catalytic activity in the reduction of p‐nitrophenol by NaBH4. Efficient catalysis was also observed by simply directing the spray of solvated Au+ onto the surface of an aqueous p‐nitrophenol/NaBH4 mixture. Organometallic ions were generated by spiking ligands into the spray solvent: for example, CuI bipyridine cations dominated the spray during Cu electrocorrosion in acetonitrile containing bipyridine. This organometallic reagent was shown to be effective in the radical polymerization of styrene. 相似文献
7.
Qingjie Zhao Chunkai Wang Edward L. Ezell Yuxiang Dong Jonathan L. Vennerstrom 《Tetrahedron letters》2014
When praziquantel was exposed to N-bromosuccinimide in the presence of ethanol, a tricyclic 3-bromo-1-ethoxy pyrazinone was formed. From this and the analogous 1,3-dibromopyrazinone, a small library of 3-alkylamino-1-ethoxy, 1,3-dialkoxy, 3-alkoxy-1-bromo, and 3-alkylamino-1-bromo substituted pyrazinones were synthesized in high yields. 相似文献
8.
Yuan Yongning Yuan Nini Guo Tuo Bai Hongcun Xia Hongqiang Ren Yanjiao Guo Qingjie 《Structural chemistry》2022,33(3):721-731
Structural Chemistry - A detailed theoretical analysis of the mechanism of chemical bond activation in cyclohexane catalysed by the atomic transition-metal cation Ni+ was performed by density... 相似文献
9.
Mei Xiang Qingjie Jiao Yanli Zhu Jinyang Yu Liping Chen 《Journal of Thermal Analysis and Calorimetry》2014,116(3):1159-1163
The thermal behavior of the energetic material 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaaza-tetracyclo-[5.5.0.05,9.03,11]-dodecane (HNIW or CL-20) and its mixtures with aluminum under linear temperature control condition and adiabatic condition were investigated by DSC-TG-MS-FT-IR and ARC. Two different particle sizes of aluminum powder (10 μm and 50 nm) were added into CL-20. The influence of particle size on the thermal behavior of CL-20 was studied by using of these apparatuses. The enthalpies of reaction and onset temperatures were determined for various heating rates. The kinetic parameters were found according to Kissinger method, Ozawa method, and Friedman method based on DSC data. The gaseous products from the decomposition of CL-20 and its mixtures were determined by simultaneous MS-FT-IR experiments. ARC measurements were performed to investigate the thermal stability of the samples. The onset temperature, adiabatic temperature rise, self-heat rate, time to maximum rate, and pressure–temperature profile were found from the data measured by ARC. Based on these results, the catalytic effect of aluminum powder was studied. 相似文献
10.