Pressure Transient Behavior of High-Fracture-Density Reservoirs (Dual-Porosity Models)

Transport in Porous Media - Naturally fractured reservoirs (NFRs) contain primary (macro), secondary, and tertiary (minor) fractures. These reservoirs are heterogeneous, where fracture properties...     

Study of hydrogen-bonded clusters of 2-methoxyphenol–water

Various hydrogen-bonded clusters of 2-methoxyphenol (2MP) with water have been analyzed using ab initio methods and Atoms in Molecules (AIM) theory. The intramolecular hydrogen bond energy (and enthalpy) for 2MP was evaluated from two different methods. The results of rotational barriers method are in better agreement with experimental data. Binding energies, vibrational frequencies and geometrical parameters were examined and compared for these complexes. It was shown that in the most stable complex, water acts both as a donor and an acceptor. The “bifurcated” complex was shown to be relatively stable based on energy values. Atoms in Molecules and Natural Bond Orbital (NBO) analysis were used to confirm the existence of hydrogen bonds and to compare the strengths of them. The results obtained from quantum mechanical, AIM and NBO calculations are in agreement with each other.     

Comparison of the three-phase oil relative permeability models

A comparative study of seven different methods for predicting three-phase oil relative permeabilities in the presence of gas and water phases is presented. Predicted oil relative permeabilities from these correlations have been compared with published three-phase experimental data obtained in Berea sandstone core samples. Some of the correlations under study have been recently developed and have never been tested against the laboratory data.The comparison shows that the commonly used models such as Stones' often do not give accurate predictions of the experimental data. It is concluded that the recently developed models fit the experimental data as well as or better than the previously developed and widely used three-phase oil relative permeability models.     

Effective Permeability of a Porous Medium with Spherical and Spheroidal Vug and Fracture Inclusions

Vugs and fractures are common features of carbonate formations. The presence of vugs and fractures in porous media can significantly affect pressure and flow behavior of a fluid. A vug is a cavity (usually a void space, occasionally filled with sediments), and its pore volume is much larger than the intergranular pore volume. Fractures occur in almost all geological formations to some extent. The fluid flow in vugs and fractures at the microscopic level does not obey Darcy’s law; rather, it is governed by Stokes flow (sometimes is also called Stokes’ law). In this paper, analytical solutions are derived for the fluid flow in porous media with spherical- and spheroidal-shaped vug and/or fracture inclusions. The coupling of Stokes flow and Darcy’s law is implemented through a no-jump condition on normal velocities, a jump condition on pressures, and generalized Beavers–Joseph–Saffman condition on the interface of the matrix and vug or fracture. The spheroidal geometry is used because of its flexibility to represent many different geometrical shapes. A spheroid reduces to a sphere when the focal length of the spheroid approaches zero. A prolate spheroid degenerates to a long rod to represent the connected vug geometry (a tunnel geometry) when the focal length of the spheroid approaches infinity. An oblate spheroid degenerates to a flat spheroidal disk to represent the fracture geometry. Once the pressure field in a single vug or fracture and in the matrix domains is obtained, the equivalent permeability of the vug with the matrix or the fracture with matrix can be determined. Using the effective medium theory, the effective permeability of the vug–matrix or fracture–matrix ensemble domain can be determined. The effect of the volume fraction and geometrical properties of vugs, such as the aspect ratio and spatial distribution, in the matrix is also investigated. It is shown that the higher volume fraction of the vugs or fractures enhances the effective permeability of the system. For a fixed-volume fraction, highly elongated vugs or fractures significantly increase the effective permeability compared with shorter vugs or fractures. A set of disconnected vugs or fractures yields lower effective permeability compared with a single vug or fracture of the same volume fraction.     

Plasma Oxidation of Polypropylene Fibers for Concrete Reinforcement

Russian Journal of Applied Chemistry - In this project, the fibers were applied to increase the tensile strength of the concrete and produce fiber reinforced concrete (FRC). Polypropylene (PP) is...