Structure of the larvicideN-(2-chlorobenzoyl)-N′-[4-(2-chloro-3,3,3-trifluoroprop-1-enyl)phenyl]urea,C17H11Cl2F3O2N2

Mw=403,2 amu,P2₁/c,a 18.944(8) Å,b=8.540(4) Å,c=10.794(7) Å,=98.11(4)°,V=1729(2) ų,Z=4,D _x=1.548 g·cm^–3, (MoK)=4.26 cm^–1; m.p. 202–204°C. FinalR=0.083 for 1632 independent observed reflections having 2 (Mo K)<50° andI>2 (I). The molecule has an extended overall nonplanar conformation with onecis and twotrans-C(O)-NH- units and intramolecular hydrogen bridges. The relatively highR factor is on account of conformational disorder of the trifluoromethyl and chloro substituents of the 2-chloro-3,3,3-trifluoropropenyl moiety.     

Vibrational analysis for surge precursor definition in gas turbines

Compressor behaviour analysis in critical working conditions, such as incipient surge, represents a significant aspect in the turbomachinery research field. Turbines connected with large-size volumes present critical issues related to surge prevention especially during transient operations. Investigations based on acoustic and vibrational measurements appear to provide an interesting diagnostic and predictive solution by adopting suitable quantifiers calculated from microphone and accelerometer signals. For this scope a wide experimental activity has been conducted on a T100 microturbine connected with different volume sizes. A machine dynamical characterisation has been useful for better interpretation of signals during its transient to the surge. Hence, different possible methods of incipient surge identification have been developed through the use of different signal processing techniques in time, frequency and angle domain. These results will be useful for control system development to prevent compressor failures.

     

Operation extension in gas turbine-based advanced cycles with a surge prevention tool

This work aims to present the development and testing of an innovative tool for surge prevention in advanced gas turbine cycles. The presence of additional components, such as a saturator in humid cycles, a heat exchanger for an external combustor, a solar receiver or fuel cell stack in a hybrid system, implies the presence of larger size volumes between compressor outlet and recuperator or expander inlet. This large volume increases the risk of incurring in surge instability, especially during dynamic operations. For these reasons, at the University of Genoa, the Thermochemical Power Group (TPG) has implemented four surge precursors in a new diagnostic real-time software which can recognise a surge incipience condition comparing the precursor values with a set of moving thresholds. The most innovative aspects of this work are: (i) operational range extension and safer management of advanced gas turbine systems for energy generation, (ii) positive impact in energy efficiency due to this range extension of high efficiency systems, (iii) development of a new diagnostic tool for surge prevention using standard probes, (iv) small impact of this tool on the control and sensor costs, (v) software flexibility for adaptation to different conditions and machines. This very important final aspect is obtained with thresholds able to change automatically to adapt themselves to the plant and machine operational regime. From the cost point of view, the utilization of standard measurements is an essential requirement to equip commercial machines without significant impact on the capital costs. The software performance has been demonstrated using experimental data from a test rig composed of a T100 microturbine connected with a modular vessel, which permits to generate the effect of additional components (especially from the volume size point of view). Vibro-acoustic data, collected during machine transients from a stable operative condition to surge, were used to tune all the software parameters and to obtain a good surge predictivity.

     

Synthesis of Lobesia botrana and Spodoptera littoralis natural sex-attractants

Starting from the coupling reaction of alkyl cuprates with 1-alkynyl-2-propenyl acetates, the title compounds were prepared by short convenient syntheses.