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1.
John Swain 《Zeitschrift fur Physik C Particles and Fields》1996,71(1):455-457
The final states for the processb→sy have been extensively discussed in the literature. Similarly-detailed analyses for the caseb→s gluon have not been performed. Generally this process is searched for in 2-body decays such as B0→K+ π ?. We present simple arguments to suggest that most of the time the quark-level process will give rise to final states with rather high multiplicities. Comments are made about the applicability of these results tob→d gluon and hadronicb→u decays. 相似文献
2.
Mogon Patel Anthony C. Swain Robert S. Maxwell 《Polymer Degradation and Stability》2006,91(3):548-554
Poly(m-carboranyl-siloxane) elastomers containing a mixture of di-methyl- and methylphenyl-silyl units were synthesised using the ferric chloride catalysed condensation reaction between di-chloro-diorganosilane and bis(di-methylmethoxysilyl)-m-carborane. These elastomeric materials were originally developed to have greater stability to extreme thermal environments and retain tailorable physical and chemical properties relative to comparable non-carborane containing elastomers. Prepared samples were aged either by heating in air at elevated temperatures or by gamma irradiation from a 60Co source. Multinuclear (1H, 13C and 11B) solid and solution state nuclear magnetic resonance (NMR) was used to assess degradation. This included measurements of segmental chain dynamics using a solid-echo pulse sequence reflecting changes in crosslink density and assessing changes to the carborane fragment by 11B and 1H Magic Angle Spinning (MAS) methods. Thermogravimetric measurements were also performed to assess thermal stability. Gamma radiation (to a dose of 1 MGy) was found to induce only a small degree of elastomer hardening as evidenced by a reduction in segmental chain dynamics. The carborane cage however, remained intact at these dose levels. Thermal degradation was observed to lead to oxidative crosslinking, the degree of which is dependent on temperature. At temperatures below 350 °C, only small changes in segmental dynamics were observed commensurate with only minor weight loss at this temperature. At temperatures above 350 °C, the degradation of the elastomer increased dramatically with decreased segmental dynamics and presumed partial oxidation of the carborane cage. The integrity of the m-carborane cage and the segmental dynamics were found to be significantly reduced at temperatures above 580 °C, in line with the known cage rearrangement temperature for icosahedral carboranes. 相似文献
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Ultranarrow Spectral Lines via Quantum Interference 总被引:2,自引:0,他引:2
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Solvent isotope effects for H2O---D2O mixtures and for ionic hydration equilibria in such mixtures can be calculated from the structure difference between D2O and H2O and that between HDO and H2O and the relative amounts of the three waters. The behavior of acids in H2O---D2O mixtures is considered in detail. Dissociation constants of acetic acid are calculated over the complete range of deuterium concentrations and found to agree with the experimentally determined ones. The Gross equation for the dependence of isotope effect on mole fraction of deuterium for acid-catalyzed reaction of substrates S proceeding via SL+ transition states (L=H or D) is derived from first principles. 相似文献
6.
Vickers deformation/fracture indentations have been investigated in six silicate glasses. The characteristic damage patterns fall into two distinct groups, according to whether the glass shows “normal” or “anomalous” mechanical behaviour. Observations of the damage morphology during and after contact, of the scales of the deformation and fracture zones, and of the residual stress intensity about the impressions, all point to a basic difference in the local stress/strain micromechanics. This difference is discussed in relation to the factors which control the brittleness of glass. 相似文献
7.
JPC – Journal of Planar Chromatography – Modern TLC - A simple normal-phase high-performance thin-layer chromatography (HPTLC) method has been developed for the quantification of... 相似文献
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Trilochan Swain 《Journal of Thermal Analysis and Calorimetry》2012,110(2):929-935
A new inorganically template metaphosphate of Ni(II) complex has been synthesized and characterized by different measurements such as DSC, FT-IR, C?CH?CN?CS, X-RD and ICP-AES. Differential scanning calorimeter (DSC) elucidated negative specific heat of the system and has used to evaluate some thermodynamical constants like specific heat, enthalpy and entropy of that system. The specific heat capacity of the system is measured in atmospheric O2 at heating rate of 278 and 283?K?min?1. The specific heat is found both positive and negative at 278?K?min?1. 相似文献